skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Life cycle based alternatives assessment (LCAA) for chemical substitution
The world faces an increasing need to phase out harmful chemicals and design sustainable alternatives across various consumer products and industrial applications. Alternatives assessment is an emerging field with focus on identifying viable solutions to substitute harmful chemicals. However, current methods fail to consider trade-offs from human and ecosystem exposures, and from impacts associated with chemical supply chains and product life cycles. To close this gap, we propose a life cycle based alternatives assessment (LCAA) framework for consistently integrating quantitative exposure and life cycle impact performance in the substitution process. We start with a pre-screening based on function-related decision rules, followed by three progressive tiers from (1) rapid risk screening of various alternatives for the consumer use stage, to (2) an assessment of chemical supply chain impacts for selected alternatives with substantially different synthesis routes, and (3) an assessment of product life cycle impacts for alternatives with substantially different product life cycles. Each tier focuses on relevant impacts and uses streamlined assessment methods. While the initial risk screening will be sufficient for evaluating chemicals with similar supply chains, each additional tier helps further restricting the number of viable solutions, while avoiding unacceptable trade-offs. We test our LCAA framework in a proof-of-concept case study for identifying suitable alternatives to a harmful plasticizer in household flooring. Results show that the use stage dominates human health impacts across alternatives, supporting that a rapid risk screening is sufficient unless very different supply chains or a broader set of alternative materials or technologies are considered. Combined with currently used indicators for technical and economic performance, our LCAA framework is suitable for informing function-based substitution at the level of chemicals, materials and product applications to foster green and sustainable chemistry solutions.  more » « less
Award ID(s):
1743682
PAR ID:
10214654
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Green Chemistry
Volume:
22
Issue:
18
ISSN:
1463-9262
Page Range / eLocation ID:
6008 to 6024
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Consumer electronic products have a complex life cycle, characterized by environmental, social, and economic impacts and benefits associated with their manufacturing, use, and disposal at end-of-life. Accurately analysing these trade-offs and creating sustainable solutions requires data about the materials and components that make up these devices. Such information is rarely disclosed by manufacturers and only exists in the open literature in disparate case study format. This study presents a comprehensive database of bill of material (BOM) data describing the mass of major materials and components contained in 95 unique consumer electronic products. Data are generated by product disassembly and physical characterization and then validated against external benchmarks in the literature. The study also contributes a reproducible framework for organizing BOM data so that they can be expanded as new products enter the market. These data will benefit researchers studying all aspects of electronics and sustainability, including material scarcity, product design, environmental life cycle assessment, electronic waste policy, and environmental health and safety. 
    more » « less
  2. Abstract Meeting the United Nations (UN) sustainable development goals efficiently requires designers and engineers to solve multi-objective optimization problems involving trade-offs between social, environmental, and economical impacts. This paper presents an approach for designers and engineers to quantify the social and environmental impacts of a product at a population level and then perform a trade-off analysis between those impacts. In this approach, designers and engineers define the attributes of the product as well as the materials and processes used in the product’s life cycle. Agent-based modeling (ABM) tools that have been developed to model the social impacts of products are combined with life cycle assessment (LCA) tools that have been developed to evaluate the pressures that different processes create on the environment. Designers and engineers then evaluate the trade-offs between impacts by finding non-dominated solutions that minimize environmental impacts while maximizing positive and/or minimizing negative social impacts. Product adoption models generated by ABM allow designers and engineers to approximate population level environmental impacts and avoid Simpson’s paradox, where a reversal in choices is preferred when looking at the population level impacts versus the individual product-level impacts. This analysis of impacts has the potential to help designers and engineers create more impactful products that aid in reaching the UN sustainable development goals. 
    more » « less
  3. With their numerous products and uses, multifunctional crops offer an attractive means for improving smallholder farmer livelihoods. This study applies a Life Cycle Sustainability Assessment (LCSA) to Moringa oleifera (moringa), a multifunctional crop with diverse applications in nutrition, cosmetics, and water treatment. The LCSA includes an Environmental Life Cycle Assessment (ELCA), Social Life Cycle Assessment (SLCA), and Life Cycle Costing (LCC). Surveys were conducted with 58 smallholder farmers and five moringa processors in Ghana. The ReCiPe 2016 Midpoint method was used for the ELCA. The 10-year Net Present Value (NPV) and Payback Period (PBP) were calculated for farmers and processors in the LCC. The SLCA focused on the Worker stakeholder category, particularly smallholder farmer impacts, including indicators for Next Generation Farming, Inclusiveness, Access to Services, Food Security, and Livelihood. A composite sustainability score was calculated from the ELCA, SLCA, and LCC results using the Characteristic Objects Method (COMET), a multi-criteria decision analysis method resistant to rank-reversal. The study compared five supply chains: leaf-only, leaf-and-seed, leaf-and-seed with seedcake reuse, seed-only, and seed-only with seedcake reuse. Environmental hotspots were identified in leaf and seed collection. Economically, leaf-only cultivation provided the highest 10-year NPV for farmers, while seed-only with seedcake reuse yielded the highest NPV for processors. The leaf-only supply chain had the best PBP for both farmers and processors. Socially, leaf-only cultivators outperformed reference points across all indicators, making it the most socially sustainable supply chain. Our findings highlight that improving market access, organizing seed cultivators into farmer-based groups, and optimizing farm gate product collection can enhance the sustainability of moringa supply chains, offering a model for other multifunctional crops in rural development. This study is the first to integrate LCSA with COMET, a promising approach that could be adopted in other sustainability assessment case studies. 
    more » « less
  4. Understanding tropical forest dynamics and planning for their sustainable management require efficient, yet accurate, predictions of the joint dynamics of hundreds of tree species. With increasing information on tropical tree life histories, our predictive understanding is no longer limited by species data but by the ability of existing models to make use of it. Using a demographic forest model, we show that the basal area and compositional changes during forest succession in a neotropical forest can be accurately predicted by representing tropical tree diversity (hundreds of species) with only five functional groups spanning two essential trade-offs—the growth-survival and stature-recruitment trade-offs. This data-driven modeling framework substantially improves our ability to predict consequences of anthropogenic impacts on tropical forests. 
    more » « less
  5. Global concerns about climate change and resource management have escalated the need for sustainable consumer products. In light of this, sustainable design methodologies that supplement the product design process are needed. Current research focuses on developing sustainable design curricula, adapting classical design methods to accommodate environmental sustainability, and sustainability tools that are applicable during the early design phase. However, concurrent work suggests that sustainability-marketed and innovative products still lack a reduction of environmental impact compared to conventional products. Life cycle assessment (LCA) has proven to be an exceptional tool used to assess the environmental impact of a realized product. However, LCA is a reactive tool that does not proactively reduce the environmental impact of novel product concepts. Here we develop a novel methodology, the PeeP method, using historical product LCA data with kernel density estimation to provide an estimated environmental impact range for a given product design. The PeeP method is tested using a series of case studies exploring four different products. Results suggest that probability density estimations developed through this method reflect the environmental impact of the product at both the product and component level. In the context of sustainable design research, the PeeP method is a viable methodology for assessing product design environmental impact prior to product realization. Our methodology can allow designers to identify high-impact components and reduce the cost of product redesign in practice. 
    more » « less