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Title: Controlled hierarchical self-assembly of networked coordination nanocapsules via the use of molecular chaperones
Supramolecular chaperones play an important role in directing the assembly of multiple protein subunits and redox-active metal ions into precise, complex and functional quaternary structures. Here we report that hydroxyl tailed C -alkylpyrogallol[4]arene ligands and redox-active Mn II ions, with the assistance of proline chaperone molecules, can assemble into two-dimensional (2D) and/or three-dimensional (3D) networked nanocapsules. Dimensionality is controlled by coordination between the exterior of nanocapsule subunits, and endohedral functionalization within the 2D system is achieved via chaperone guest encapsulation. The tailoring of surface properties of nanocapsules via coordination chemistry is also shown as an effective method for the fine-tuning magnetic properties, and electrochemical and spectroscopic studies support that the nanocapsule is an effective homogeneous water-oxidation electrocatalyst, operating at pH 6.07 with an exceptionally low overpotential of 368 mV.  more » « less
Award ID(s):
1825352
PAR ID:
10215643
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Chemical Science
Volume:
11
Issue:
46
ISSN:
2041-6520
Page Range / eLocation ID:
12547 to 12552
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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