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Recent progress on stretchable, tough dual-dynamic polymer single networks (SN) and interpenetrated networks (IPN) has broadened the potential applications of dynamic polymers. However, the impact of macromolecular structure on the material mechanics remains poorly understood. Here, rapidly exchanging hydrogen bonds and thermoresponsive Diels–Alder bonds were included into molecularly engineered interpenetrated network materials. RAFT polymerization was used to make well-defined polymers with control over macromolecular architecture. The IPN materials were assessed by gel permeation chromatography, differential scanning calorimetry, tensile testing and rheology. The mechanical properties of these IPN materials can be tuned by varying the crosslinker content and chain length. All materials are elastic and have dynamic behavior at both ambient temperature and elevated temperature (90 °C), owing to the presence of the dual dynamic noncovalent and covalent bonds. 100% self-healing recovery was achieved and a maximum stress level of up to 6 MPa was obtained. The data suggested the material's healing properties are inversely proportional to the content of the crosslinker or the degree of polymerization at both room and elevated temperature. The thermoresponsive crosslinker restricted deformation to some extent in an ambient environment but gave excellent malleability upon heating. The underlying mechanism was explored by the computational simulations. Furthermore, a single network material with the same crosslinker content and degree of polymerization as the IPN was made. The SN was substantially weaker than the comparable IPN material.
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Dynamic covalent chemistry for architecture changing interpenetrated and single networks
Interpenetrating networks (IPN) comprise two or more networks which are woven but not covalently bonded to each other. This is in contrast to simple, or single Networks (SN), which contain only one network that is covalently crosslinked. This study develops SNs and IPNs using 2-hydroxyethyl acrylate as the monomer and (2-((1-(2-(acryloyloxy)ethyl)-2,5-dioxopyrrolidin-3-yl) thio)ethyl acrylate) (TMMDA) as a thermoresponsive dynamic thiol-Michael crosslinker. In the case of the IPN and SN materials the TMMDA is used as a thermoresponsive linker in each network, since TMMDA undergoes dynamic covalent exchange above 90 °C. In this way the SN and IPNs are kinetically trapped in their as synthesized structures until exposed to thermal stimulus. The focus of this study is to investigate how dynamic bond exchange can modulate material properties, after the material has been synthesized using the SN and IPN materials as model systems. The dynamic nature of the thiol-Michael crosslinker allows the transition of IPNs into SN like structures above 90 °C resulting in similar polymer architecture in both SN and IPN. Surprisingly, upon heating the SN materials also changed their mechanical properties, upon activation of the dynamic thiol-Michael bonds. This enhancement is proposed to occur by thermally activating the thiol-Michael bonds and reducing the number of floppy loops at higher temperature.
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- Award ID(s):
- 1749730
- PAR ID:
- 10218040
- Date Published:
- Journal Name:
- Polymer Chemistry
- ISSN:
- 1759-9954
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D1PY00198A
