skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.
Attention:The NSF Public Access Repository (PAR) system and access will be unavailable from 11:00 PM ET on Thursday, May 14 until 2:00 AM ET on Friday, May 15 due to maintenance. We apologize for the inconvenience.


Title: Extreme isotopic heterogeneity in Samoan clinopyroxenes constrains sediment recycling
Abstract Lavas erupted at hotspot volcanoes provide evidence of mantle heterogeneity. Samoan Island lavas with high 87 Sr/ 86 Sr (>0.706) typify a mantle source incorporating ancient subducted sediments. To further characterize this source, we target a single high 87 Sr/ 86 Sr lava from Savai’i Island, Samoa for detailed analyses of 87 Sr/ 86 Sr and 143 Nd/ 144 Nd isotopes and major and trace elements on individual magmatic clinopyroxenes. We show the clinopyroxenes exhibit a remarkable range of 87 Sr/ 86 Sr—including the highest observed in an oceanic hotspot lava—encompassing ~30% of the oceanic mantle’s total variability. These new isotopic data, data from other Samoan lavas, and magma mixing calculations are consistent with clinopyroxene 87 Sr/ 86 Sr variability resulting from magma mixing between a high silica, high 87 Sr/ 86 Sr (up to 0.7316) magma, and a low silica, low 87 Sr/ 86 Sr magma. Results provide insight into the composition of magmas derived from a sediment-infiltrated mantle source and document the fate of sediment recycled into Earth’s mantle.  more » « less
Award ID(s):
1900652
PAR ID:
10222126
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Nature Communications
Volume:
12
Issue:
1
ISSN:
2041-1723
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract To deconvolve contributions from the four overlapping hotspots that form the “hotspot highway” on the Pacific plate—Samoa, Rarotonga, Arago-Rurutu, and Macdonald—we geochemically characterize and/or date (by the 40Ar/39Ar method) a suite of lavas sampled from the eastern region of the Samoan hotspot and the region “downstream” of the Samoan hotspot track. We find that Papatua seamount, located ~60 km south of the axis of the Samoan hotspot track, has lavas with both a HIMU (high μ = 238U/204Pb) composition (206Pb/204Pb = 20.0), previously linked to one of the Cook-Austral hotspots, and an enriched mantle I (EM1) composition, which we interpret to be rejuvenated and Samoan in origin. We show that these EM1 rejuvenated lavas at Papatua are geochemically similar to rejuvenated volcanism on Samoan volcanoes and suggest that flexural uplift, caused by tectonic forces associated with the nearby Tonga trench, triggered a new episode of melting of Samoan mantle material that had previously flattened and spread laterally along the base of the Pacific plate under Papatua, resulting in volcanism that capped the previous HIMU edifice. We argue that this process generated Samoan rejuvenated volcanism on the older Cook-Austral volcano of Papatua. We also study Waterwitch seamount, located ~820 km WNW of the Samoan hotspot, and provide an age (10.49 ± 0.09 Ma) that places it on the Samoan hotspot trend, showing that it is genetically Samoan and not related to the Cook-Austral hotspots as previously suggested. Consequently, with the possible exception of the HIMU stage of Papatua seamount, there are currently no known Arago-Rurutu plume-derived lava flows sampled along the swath of Pacific seafloor that stretches between Rose seamount (~25 Ma) and East Niulakita seamount (~45 Ma), located 1400 km to the west. The “missing” ~20-million-year segment of the Arago-Rurutu hotspot track may have been subducted into the northern Tonga trench, or perhaps was covered by subsequent volcanism from the overlapping Samoan hotspot, and has thus eluded sampling. Finally, we explore tectonic reactivation as a cause for anomalously young volcanism present within the western end of the Samoan hotspot track. 
    more » « less
  2. null (Ed.)
    The noble gas isotope systematics of ocean island basalts suggest the existence of primordial mantle signatures in the deep mantle. Yet, the isotopic compositions of lithophile elements (Sr, Nd, Hf) in these lavas require derivation from a mantle source that is geochemically depleted by melt extraction rather than primitive. Here, this apparent contradiction is resolved by employing a compilation of the Sr, Nd, and Hf isotope composition of kimberlites—volcanic rocks that originate at great depth beneath continents. This compilation includes kimberlites as old as 2.06 billion years and shows that kimberlites do not derive from a primitive mantle source but sample the same geochemically depleted component (where geochemical depletion refers to ancient melt extraction) common to most oceanic island basalts, previously called PREMA (prevalent mantle) or FOZO (focal zone). Extrapolation of the Nd and Hf isotopic compositions of the kimberlite source to the age of Earth formation yields a 143 Nd/ 144 Nd- 176 Hf/ 177 Hf composition within error of chondrite meteorites, which include the likely parent bodies of Earth. This supports a hypothesis where the source of kimberlites and ocean island basalts contains a long-lived component that formed by melt extraction from a domain with chondritic 143 Nd/ 144 Nd and 176 Hf/ 177 Hf shortly after Earth accretion. The geographic distribution of kimberlites containing the PREMA component suggests that these remnants of early Earth differentiation are located in large seismically anomalous regions corresponding to thermochemical piles above the core–mantle boundary. PREMA could have been stored in these structures for most of Earth’s history, partially shielded from convective homogenization. 
    more » « less
  3. Abstract The Lower Jurassic Ferrar Large Igneous Province consists predominantly of intrusive rocks, which crop out over a distance of 3500 km. In comparison, extrusive rocks are more restricted geographically. Geochemically, the province is divided into the Mount Fazio Chemical Type, forming more than 99% of the exposed province, and the Scarab Peak Chemical Type, which in the Ross Sea sector is restricted to the uppermost lava. The former exhibits a range of compositions (SiO 2 = 52–59%; MgO = 9.2–2.6%; Zr = 60–175 ppm; Sr i = 0.7081–0.7138; ε Nd = −6.0 to −3.8), whereas the latter has a restricted composition (SiO 2 = c. 58%; MgO = c. 2.3%; Zr = c. 230 ppm; Sr i = 0.7090–0.7097; ε Nd = −4.4 to −4.1). Both chemical types are characterized by enriched initial isotope compositions of neodymium and strontium, low abundances of high field strength elements, and crust-like trace element patterns. The most basic rocks, olivine-bearing dolerites, indicate that these geochemical characteristics were inherited from a mantle source modified by subduction processes, possibly the incorporation of sediment. In one model, magmas were derived from a linear source having multiple sites of generation each of which evolved to yield, in sum, the province-wide coherent geochemistry. The preferred interpretation is that the remarkably coherent geochemistry and short duration of emplacement demonstrate derivation from a single source inferred to have been located in the proto-Weddell Sea region. The spatial variation in geochemical characteristics of the lavas suggests distinct magma batches erupted at the surface, whereas no clear geographical pattern is evident for intrusive rocks. 
    more » « less
  4. We present new observations on the dynamics and locations of deep mantle reservoirs derived from the ages and compositions of Voyager Seamount Chain lava flows. The previously unexplored Voyager Seamount Chain trends NW–SE between the Mid‐Pacific Mountains and the Northwestern Hawaiian Ridge. Volcanic samples were recovered from the chain during the Ocean Exploration Trust expedition NA134. The lava flows are alkalic to highly alkalic in composition. Ages ranged from 81 to 86 Ma (n = 8), with the oldest ages in the NW and an age‐progression toward the SE. The Voyager age‐progression continues southward through the Northern Line Islands region until at least 69 Ma. Mantle flowlines using absolute plate motion models indicate that the Voyagers were emplaced near the modern Marquesas Hotspot location approximately 86–69 Ma. The Sr‐Nd‐Pb‐Hf isotope systematics show the influence of an EMII component and overlap the compositions of Pliocene volcanism from the Marquesas Islands, consistent with the plate motion age model. These data imply a long‐lived plume as the source of the Voyager seamounts and the Marquesas. However, the lack of a clear and continuous seamount chain between the 86–69 Ma Voyager Seamount Chain and the 6–0 Ma Marquesas Islands implies that the mantle plume displays variable buoyancy flux over time. The surface expression of this mantle reservoir experienced a potential hiatus of up to ∼60 m.y. These new data indicate that the mantle beneath the Marquesas Islands region has been discontinuously producing age‐progressive, EMII‐like hotspot volcanism since at least the Late Cretaceous. 
    more » « less
  5. null (Ed.)
    Oceanic island basalts are targeted for geochemical study because they provide a direct window into mantle composition and a wealth of information on the dynamics and timescales associated with Earth mixing. Previous studies mainly focused on the shield volcanic stage of oceanic islands and the more fusible, enriched mantle components that are easily distinguished in those basalts. Mantle depleted compositions are typically more difficult to resolve unless large amounts of this material participated in mantle melting (e.g., mid-ocean ridges), or unique processes allow for their compositions to be erupted undiluted, such as very small degrees of melting of a source with minimal fusible enriched components (e.g., rejuvenated basalts) or as xenoliths (e.g., abyssal peridotites). Mantle depleted components, defined here as material with low time-integrated Rb/Sr (low 87Sr/86Sr) and high time-integrated Sm/Nd and Lu/Hf ratios (high 143Nd/144Nd and 176Hf/177Hf) relative to primitive mantle, derive from a potentially very large volume reservoir (up to 80% of the mantle), and therefore need adequate characterization in order estimate the composition of the Earth and mantle-derived melts. This review focuses on mantle depleted compositions in oceanic island basalts using the Hawaiian-Emperor chain as a case study. The Hawaiian-Emperor chain is the ∼6000 km long geological record of the deeply sourced Hawaiian mantle plume, active for>81 Myr. Hawaiian volcanism evolves through four volcanic stages as a volcano traverses the Hawaiian plume: alkalic preshield, tholeiitic shield (80–90% volcano volume), alkalic postshield (∼1%), and silica undersaturated rejuvenated (< 0.1%). We report Pb-Sr-Nd-Hf isotope compositions and trace element concentrations of three rejuvenated Northwest Hawaiian Ridge basalts and compare them to an exhaustive compiled dataset of basalts from the Hawaiian Islands to the Emperor Seamounts. The Northwest Hawaiian Ridge (NWHR) includes 51 volcanoes spanning ∼42 m.y. between the bend in the Hawaiian-Emperor chain and the Hawaiian Islands where there is no high-precision isotopic data published on the rejuvenated-stage over ∼47% of the chain. NWHR and Hawaiian Island rejuvenated basalts are geochemically similar, indicating a consistent source for rejuvenated volcanism over ∼12.5 million years. In contrast, shield-stage basalts from the oldest Emperor Seamounts are more depleted in isotopic composition (i.e., higher 176Hf/177Hf, and 143Nd/144Nd with lower 87Sr/86Sr and 208Pb*/206Pb*) and trace element concentrations (i.e., much lower concentrations of highly incompatible elements) than all other depleted Hawaiian basalts younger than the bend, including NWHR rejuvenated basalts. The strongly depleted source for the oldest Emperor Seamounts (> 70 Ma) was likely related to interaction with the Kula-Pacific-Izanagi mid-ocean ridge spreading system active near the Hawaiian plume in the Late Cretaceous. In contrast, the incompatible trace element ratios of NWHR rejuvenated basalts require a distinct source in the Hawaiian mantle plume that was imprinted by ancient (> 1 Ga) partial melting, likely ancient recycled oceanic lithosphere. This review of the geochemistry of Hawaiian depleted components documents the need for the sampling of multiple distinctive depleted compositions, each preferentially melted during specific periods of Hawaiian plume activity. This suggests that the composition of depleted components can evolve during the lifetime of the mantle plume, as observed for enriched components in the Hawaiian mantle plume. Changes in the composition of depleted components are dominantly controlled by the upper mantle tectonic configurations at the time of eruption (i.e., proximity to a mid-ocean ridge), as this effect overwhelms the signal imparted by potentially sampling different lower mantle components through time. 
    more » « less