Search for: All records

Lavas erupted at hotspot volcanoes provide evidence of mantle heterogeneity. Samoan Island lavas with high⁸⁷Sr/⁸⁶Sr (>0.706) typify a mantle source incorporating ancient subducted sediments. To further characterize this source, we target a single high⁸⁷Sr/⁸⁶Sr lava from Savai’i Island, Samoa for detailed analyses of⁸⁷Sr/⁸⁶Sr and¹⁴³Nd/¹⁴⁴Nd isotopes and major and trace elements on individual magmatic clinopyroxenes. We show the clinopyroxenes exhibit a remarkable range of⁸⁷Sr/⁸⁶Sr—including the highest observed in an oceanic hotspot lava—encompassing ~30% of the oceanic mantle’s total variability. These new isotopic data, data from other Samoan lavas, and magma mixing calculations are consistent with clinopyroxene⁸⁷Sr/⁸⁶Sr variability resulting from magma mixing between a high silica, high⁸⁷Sr/⁸⁶Sr (up to 0.7316) magma, and a low silica, low⁸⁷Sr/⁸⁶Sr magma. Results provide insight into the composition of magmas derived from a sediment-infiltrated mantle source and document the fate of sediment recycled into Earth’s mantle.

 

The element mercury (Hg) can develop large mass‐independent fractionation (MIF) (Δ¹⁹⁹Hg) due to photo‐chemical reactions at Earth's surface. This results in globally negative Δ¹⁹⁹Hg for terrestrial sub‐aerially‐derived materials and positive Δ¹⁹⁹Hg for sub‐aqueously‐derived marine sediments. The mantle composition least affected by crustal recycling is estimated from high‐³He/⁴He lavas from Samoa and Iceland, providing an average of Δ¹⁹⁹Hg = 0.00 ± 0.10, Δ²⁰¹Hg = −0.02 ± 0.0.09,δ²⁰²Hg = −1.7 ± 1.2; 2SD,N = 11. By comparison, a HIMU‐type lava from Tubuai exhibits positive Δ¹⁹⁹Hg, consistent with altered oceanic crust in its mantle source. A Samoan (EM2) lava has negative Δ¹⁹⁹Hg reflecting incorporation of continental crust materials into its source. Three Pitcairn lavas exhibit positive Δ¹⁹⁹Hg which correlate with⁸⁷Sr/⁸⁶Sr, consistent with variable proportions of continental (low Δ¹⁹⁹Hg and high⁸⁷Sr/⁸⁶Sr) and oceanic (high Δ¹⁹⁹Hg and low⁸⁷Sr/⁸⁶Sr) crustal material in their mantle sources. These observations indicate that MIF signatures offer a powerful tool for examining atmosphere‐deep Earth interactions.

 

The spatial distribution of the geochemical domains hosting recycled crust and primordial (high‐³He/⁴He) reservoirs, and how they are linked to mantle convection, are poorly understood. Two continent‐sized seismic anomalies located near the core‐mantle boundary—called the Large Low Shear Wave Velocity Provinces (LLSVPs)—are potential geochemical reservoir hosts. It has been suggested that high‐³He/⁴He hotspots are spatially confined to the LLSVPs, hotspots sampling recycled continental crust are associated with only one of the LLSVPs, and recycled continental crust shows no relationship with latitude. We reevaluate the links between LLSVPs and isotopic signatures of hotspot lavas using improved mantle flow models including plume conduit advection. While most hotspots with the highest‐³He/⁴He can indeed be traced to the LLSVP interiors, at least one high‐³He/⁴He hotspot, Yellowstone, is located outside of the LLSVPs. This suggests high‐³He/⁴He is not geographically confined to the LLSVPs. Instead, a positive correlation between hotspot buoyancy flux and maximum hotspot³He/⁴He suggests that it is plume dynamics (i.e., buoyancy), not geography, which determines whether a dense, deep, and possibly widespread high‐³He/⁴He reservoir is entrained. We also show that plume‐fed EM hotspots (enriched mantle, with low‐¹⁴³Nd/¹⁴⁴Nd), signaling recycled continental crust, are spatially linked to both LLSVPs, and located primarily in the southern hemisphere. Lastly, we confirm that hotspots sampling HIMU (“high‐μ,” or high²³⁸U/²⁰⁴Pb) domains are not spatially limited to the LLSVPs. These findings clarify and advance our understanding of deep mantle reservoir distributions, and we discuss how continental and oceanic crust subduction is consistent with the spatial decoupling of EM and HIMU.

 

The Icelandic hotspot has erupted basaltic magma with the highest mantle‐derived³He/⁴He over a period spanning much of the Cenozoic, from the early‐Cenozoic Baffin Island‐West Greenland flood basalt province (49.8R_A), to mid‐Miocene lavas in northwest Iceland (40.2 to 47.5R_A), to Pleistocene lavas in Iceland's neovolcanic zone (34.3R_A). The Baffin Island lavas transited through and potentially assimilated variable amounts of Precambrian continental basement. We use geochemical indicators sensitive to continental crust assimilation (Nb/Th, Ce/Pb, MgO) to identify the least crustally contaminated lavas. Four lavas, identified as “least crustally contaminated,” have high MgO (>15 wt.%), and Nb/Th and Ce/Pb that fall within the mantle range (Nb/Th = 15.6 ± 2.6, Ce/Pb = 24.3 ± 4.3). These lavas have⁸⁷Sr/⁸⁶Sr = 0.703008–0.703021,¹⁴³Nd/¹⁴⁴Nd = 0.513094–0.513128,¹⁷⁶Hf/¹⁷⁷Hf = 0.283265–0.283284,²⁰⁶Pb/²⁰⁴Pb = 17.7560–17.9375,³He/⁴He up to 39.9R_A, and mantle‐like δ¹⁸O of 5.03–5.21‰. The radiogenic isotopic compositions of the least crustally contaminated lavas are more geochemically depleted than Iceland high‐³He/⁴He lavas, a shift that cannot be explained by continental crust assimilation in the Baffin suite. Thus, we argue for the presence oftwogeochemically distinct high‐³He/⁴He components within the Iceland plume. Additionally, the least crustally contaminated primary melts from Baffin Island‐West Greenland have higher mantle potential temperatures (1510 to 1630 °C) than Siqueiros mid‐ocean ridge basalts (1300 to 1410 °C), which attests to a hot, buoyant plume origin for early Iceland plume lavas. These observations support the contention that the geochemically heterogeneous high‐³He/⁴He domain is dense, located in the deep mantle, and sampled by only the hottest plumes.

 

Volcanic hotspots are thought to be fed by hot, active upwellings from the deep mantle, with excess temperatures ( T ex ) ~100° to 300°C higher than those of mid-ocean ridges. However, T ex estimates are limited in geographical coverage and often inconsistent for individual hotspots. We infer the temperature of oceanic hotspots and ridges simultaneously by converting seismic velocity to temperature. We show that while ~45% of plume-fed hotspots are hot ( T ex ≥ 155°C), ~15% are cold ( T ex ≤ 36°C) and ~40% are not hot enough to actively upwell (50°C ≤ T ex ≤ 136°C). Hot hotspots have an extremely high helium-3/helium-4 ratio and buoyancy flux, but cold hotspots do not. The latter may originate at upper mantle depths. Alternatively, the deep plumes that feed them may be entrained and cooled by small-scale convection. 

The Cook-Austral volcanic lineament extends from Macdonald Seamount (east) to Aitutaki Island (west) in the South Pacific Ocean and consists of hotspot-related volcanic islands, seamounts, and atolls. The Cook-Austral volcanic lineament has been characterized as multiple overlapping, age-progressive hotspot tracks generated by at least two mantle plumes, including the Arago and Macdonald plumes, which have fed volcano construction for ~20 m.y. The Arago and Macdonald hotspot tracks are argued to have been active for at least 70 m.y. and to extend northwest of the Cook-Austral volcanic lineament into the Cretaceous-aged Tuvalu-Gilbert and Tokelau Island chains, respectively. Large gaps in sampling exist along the predicted hotspot tracks, complicating efforts seeking to show that the Arago and Macdonald hotspots have been continuous, long-lived sources of hotspot volcanism back into the Cretaceous. We present new major- and trace-element concentrations and radiogenic isotopes for three seamounts (Moki, Malulu, Dino) and one atoll (Rose), and new clinopyroxene 40Ar/39Ar ages for Rose (24.81 ± 1.02 Ma) and Moki (44.53 ± 10.05 Ma). All volcanoes are located in the poorly sampled region between the younger Cook-Austral and the older, Cretaceous portions of the Arago and Macdonald hotspot tracks. Absolute plate motion modeling indicates that the Rose and Moki volcanoes lie on or near the reconstructed traces of the Arago and Macdonald hotspots, respectively, and the 40Ar/39Ar ages for Rose and Moki align with the predicted age progression for the Arago (Rose) and Macdonald (Moki) hotspots, thereby linking the younger Cook-Austral and older Cretaceous portions of the long-lived (>70 m.y.) Arago and Macdonald hotspot tracks. 

The noble gas isotope systematics of ocean island basalts suggest the existence of primordial mantle signatures in the deep mantle. Yet, the isotopic compositions of lithophile elements (Sr, Nd, Hf) in these lavas require derivation from a mantle source that is geochemically depleted by melt extraction rather than primitive. Here, this apparent contradiction is resolved by employing a compilation of the Sr, Nd, and Hf isotope composition of kimberlites—volcanic rocks that originate at great depth beneath continents. This compilation includes kimberlites as old as 2.06 billion years and shows that kimberlites do not derive from a primitive mantle source but sample the same geochemically depleted component (where geochemical depletion refers to ancient melt extraction) common to most oceanic island basalts, previously called PREMA (prevalent mantle) or FOZO (focal zone). Extrapolation of the Nd and Hf isotopic compositions of the kimberlite source to the age of Earth formation yields a¹⁴³Nd/¹⁴⁴Nd-¹⁷⁶Hf/¹⁷⁷Hf composition within error of chondrite meteorites, which include the likely parent bodies of Earth. This supports a hypothesis where the source of kimberlites and ocean island basalts contains a long-lived component that formed by melt extraction from a domain with chondritic¹⁴³Nd/¹⁴⁴Nd and¹⁷⁶Hf/¹⁷⁷Hf shortly after Earth accretion. The geographic distribution of kimberlites containing the PREMA component suggests that these remnants of early Earth differentiation are located in large seismically anomalous regions corresponding to thermochemical piles above the core–mantle boundary. PREMA could have been stored in these structures for most of Earth’s history, partially shielded from convective homogenization.