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1. Early Planet Formation in Embedded Disks (eDisk). III. A First High-resolution View of Submillimeter Continuum and Molecular Line Emission toward the Class 0 Protostar L1527 IRS

   https://doi.org/10.3847/1538-4357/accf87  

   van ’t Hoff, Merel L. R. ; Tobin, John J. ; Li, Zhi-Yun ; Ohashi, Nagayoshi ; Jørgensen, Jes K. ; Lin, Zhe-Yu Daniel ; Aikawa, Yuri ; Aso, Yusuke ; de Gregorio-Monsalvo, Itziar ; Gavino, Sacha ; et al ( June 2023 , The Astrophysical Journal)

   Studying the physical and chemical conditions of young embedded disks is crucial to constrain the initial conditions for planet formation. Here we present Atacama Large Millimeter/submillimeter Array observations of dust continuum at ∼0.″06 (8 au) resolution and molecular line emission at ∼0.″17 (24 au) resolution toward the Class 0 protostar L1527 IRS from the Large Program eDisk (Early Planet Formation in Embedded Disks). The continuum emission is smooth without substructures but asymmetric along both the major and minor axes of the disk as previously observed. The detected lines of¹²CO,¹³CO, C¹⁸O, H₂CO, c-C₃H₂, SO, SiO, and DCN trace different components of the protostellar system, with a disk wind potentially visible in¹²CO. The¹³CO brightness temperature and the H₂CO line ratio confirm that the disk is too warm for CO freezeout, with the snowline located at ∼350 au in the envelope. Both molecules show potential evidence of a temperature increase around the disk–envelope interface. SO seems to originate predominantly in UV-irradiated regions such as the disk surface and the outflow cavity walls rather than at the disk–envelope interface as previously suggested. Finally, the continuum asymmetry along the minor axis is consistent with the inclination derived from the large-scale (100″ or 14,000 au) outflow, but opposite to that based on the molecular jet and envelope emission, suggesting a misalignment in the system. Overall, these results highlight the importance of observing multiple molecular species in multiple transitions to characterize the physical and chemical environment of young disks.

    

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2. Cold Deuterium Fractionation in the Nearest Planet-forming Disk

   https://doi.org/10.3847/1538-4357/aca765  

   Muñoz-Romero, Carlos E. ; Öberg, Karin I. ; Law, Charles J. ; Teague, Richard ; Aikawa, Yuri ; Bergner, Jennifer B. ; Wilner, David J. ; Huang, Jane ; Guzmán, Viviana V. ; Cleeves, L. Ilsedore ( January 2023 , The Astrophysical Journal)

   Deuterium fractionation provides a window into the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed toward a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new Atacama Large Millimeter/submillimeter Array observations of DCO⁺and DCNJ= 2–1 at an angular resolution of 0.″5 (30 au) and combine them with archival data of higher energy transitions toward the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO⁺and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of 1.9 × 10¹²and 9.8 × 10¹¹cm⁻²for DCO⁺and DCN, with typical kinetic temperatures for both molecules of 20–30 K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO⁺/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas-phase C/O enhancement within <40 au. Observations of DCO⁺and DCN in other disks, as well as HCN and HCO⁺, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks.

    

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3. The Central 1000 au of a Prestellar Core Revealed with ALMA. II. Almost Complete Freeze-out

   https://doi.org/10.3847/1538-4357/ac5913  

   Caselli, Paola ; Pineda, Jaime E. ; Sipilä, Olli ; Zhao, Bo ; Redaelli, Elena ; Spezzano, Silvia ; Maureira, Maria José ; Alves, Felipe ; Bizzocchi, Luca ; Bourke, Tyler L. ; et al ( April 2022 , The Astrophysical Journal)

   Abstract Prestellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures (<10 K) allow the formation of thick icy dust mantles, which will be partially preserved in future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in prestellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH 3 and, in particular, its deuterated isotopologues appear to maintain high abundances where CO molecules are mainly in the solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH 2 D freeze-out toward the L1544 prestellar core, suggestive of the presence of a “complete depletion zone” within a ≃1800 au radius, in agreement with astrochemical prestellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH 2 D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing out already at ≃7000 au. Radiative transfer effects within the prestellar core cause the NH 2 D(1 11 − 1 01 ) emission to appear centrally concentrated, with a flattened distribution within the central ≃3000 au, unlike the 1.3 mm dust continuum emission, which shows a clear peak within the central ≃1800 au. This prevented NH 2 D freeze-out from being detected in previous observations, where the central 1000 au cannot be spatially resolved. 

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4. Molecules with ALMA at Planet-forming Scales (MAPS). XI. CN and HCN as Tracers of Photochemistry in Disks

   https://doi.org/10.3847/1538-4365/ac143a  

   Bergner, Jennifer B. ; Öberg, Karin I. ; Guzmán, Viviana V. ; Law, Charles J. ; Loomis, Ryan A. ; Cataldi, Gianni ; Bosman, Arthur D. ; Aikawa, Yuri ; Andrews, Sean M. ; Bergin, Edwin A. ; et al ( November 2021 , The Astrophysical Journal Supplement Series)

   Abstract UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects; however, to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N = 1–0 transitions at 0.″3 resolution toward five disk systems. All disks show bright CN emission within ∼50–150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions and also means that CN is the dominant carrier of the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement. 

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5. SO and SiS Emission Tracing an Embedded Planet and Compact 12 CO and 13 CO Counterparts in the HD 169142 Disk

   https://doi.org/10.3847/2041-8213/acdfd0  

   Law, Charles J. ; Booth, Alice S. ; Öberg, Karin I. ( August 2023 , The Astrophysical Journal Letters)

   Planets form in dusty, gas-rich disks around young stars, while at the same time, the planet formation process alters the physical and chemical structure of the disk itself. Embedded planets will locally heat the disk and sublimate volatile-rich ices, or in extreme cases, result in shocks that sputter heavy atoms such as Si from dust grains. This should cause chemical asymmetries detectable in molecular gas observations. Using high-angular-resolution ALMA archival data of the HD 169142 disk, we identify compact SOJ= 8₈− 7₇and SiSJ= 19 − 18 emission coincident with the position of a ∼ 2M_Jupplanet seen as a localized, Keplerian NIR feature within a gas-depleted, annular dust gap at ≈38 au. The SiS emission is located along an azimuthal arc and has a morphology similar to that of a known¹²CO kinematic excess. This is the first tentative detection of SiS emission in a protoplanetary disk and suggests that the planet is driving sufficiently strong shocks to produce gas-phase SiS. We also report the discovery of compact¹²CO and¹³COJ= 3 − 2 emission coincident with the planet location. Taken together, a planet-driven outflow provides the best explanation for the properties of the observed chemical asymmetries. We also resolve a bright, azimuthally asymmetric SO ring at ≈24 au. While most of this SO emission originates from ice sublimation, its asymmetric distribution implies azimuthal temperature variations driven by a misaligned inner disk or planet–disk interactions. Overall, the HD 169142 disk shows several distinct chemical signatures related to giant planet formation and presents a powerful template for future searches of planet-related chemical asymmetries in protoplanetary disks.

    

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