Title: Preference of cis -Thioamide Structure in N -Thioacyl- N -methylanilines
Award ID(s):
1650766
PAR ID:
10224909
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Organic Letters
Volume:
22
Issue:
24
ISSN:
1523-7060
Page Range / eLocation ID:
9500 to 9505
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
    First row transition metal complexes (Ni, Co, Cu, Zn) with N , N -disubstituted- N ′-acylthiourea ligands have been synthesized and characterized. Bis( N , N -diisopropyl- N ′-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N , N -diisopropyl- N ′-cinnamoylthiourea complexes at 350 °C has been demonstrated. 
    more » « less
  2. The synthesis of the title compound, C 13 H 21 NO 2 S, is reported here along with its crystal structure. This compound crystallizes with two molecules in the asymmetric unit. The sulfonamide functional group of this structure features S=O bond lengths ranging from 1.433 (3) to 1.439 (3) Å, S—C bond lengths of 1.777 (3) and 1.773 (4) Å, and S—N bond lengths of 1.622 (3) and 1.624 (3) Å. When viewing the molecules down the S—N bond, the isopropyl groups are gauche to the aromatic ring. On each molecule, two methyl hydrogen atoms of one isopropyl group are engaged in intramolecular C—H...O hydrogen bonds with a nearby sulfonamide oxygen atom. Intermolecular C—H...O hydrogen bonds and C—H...π interactions link molecules of the title compound in the solid state. 
    more » « less
  3. null (Ed.)