An official website of the United States government
Abstract A body that violates Kirchhoff’s law of thermal radiation exhibits an inequality in its spectral directional absorptivity and emissivity. Achieving such an inequality is of fundamental interest as well as a prerequisite for achieving thermodynamic limits in photonic energy conversion1and radiative cooling2. Thus far, inequalities in the spectral directional emissivity and absorptivity have been limited to narrow spectral resonances3, or wavelengths well beyond the infrared regime4. Bridging the gap from basic demonstrations to practical applications requires control over a broad spectral range of the unequal spectral directional absorptivity and emissivity. In this work, we demonstrate broadband nonreciprocal thermal emissivity and absorptivity by measuring the thermal emissivity and absorptivity of gradient epsilon-near-zero InAs layers of subwavelength thicknesses (50 nm and 150 nm) with an external magnetic field. The effect occurs in a spectral range (12.5–16 μm) that overlaps with the infrared transparency window and is observed at moderate (1 T) magnetic fields.
more »
« less
Blackbody-cavity ideal absorbers for solar energy harvesting
Abstract Spectrally selective solar absorbers (SSAs), which harvest heat from sunlight, are the key to concentrated solar thermal systems. An ideal SSA must have an absorptivity of unity in the solar irradiance wavelength region (0.3–2.5 $$\upmu $$ μ m), and its infrared thermal emissivity must be zero to depress spontaneous blackbody irradiation (2.5–25 $$\upmu $$ μ m). Current SSA designs which utilize photonic crystals, metamaterials, or cermets are either cost-inefficient due to the complexity of the required nanofabrication methods, or have limited applicability due to poor thermal stability at high temperatures. We conceptually present blackbody-cavity solar absorber designs with nearly ideal spectrally selective properties, capable of being manufactured at scale. The theoretical analyses show that the unity solar absorptivity of the blackbody cavity and nearly zero infrared emissivity of the SSA’s outer surface allow for a stagnation temperature of 880 $$^\circ $$ ∘ C under 10 suns. The performance surpasses state-of-the-art SSAs manufactured using nanofabrication methods. This design relies only on traditional fabrication methods, such as machining, casting, and polishing. This makes it suitable for large-scale industrial applications, and the “blackbody cavity” feature enables easy integration with existing concentrated solar thermal systems using the parabolic reflector and Fresnel lens as optical concentrators.
more »
« less
- Award ID(s):
- 1941743
- PAR ID:
- 10228784
- Date Published:
- Journal Name:
- Scientific Reports
- Volume:
- 10
- Issue:
- 1
- ISSN:
- 2045-2322
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Radiative cooling textiles hold promise for achieving personal thermal comfort under increasing global temperature. However, urban areas have heat island effects that largely diminish the effectiveness of cooling textiles as wearable fabrics because they absorb emitted radiation from the ground and nearby buildings. We developed a mid-infrared spectrally selective hierarchical fabric (SSHF) with emissivity greatly dominant in the atmospheric transmission window through molecular design, minimizing the net heat gain from the surroundings. The SSHF features a high solar spectrum reflectivity of 0.97 owing to strong Mie scattering from the nano-micro hybrid fibrous structure. The SSHF is 2.3°C cooler than a solar-reflecting broadband emitter when placed vertically in simulated outdoor urban scenarios during the day and also has excellent wearable properties.more » « less
-
Recent advancements in nonreciprocal thermal emitters challenge the conventional Kirchhoff's law, which states that emissivity and absorptivity should be equal for a given direction, frequency, and polarization. These emitters can break Kirchhoff's law and enable unprecedented thermal photon control capabilities. However, current studies mainly focus on increasing the magnitude of the contrast between emissivity and absorptivity, with little attention paid to how the sign or bandwidth of the contrast may be controlled. In this work, we show such control ability can be achieved by coupling resonances that can provide opposite contrasts between emissivity and absorptivity.more » « less
-
Abstract Controlling both the spectral bandwidth and directionality of emitted thermal radiation is a fundamental challenge in contemporary photonics. Recent work has shown that materials with a spatial gradient in the frequency range of their epsilon‐near‐zero (ENZ) response can support broad spectrum directionality in their emissivity, enabling high total radiance to specific angles of incidence. However, this capability is limited spectrally and directionally by the availability of materials with phonon‐polariton resonances over long‐wave infrared wavelengths. Here, an approach is designed and experimentally demonstrated using doped III–V semiconductors that can simultaneously tailor spectral peak, bandwidth, and directionality of infrared emissivity. InAs‐based gradient ENZ photonic structures that exhibit broadband directional emission with varying spectral bandwidths and directional ranges as a function of their doping concentration profile and thickness are epitaxially grown and characterized. Due to its easy‐to‐fabricate geometry, it is believed that this approach provides a versatile photonic platform to dynamically control broadband spectral and directional emissivity for a range of emerging applications in heat transfer and infrared sensing.more » « less
-
This study introduces a movable piston-like structure that provides a simple and cost-effective avenue for dynamically tuning thermal radiation. This structure leverages two materials with dissimilar optical responses—graphite and aluminum—to modulate from a state of high reflectance to a state of high absorptance. A cavity is created in the graphite to house an aluminum cylinder, which is displaced to actuate the device. In its raised state, the large aluminum surface area promotes a highly reflective response, while in its lowered state, the expanded graphite surface area and blackbody cavity-like interactions significantly enhance absorptance. By optimizing the area ratio, reflectance tunability of over 30% is achieved for nearly the entire ultraviolet, visible, and near-infrared wavelength regions. Furthermore, a theoretical analysis postulates wavelength-dependent effectivenesses as high as 0.70 for this method, indicating that tunabilities approaching 70% can be achieved by exploiting near-ideal absorbers and reflectors. The analog nature of this control method allows for an infinitely variable optical response between the upper and lower bounds of the device. These valuable characteristics would enable this material structure to serve practical applications, such as reducing cost and energy requirements for environmental temperature management operations.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1038/s41598-020-77372-9
