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Abstract Switchable radiative cooling based on the phase-change material vanadium dioxide (VO₂) automatically modulates thermal emission in response to varying ambient temperature. However, it is still challenging to achieve constant indoor temperature control solely using a VO₂-based radiative cooling system, especially at low ambient temperatures. Here, we propose a reverse-switching VO₂-based radiative cooling system, assisting indoor air conditioning to obtain precise indoor temperature control. Unlike previous VO₂-based radiative cooling systems, the reverse VO₂-based radiative cooler turns on radiative cooling at low ambient temperatures and turns off radiative cooling at high ambient temperatures, thereby synchronizing its cooling modes with the heating and cooling cycles of the indoor air conditioning during the actual process of precise temperature control. Calculations demonstrate that our proposed VO₂-based radiative cooling system significantly reduces the energy consumption by nearly 30 % for heating and cooling by indoor air conditioning while maintaining a constant indoor temperature, even surpassing the performance of an ideal radiative cooler. This work advances the intelligent thermal regulation of radiative cooling in conjunction with the traditional air conditioning technology. 

Abstract Heat dissipation is a severe barrier for ever‐smaller and more functionalized electronics, necessitating the continuous development of accessible, cost‐effective, and highly efficient cooling solutions. Metals, such as silver and copper, with high thermal conductivity, can efficiently remove heat. However, ultralow infrared thermal emittance (<0.03) severely restricts their radiative heat dissipation capability. Here, a solution‐processed chemical oxidation reaction is demonstrated for transfiguring “infrared‐white” metals (high infrared thermal reflectance) to “infrared‐black” metametals (high infrared thermal emittance). Enabled by strong molecular vibrations of metal‐oxygen chemical bonds, this strategy via assembling nanostructured metal oxide thin films on metal surface yields infrared spectrum manipulation, high and omnidirectional thermal emittance (0.94 from 0 to 60°) with excellent thermomechanical stability. The thin film of metal oxides with relatively high thermal conductivity does not hinder heat dissipation. “Infrared‐black” meta‐aluminum shows a temperature drop of 21.3 °C corresponding to a cooling efficiency of 17.2% enhancement than the pristine aluminum alloy under a heating power of 2418 W m⁻². This surface photon‐engineered strategy is compatible with other metals, such as copper and steel, and it broadens its implementation for accelerating heat dissipation. 

Abstract Passive radiative cooling, drawing heat energy of objects to the cold outer space through the atmospheric transparent window, is significant for reducing the energy consumption of buildings. Daytime and nighttime radiative cooling have been extensively investigated in the past. However, radiative cooling which can continuously regulate its cooling temperature, like a valve, according to human need is rarely reported. In this study, we propose a reconfigurable photonic structure, based on the effective medium theory and semi-analytical calculations, for the adaptive radiative cooling by continuous variation of the emission spectra in the atmospheric window. This is realized by the deformation of a one-dimensional polydimethylsiloxane (PDMS) grating and nanoparticle-embedded PDMS thin film when subjected to mechanical stress/strain. The proposed structure reaches different stagnation temperatures under certain strains. A dynamic tuning in emissivity under different strains results in a continuously variable “ON”/“OFF” mode in a particular atmospheric window that corresponds to the deformation-induced fluctuation of the operating temperatures of the reconfigurable nanophotonic structure. 

Abstract Solar‐driven steam generation, whereby solar energy is harvested to purify water directly, is emerging as a promising approach to mitigate the worldwide water crisis. The scalable application of conventional 3D evaporators is hindered by their complex spatial geometries. A 2.5D structure is a spatial extension of a 2D structure with an addition of a third vertical dimension, achieving both the feasibility of 2D structure and the performance of 3D structure simultaneously. Here, an interconnected open‐pore 2.5D Cu/CuO foam‐based photothermal evaporator capable of achieving a high evaporation rate of 4.1 kg m⁻²h⁻¹under one sun illumination by exposing one end of the planar structure to air is demonstrated. The micro‐sized open‐pore structure of Cu/CuO foam allows it to trap incident sunlight, and the densely distributed blade‐like CuO nanostructures effectively scatter sunlight inside pores simultaneously. The inherent hydrophilicity of CuO and capillarity forces from the porous structure of Cu foam continuously supply sufficient water. Moreover, the doubled working sides of Cu/CuO foam enlarge the exposure area enabling efficient vapor diffusion. The feasible fabrication process and the combined structural features of Cu/CuO foam offer new insight into the future development of solar‐driven evaporators in large‐scale applications with practical durability. 

Phase-change materials (PCMs) play a pivotal role in the development of advanced thermal devices due to their reversible phase transitions, which drastically modify their thermal and optical properties. In this study, we present an effective dynamic thermal transistor with an asymmetric design that employs distinct PCMs, vanadium dioxide (VO2), and germanium antimony telluride (GST), on either side of the gate terminal, which is the center of the control unit of the near-field thermal transistor. This asymmetry introduces unique thermal modulation capabilities, taking control of thermal radiation in the near-field regime. VO2 transitions from an insulating to a metallic state, while GST undergoes a reversible switch between amorphous and crystalline phases, each inducing substantial changes in thermal transport properties. By strategically combining these materials, the transistor exhibits enhanced functionality, dynamically switching between states of absorbing and releasing heat by tuning the temperature of gate. This gate terminal not only enables active and efficient thermal management but also provides effective opportunities for manipulating heat flow in radiative thermal circuits. Our findings highlight the potential of such asymmetrically structured thermal transistors in advancing applications across microelectronics, high-speed data processing, and sustainable energy systems, where precise and responsive thermal control is critical for performance and efficiency. 

Comparative evaporation rate testing in a dark environment, commonly used to characterize a reduced vaporization enthalpy in interfacial solar evaporators, requires the assumption of equal energy input between cases. However, this assumption is not generally valid, leading to misleading characterization results. Interfacial evaporators yield larger evaporation rates in dark conditions due to enlarged liquid-vapor surface areas, resulting in increased evaporative cooling and larger environmental temperature differentials. Theoretical and experimental evidence is provided, which shows that these temperature differences invalidate the equal energy input assumption. The results indicate that differences in evaporation rates correspond to energy input variations, without requiring enthalpy to be reduced below theoretical values. These findings offer alternative explanations for previous claims of reduced vaporization enthalpy and contradict enthalpy-related conclusions drawn from differential scanning calorimetry. We conclude that postulating a reduced vaporization enthalpy using the dark environment method is inaccurate and that re-evaluation of vaporization enthalpy reduction is required.