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1. Accurate Determination of the Quantity and Spatial Distribution of Counterions around a Spherical Macroion

   https://doi.org/10.1002/anie.202013806  

   Chen, Jiahui ; Bera, Mrinal K. ; Li, Hui ; Yang, Yuqing ; Sun, Xinyu ; Luo, Jiancheng ; Baughman, Jessi ; Liu, Cheng ; Yao, Xuesi ; Chuang, Steven S. C. ; et al ( January 2021 , Angewandte Chemie International Edition)

   The accurate distribution of countercations (Rb⁺and Sr²⁺) around a rigid, spherical, 2.9‐nm size polyoxometalate cluster, {Mo₁₃₂}⁴²⁻, is determined by anomalous small‐angle X‐ray scattering. Both Rb⁺and Sr²⁺ions lead to shorter diffuse lengths for {Mo₁₃₂} than prediction. Most Rb⁺ions are closely associated with {Mo₁₃₂} by staying near the skeleton of {Mo₁₃₂} or in the Stern layer, whereas more Sr²⁺ions loosely associate with {Mo₁₃₂} in the diffuse layer. The stronger affinity of Rb⁺ions towards {Mo₁₃₂} than that of Sr²⁺ions explains the anomalous lower critical coagulation concentration of {Mo₁₃₂} with Rb⁺compared to Sr²⁺. The anomalous behavior of {Mo₁₃₂} can be attributed to majority of negative charges being located at the inner surface of its cavity. The longer anion–cation distance weakens the Coulomb interaction, making the enthalpy change owing to the breakage of hydration layers of cations more important in regulating the counterion–{Mo₁₃₂} interaction.

    

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2. Hydrothermal Seepage of Altered Crustal Formation Water Seaward of the Middle America Trench, Offshore Costa Rica

   https://doi.org/10.1029/2023GC011246  

   Parsons, Patrice K. F. ; Wheat, C. Geoffrey ; Fisher, Andrew T. ; Silver, Eli A. ; Hutnak, Michael ( January 2024 , Geochemistry, Geophysics, Geosystems)

   Chemical compositions of sediment pore waters are presented from 13 piston and gravity cores that were collected on ∼24 Ma crust of the Cocos Plate seaward of the Middle America Trench and near the onset of crustal faulting from subduction. Cores were collected mainly within a 1.75 km²area overlying a buried basement topographic high that supports an elevated heat flux, consistent with seawater transport within the upper volcanic crust. Systematic variations in pore water chemical profiles indicate upward seepage speeds (up to 1.7 cm yr⁻¹providing a net flux of 0.1 L s⁻¹), constrain the chemical composition of the formation water within the underlying upper basaltic basement, and elucidate diagenetic reactions in the sediment. Relative to seawater, formation water has an elevated temperature (70–80°C) and concentrations or values of Ca, chlorinity, Sr, Ba, Li, Fe, Mn, Si, Cs, D/H, and Mo, and lower concentrations or values of Mg, Na, sulfate, alkalinity, TCO₂, K, B, F, phosphate,⁸⁷Sr/⁸⁶Sr, δ¹³C, δ¹⁸O, U, and Rb. Although this site is located only 30 km from the trench axis, there is no chemical evidence for subduction‐related hydrologic influences. Instead, the data are explained by a combination of seawater‐basalt reactions within the upper basement and diffusive exchange with overlying sediment, as part of a shallow, ridge‐flank hydrothermal system. It is unclear why this site has an elevated heat flux relative to neighboring crust, but this may result from variations in crustal properties or modification related to flexural faulting outboard of the trench.

    

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3. The FRB 20190520B Sight Line Intersects Foreground Galaxy Clusters

   https://doi.org/10.3847/2041-8213/acefb5  

   Lee, Khee-Gan ; Khrykin, Ilya S. ; Simha, Sunil ; Ata, Metin ; Huang, Yuxin ; Prochaska, J. Xavier ; Tejos, Nicolas ; Cooke, Jeff ; Nagamine, Kentaro ; Zhang, Jielai ( August 2023 , The Astrophysical Journal Letters)

   The repeating fast radio burst FRB 20190520B is an anomaly of the FRB population thanks to its high dispersion measure (DM = 1205 pc cm⁻³) despite its low redshift ofz_frb= 0.241. This excess has been attributed to a large host contribution of DM_host≈ 900 pc cm⁻³, far larger than any other known FRB. In this paper, we describe spectroscopic observations of the FRB 20190520B field obtained as part of the FLIMFLAM survey, which yielded 701 galaxy redshifts in the field. We find multiple foreground galaxy groups and clusters, for which we then estimated halo masses by comparing their richness with numerical simulations. We discover two separateM_halo> 10¹⁴M_⊙galaxy clusters atz= 0.1867 and 0.2170 that are directly intersected by the FRB sight line within their characteristic halo radiusr₂₀₀. Subtracting off their estimated DM contributions, as well that of the diffuse intergalactic medium, we estimate a host contribution of${\mathrm{D}\mathrm{M}}_{\mathrm{h}\mathrm{o}\mathrm{s}\mathrm{t}}={430}_{-220}^{+140}$or${280}_{-170}^{+140}\mathrm{p}\mathrm{c}{\mathrm{c}\mathrm{m}}^{-3}$(observed frame), depending on whether we assume that the halo gas extends tor₂₀₀or 2 ×r₂₀₀. This significantly smaller DM_host—no longer the largest known value—is now consistent with Hαemission measures of the host galaxy without invoking unusually high gas temperatures. Combined with the observed FRB scattering timescale, we estimate the turbulent fluctuation and geometric amplification factor of the scattering layer to be$\tilde{F}G\approx 4.5–11{({\mathrm{pc}}^2\mathrm{km})}^{-1/3}$, suggesting that most of the gas is close to the FRB host. This result illustrates the importance of incorporating foreground data for FRB analyses both for understanding the nature of FRBs and to realize their potential as a cosmological probe.

    

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4. Radiogenic Power and Geoneutrino Luminosity of the Earth and Other Terrestrial Bodies Through Time

   https://doi.org/10.1029/2019GC008865  

   McDonough, W. F. ; Šrámek, O. ; Wipperfurth, S. A. ( July 2020 , Geochemistry, Geophysics, Geosystems)

   We report the Earth's rate of radiogenic heat production and (anti)neutrino luminosity from geologically relevant short‐lived radionuclides (SLR) and long‐lived radionuclides (LLR) using decay constants from the geological community, updated nuclear physics parameters, and calculations of theβspectra. We track the time evolution of the radiogenic power and luminosity of the Earth over the last 4.57 billion years, assuming an absolute abundance for the refractory elements in the silicate Earth and key volatile/refractory element ratios (e.g., Fe/Al, K/U, and Rb/Sr) to set the abundance levels for the moderately volatile elements. The relevant decays for the present‐day heat production in the Earth (19.9 ± 3.0 TW) are from⁴⁰K,⁸⁷Rb,¹⁴⁷Sm,²³²Th,²³⁵U, and²³⁸U. Given element concentrations in kg‐element/kg‐rock and densityρin kg/m³, a simplified equation to calculate the present‐day heat production in a rock isurn:x-wiley:ggge:media:ggge22244:ggge22244-math-0001

   The radiogenic heating rate of Earth‐like material at solar system formation was some 10³to 10⁴times greater than present‐day values, largely due to decay of²⁶Al in the silicate fraction, which was the dominant radiogenic heat source for the first∼10 Ma. Assuming instantaneous Earth formation, the upper bound on radiogenic energy supplied by the most powerful short‐lived radionuclide²⁶Al (t_1/2= 0.7 Ma) is 5.5×10³¹ J, which is comparable (within a factor of a few) to the planet's gravitational binding energy.

    

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5. Geodynamic Evolution of the East African Superplume: Insights From Volcanism in the Western Turkana Basin

   https://doi.org/10.1029/2023JB026755  

   Cai, Yue ; Mana, Sara ; Cox, Stephen E. ; Beck, Catherine C. ; Feibel, Craig ; Hanley, Jean ; Liu, Tanzhuo ; Bolge, Louise ; Hemming, Sidney ; Goldstein, Steven L. ( September 2023 , Journal of Geophysical Research: Solid Earth)

   There is a consensus that volcanism along the East African Rift System (EARS) is related to plume activities. However, because of our limited knowledge of the local lithospheric mantle, the dynamics of the plume are poorly constrained by magma chemistry. The Turkana Basin is one of the best places to study plume‐related volcanism because the lithospheric mantle there is unusually thin. New Ar‐Ar geochronology and geochemical data on lavas from western Turkana show that Eocene volcanics have relatively low²⁰⁶Pb/²⁰⁴Pb (<19.1) and high εNd (>3.78). Their relatively high Ba/Rb (35–78) ratios suggest contributions from the shallow lithospheric mantle. Oligo‐Miocene Turkana volcanics have HIMU‐ and EMI‐ type enriched mantle signatures with overall lower Ba/Rb ratios, which is consistent with partial melting of plume material. Pliocene and younger Turkana volcanics have low Ba/Rb and Sr‐Nd‐Pb isotope ratios that resemble those of Ethiopian volcanics with elevated³He/⁴He ratios. This temporal variation can be reconciled with a layered plume model where an outer layer of ancient recycled oceanic crust and sediment overlies more primitive lower mantle material. Beneath Ethiopia, the outer layer of the plume is either missing or punctured by the delamination of the thicker overlying lithospheric mantle atca.30 Ma, an event that would have facilitated the rapid upwelling of the inner portion of the plume and triggered the Ethiopian flood volcanism. The outer layer of the plume may be thicker in the southern EARS, which could explain the occurrence of young HIMU‐ and EMI‐type volcanics with primordial noble gas signatures.

    

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