In mountainous river basins of the Pacific Northwest, climate models predict that winter warming will result in increased precipitation falling as rain and decreased snowpack. A detailed understanding of the spatial and temporal dynamics of water sources across river networks will help illuminate climate change impacts on river flow regimes. Because the stable isotopic composition of precipitation varies geographically, variation in surface water isotope ratios indicates the volume‐weighted integration of upstream source water. We measured the stable isotope ratios of surface water samples collected in the Snoqualmie River basin in western Washington over June and September 2017 and the 2018 water year. We used ordinary least squares regression and geostatistical Spatial Stream Network models to relate surface water isotope ratios to mean watershed elevation (MWE) across seasons. Geologic and discharge data was integrated with water isotopes to create a conceptual model of streamflow generation for the Snoqualmie River. We found that surface water stable isotope ratios were lowest in the spring and highest in the dry, Mediterranean summer, but related strongly to MWE throughout the year. Low isotope ratios in spring reflect the input of snowmelt into high elevation tributaries. High summer isotope ratios suggest that groundwater is sourced from low elevation areas and recharged by winter precipitation. Overall, our results suggest that baseflow in the Snoqualmie River may be relatively resilient to predicted warming and subsequent changes to snowpack in the Pacific Northwest.
Using δ18O and δ2H to Detect Hydraulic Connection Between a Sinkhole Lake and a First‐Magnitude Spring
Oxygen and hydrogen isotopes were used in this study to detect a hydraulic connection between a sinkhole lake and a karst spring. In karst areas, surface water that flows to a lake can drain through sinkholes in the lakebed to the underlying aquifer, and then flows in karst conduits and through aquifer matrix. At the study site located in northwest Florida, USA, Lake Miccosukee immediately drains into two sinkholes. Results from a dye tracing experiment indicate that lake water discharges at Natural Bridge Spring, a first‐magnitude spring 32 km downgradient from the lake. By collecting weekly water samples from the lake, the spring, and a groundwater well 10 m away from the lake during the dry period between October 2019 and January 2020, it was found that, when rainfall effects on isotopic signature in spring water are removed, increased isotope ratios of spring water can be explained by mixing of heavy‐isotope‐enriched lake water into groundwater, indicating hydraulic connection between the lake and the spring. Such a detection of hydraulic connection at the scale of tens of kilometers and for a first‐magnitude spring has not been previously reported in the literature. Based on the isotope ratio data, it was estimated that, during the study period, about 8.5% the spring discharge was the lake water that drained into the lake sinkholes.
more » « less- Award ID(s):
- 1828827
- NSF-PAR ID:
- 10244949
- Publisher / Repository:
- Wiley-Blackwell
- Date Published:
- Journal Name:
- Groundwater
- Volume:
- 59
- Issue:
- 6
- ISSN:
- 0017-467X
- Page Range / eLocation ID:
- p. 856-865
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
more » « less
Abstract -
San Salvador Island is a small isolated carbonate platform on the southeastern edge of the Bahamian Archipelago. The Line Hole well field is located on an eogenetic karst aquifer on San Salvador Island's northern coast. The island's negative water budget and extensive lake cover have resulted in the upconing of saline water that has fragmented the once continuous freshwater lens. The Line Hole well field consists of several 15-cm diameter wells drilled into the fresh-water lens and arranged in a line perpendicular to the shore. The well field also has two monitoring wells (LH 1, and LH 13), that penetrate approximately 7 m below the water table into higher salinity groundwater. The well field was abandoned in 2016 upon saltwater intrusion to the aquifer. To evaluate the connectivity between the eogenetic karst aquifer monitored by the Line Hole well field and the ocean, we instrumented wells with HOBO U20L-04 loggers to measure pressure and temperature timeseries. We instrumented wells LH4, and LH8, in addition to the monitoring wells LH1 and LH13.more » « less
-
null (Ed.)Sinkholes are common and naturally occurring in certain areas such as Florida and Southern Georgia. The region’s aquifer is often covered by limestone or dolomite carbonate rock, which are made up of minerals that can dissolve in water under the right conditions. Anthropogenic changes are leading to an increased risk of sinkholes in susceptible areas. The formation of these geologic features is hastened by the improper management of ground water, the increase in watershed pollution and runoff, and the mismanagement of underground fresh and wastewater pipes and structures. The goal of this study is to develop an automated geospatial model to determine areas within the study having a potential high risk for sinkholes. Eleven types of geospatial data were collected, processed, and analyzed in ArcGIS Pro Model Builder to calculate sinkhole vulnerability layers in the study area. The eleven data types were geology, soil, land use, aquifer, ground water measurements, road, fault line, elevation precipitation, and evapotranspiration. From this data, ten sinkhole vulnerability layers were produced: 1) subsidence or surface change, 2) average aquifer well depth, 3) ground water vulnerability (DRASTIC), 4) road density, 5) groundwater travel time, 6) aquifer media (Suwannee Limestone) , 7) geology type, 8) slope, 9) land use, and 10) distance from fault lines. Each layer was reclassified and reassigned a value from 1 to 10 according to its sinkhole vulnerability. The weighted layers were analyzed interpretively using ArcGIS Pro’s weighted sum tool producing a Sinkhole Risk Probability Raster. The sampling tool was used for accuracy assessment by comparing the obtained result with historical sinkhole data. This method showed 77% accuracy between known sinkholes and those shown on the sinkholes probability raster. This study is useful to environmental planners/managers and other stakeholders for decision support.more » « less
-
null (Ed.)The increased environmental abundance of anthropogenic reactive nitrogen species (Nr = ammonium [NH4+], nitrite [NO2−] and nitrate [NO3−]) may increase atmospheric nitrous oxide (N2O) concentrations, and thus global warming and stratospheric ozone depletion. Nitrogen cycling and N2O production, reduction, and emissions could be amplified in carbonate karst aquifers because of their extensive global range, susceptibility to nitrogen contamination, and groundwater-surface water mixing that varies redox conditions of the aquifer. The magnitude of N2O cycling in karst aquifers is poorly known, however, and thus we sampled thirteen springs discharging from the karstic Upper Floridan Aquifer (UFA) to evaluate N2O cycling. The springs can be separated into three groups based on variations in subsurface residence times, differences in surface–groundwater interactions, and variable dissolved organic carbon (DOC) and dissolved oxygen (DO) concentrations. These springs are oxic to sub-oxic and have NO3− concentrations that range from < 0.1 to 4.2 mg N-NO3−/L and DOC concentrations that range from < 0.1 to 50 mg C/L. Maximum spring water N2O concentrations are 3.85 μg N-N2O/L or ~ 12 times greater than water equilibrated with atmospheric N2O. The highest N2O concentrations correspond with the lowest NO3− concentrations. Where recharge water has residence times of a few days, partial denitrification to N2O occurs, while complete denitrification to N2 is more prominent in springs with longer subsurface residence times. Springs with short residence times have groundwater emission factors greater than the global average of 0.0060, reflecting N2O production, whereas springs with residence times of months to years have groundwater emission factors less than the global average. These findings imply that N2O cycling in karst aquifers depends on DOC and DO concentrations in recharged surface water and subsequent time available for N processing in the subsurface.more » « less
-
null (Ed.)The increased environmental abundance of anthropogenic reactive nitrogen species (Nr = ammonium [NH4+], nitrite [NO2 ] and nitrate [NO3 ]) may increase atmospheric nitrous oxide (N2O) concentrations, and thus global warming and stratospheric ozone depletion. Nitrogen cycling and N2O production, reduction, and emissions could be amplified in carbonate karst aquifers because of their extensive global range, susceptibility to nitrogen contamination, and groundwater-surface water mixing that varies redox conditions of the aquifer. The magnitude of N2O cycling in karst aquifers is poorly known, however, and thus we sampled thirteen springs discharging from the karstic Upper Floridan Aquifer (UFA) to evaluate N2O cycling. The springs can be separated into three groups based on variations in subsurface residence times, differences in surface–groundwater interactions, and variable dissolved organic carbon (DOC) and dissolved oxygen (DO) concentrations. These springs are oxic to sub-oxic and have NO3 concentrations that range from < 0.1 to 4.2 mg N-NO3 /L and DOC concentrations that range from < 0.1 to 50 mg C/L. Maximum spring water N2O concentrations are 3.85 μg N-N2O/L or ~ 12 times greater than water equilibrated with atmospheric N2O. The highest N2O concentrations correspond with the lowest NO3 concentrations. Where recharge water has residence times of a few days, partial denitrification to N2O occurs, while complete denitrification to N2 is more prominent in springs with longer subsurface residence times. Springs with short residence times have groundwater emission factors greater than the global average of 0.0060, reflecting N2O production, whereas springs with residence times of months to years have groundwater emission factors less than the global average. These findings imply that N2O cycling in karst aquifers depends on DOC and DO concentrations in recharged surface water and subsequent time available for N processing in the subsurface.more » « less
