A model is constructed to describe the flow field and arbitrary deformation of a drop or vesicle that contains and is embedded in an electrolyte solution, where the flow and deformation are caused by an applied electric field. The applied field produces an electrokinetic flow, which is set up on the charge-up time scale $\tau _{*c}=\lambda _{*} a_{*}/D_{*}$ , where $\lambda _{*}$ is the Debye screening length, $a_{*}$ is the inclusion length scale and $D_{*}$ is an ion diffusion constant. The model is based on the Poisson–Nernst–Planck and Stokes equations. These are reduced or simplified by forming the limit of strong electrolytes, for which dissolved salts are completely ionised in solution, together with the limit of thin Debye layers. Debye layers of opposite polarity form on either side of the drop interface or vesicle membrane, together forming an electrical double layer. Two formulations of the model are given. One utilises an integral equation for the velocity field on the interface or membrane surface together with a pair of integral equations for the electrostatic potential on the outer faces of the double layer. The other utilises a form of the stress-balance boundary condition that incorporates the double layer structure into relations between the dependent variables on the layers’ outer faces. This constitutes an interfacial boundary condition that drives an otherwise unforced Stokes flow outside the double layer. For both formulations relations derived from the transport of ions in each Debye layer give additional boundary conditions for the potential and ion concentrations outside the double layer.
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Breaking electrolyte symmetry in induced-charge electro-osmosis
Induced-charge electro-osmotic (ICEO) flow caused by an alternating electric field applied around an infinitely long, ideally polarizable, uncharged circular cylinder in a binary electrolyte with unequal cation and anion diffusion coefficients is analysed. The thin-Debye-layer and weak-field approximations are invoked to compute the time-averaged, or rectified, quadrupolar ICEO flow around the cylinder. The inequality of ionic diffusion coefficients leads to transient ion concentration gradients, or concentration polarization, in the electroneutral bulk electrolyte outside the Debye layer. Consequently, the electric potential in the bulk is non-harmonic. Further, the concentration polarization alters the electro-osmotic slip at the surface of the cylinder and generates body forces in the bulk, both of which affect the rectified ICEO flow. Predictions for the strength of the rectified flow for varying ratio of ionic diffusion coefficients are in reasonable agreement with available experimental data. Our work highlights that an inequality in ionic diffusion coefficients – which all electrolytes possess to some extent – is an important factor in modelling ICEO flows.
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- Award ID(s):
- 2002120
- NSF-PAR ID:
- 10250102
- Date Published:
- Journal Name:
- Journal of Fluid Mechanics
- Volume:
- 905
- ISSN:
- 0022-1120
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1017/jfm.2020.754
