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  • Synthesis of a light-harvesting ruthenium porphyrin complex substituted with BODIPY units. Implications for visible light-promoted catalytic oxidations
Title: Synthesis of a light-harvesting ruthenium porphyrin complex substituted with BODIPY units. Implications for visible light-promoted catalytic oxidations
A light-harvesting ruthenium porphyrin substituted covalently with four boron–dipyrrin (BODIPY) moieties has been synthesized and studied. The resulting complex showed an efficient decarbonylation reaction predominantly due to a photo-induced energy transfer process. Chemical oxidation of the ruthenium( ii ) BODIPY–porphyrin afforded a high-energy trans -dioxoruthenium( vi ) species that is one order of magnitude more reactive towards alkene oxidation than those analogues supported by conventional porphyrins. In the presence of visible light, the ruthenium( ii ) BODIPY–porphyrin displayed remarkable catalytic activity toward sulfide oxidation and alkene epoxidation using iodobenzene diacetate [PhI(OAc) 2 ] and 2,6-dichloropyridine N -oxide (Cl 2 pyNO) as terminal oxidants, respectively. The findings in this work highlight that porphyrin–BODIPY conjugated metal complexes are potentially useful for visible light-promoted catalytic oxidations.  more » « less
Award ID(s):
1764315
PAR ID:
10253246
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
New Journal of Chemistry
Volume:
45
Issue:
11
ISSN:
1144-0546
Page Range / eLocation ID:
4977 to 4985
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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