skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Additive Manufacturing of Polymer Matrix Composite Materials with Aligned or Organized Filler Material: A Review
The ability to fabricate polymer matrix composite materials with continuous or discontinuous filler material, oriented in a user‐specified direction, enables implementing designer material properties, such as anisotropic mechanical, thermal, and electrical properties. Conventional fabrication methods rely on a mold, which limits specimen geometry and is difficult to implement. In contrast, additive manufacturing, including fused filament fabrication or fused deposition modeling, direct ink writing, or stereolithography, combined with a method to align filler material such as a mechanical force or an electric, magnetic, shear force, or ultrasound wave field, enables 3D printing polymer matrix composite material specimens with complex geometry and aligned filler material, without the need for a mold. Herein, we review the combinations of fabrication and filler material alignment methods used to fabricate polymer matrix composite materials, in terms of operating and design parameters including size, resolution, print speed, filler material alignment time, polymer matrix and filler material requirements, and filler manipulation requirements. The operating envelope of each fabrication method is described and their advantages, disadvantages, and limitations are discussed. Finally, different combinations of 3D printing and filler material alignment methods in the context of important engineering applications, such as structural materials, flexible electronics, and shape‐changing materials, are illustrated.  more » « less
Award ID(s):
2017588
PAR ID:
10254138
Author(s) / Creator(s):
 ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Advanced Engineering Materials
Volume:
23
Issue:
4
ISSN:
1438-1656
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract: Waste energy harvest using thermoelectric (TE) materials will be a potential solution to the serious environmental pollution and energy shortage problems. Due to limitations of current manufacturing techniques in geometry complexity and high density, TE devices are not widely utilized in daily life to gather waste energy. 3D printing brings an opportunity to solve the fabrication limitations. In this paper, a hybrid process was developed to fabricate thermoelectric materials by integrating hot pressing with stereolithography. The mold and punch were designed and printed to fabricate thermoelectric devices used on hot water tubes via stereolithography. The Sb2Te3 powders filled the 3D printed mold in a layered manner, and each layer of powders was compacted under the pressing of punch at a certain temperature and compressive force. The polymer mold was removed after the sintering process to form the final TE components. A series of experiments were conducted to identify the optimal heating temperature and compressive force. The microstructures morphology and electrical conductivity of fabricated Sb2Te3 samples were evaluated. This research work conducted a scientific investigation into the fabrication of TE material with a hybrid process, including hot pressing and 3D printing, to solve the current manufacturing challenges, providing perspectives on developments of TE devices used in various energy harvest applications. 
    more » « less
  2. Fabricating polymer-matrix composite materials with microfibers aligned along a user-specified direction is important to obtain specific material properties, such as anisotropic electrical and thermal conductivity and improved mechanical strength. We quantify macro- and microscale alignment of microfibers embedded in photopolymer resin, 3D-printed using ultrasound directed self-assembly (DSA) and stereolithography, as a function of three dimensionless input parameters: microfiber weight fraction, dimensionless ultrasound transducer input power, and dimensionless ultrasound transducer separation distance. We use regression analysis to determine microfiber alignment as a function of the fabrication process parameters. Microscale alignment is primarily determined by microfiber weight fraction, whereas macroscale alignment is a function of microfiber weight fraction, dimensionless ultrasound transducer separation distance, and dimensionless ultrasound transducer input power. Relating microfiber alignment to the fabrication process parameters is a crucial step towards 3D-printing composite materials with specific anisotropic material properties. 
    more » « less
  3. Polymer composites are becoming an important class of materials for a diversified range of industrial applications due to their unique characteristics and natural and synthetic reinforcements. Traditional methods of polymer composite fabrication require machining, manual labor, and increased costs. Therefore, 3D printing technologies have come to the forefront of scientific, industrial, and public attention for customized manufacturing of composite parts having a high degree of control over design, processing parameters, and time. However, poor interfacial adhesion between 3D printed layers can lead to material failure, and therefore, researchers are trying to improve material functionality and extend material lifetime with the addition of reinforcements and self-healing capability. This review provides insights on different materials used for 3D printing of polymer composites to enhance mechanical properties and improve service life of polymer materials. Moreover, 3D printing of flexible energy-storage devices (FESD), including batteries, supercapacitors, and soft robotics using soft materials (polymers), is discussed as well as the application of 3D printing as a platform for bioengineering and earth science applications by using a variety of polymer materials, all of which have great potential for improving future conditions for humanity and planet Earth. 
    more » « less
  4. Spearing, M; Tsai, SW; Karbhari, VM (Ed.)
    Triboluminescence (TL) is a phenomenon of light emission induced by impact, stress, fracture, or an applied mechanical force. This phenomenon can be used to detect, evaluate, and predict mechanical failures in composites. In this report, we utilized manganese-doped zinc-sulphide (ZnS: Mn) and Polystyrene (PS) composite to fabricate a TL functional part via additive manufacturing. The morphology of the particles inside the polymer matrix were studied using scanning electron microscopy and micro CT scan. Thermoanalytical techniques such as differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were carried out to evaluate the thermal transitions and degradation of the composites. The mechanoluminescence performance of the printed samples is evaluated by three-point flexural test and observed to depend on processing conditions that can be utilized to achieve a strong light signal at different mechanical loads. The polymer composite fabrication and processing reduced particle size, enhanced particle dispersion, and altered the mechanical properties of the polymer to help increase the mechanoluminescence response up to 10 times in the 3D printed parts. The unique mechanoluminescence properties of 3D printed luminescent composite have great potential for structural monitoring applications. 
    more » « less
  5. The size and shape of polymer materials is becoming an increasingly important property in accessing new functions and applications of nano‐/microparticles in many scientific fields. New synthetic methods have allowed unprecedented capability for the facile fabrication of anisotropic and shape‐defined nanomaterials. Bottom‐up approaches including: emulsion polymerization techniques, amphiphile self‐assembly, and polymerization‐induced self‐assembly, can lead to polymer particles with precise dimensions in the nanoscale. Top‐down methods such as lithographic templating, and 3D printing, have increased the access to unique particle shapes. In this review, these recent developments are appraised and contrasted, with future research directions providing that focus on biomedical applications. Finally, the opportunity available for synergistic combinations of top‐down and bottom‐up fabrication approaches in realizing previously unattainable architectures and material properties is highlighted. 
    more » « less