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Title: Additive manufacturing of functional polymer-based composite with enhanced mechanoluminescence (ZnS:Mn) performance
Triboluminescence (TL) is a phenomenon of light emission induced by impact, stress, fracture, or an applied mechanical force. This phenomenon can be used to detect, evaluate, and predict mechanical failures in composites. In this report, we utilized manganese-doped zinc-sulphide (ZnS: Mn) and Polystyrene (PS) composite to fabricate a TL functional part via additive manufacturing. The morphology of the particles inside the polymer matrix were studied using scanning electron microscopy and micro CT scan. Thermoanalytical techniques such as differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were carried out to evaluate the thermal transitions and degradation of the composites. The mechanoluminescence performance of the printed samples is evaluated by three-point flexural test and observed to depend on processing conditions that can be utilized to achieve a strong light signal at different mechanical loads. The polymer composite fabrication and processing reduced particle size, enhanced particle dispersion, and altered the mechanical properties of the polymer to help increase the mechanoluminescence response up to 10 times in the 3D printed parts. The unique mechanoluminescence properties of 3D printed luminescent composite have great potential for structural monitoring applications.  more » « less
Award ID(s):
1646897 1735968 2215931
PAR ID:
10207962
Author(s) / Creator(s):
; ; ;
Editor(s):
Spearing, M; Tsai, SW; Karbhari, VM
Publisher / Repository:
Sage
Date Published:
Journal Name:
Journal of Composite Materials
Volume:
54
Issue:
22
ISSN:
0021-9983
Page Range / eLocation ID:
3181 to 3188
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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