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1. Surfactant‐mediated mobile droplets on smooth hydrophilic surfaces

   https://doi.org/10.1002/dro2.70004  

   Alipanahrostami, Mohammad; McCoy, Tyler R; Li, Mi; Wang, Wei (April 2025, Droplet)

   Abstract Achieving mobile liquid droplets on solid surfaces is crucial for various practical applications, such as self‐cleaning and anti‐fouling coatings. The last two decades have witnessed remarkable progress in designing functional surfaces, including super‐repellent surfaces and lubricant‐infused surfaces, which allow droplets to roll/slide on the surfaces. However, it remains a challenge to enable droplet motion on hydrophilic solid surfaces. In this work, we demonstrate mobile droplets containing ionic surfactants on smooth hydrophilic surfaces that are charged similarly to surfactant molecules. The ionic surfactant‐laden droplets display ultra‐low contact angle and ultra‐low sliding angle simultaneously on the hydrophilic surfaces. The sliding of the droplet is enabled by the adsorbed surfactant ahead of three‐phase contact line, which is regulated by the electrostatic interaction between ionic surfactant and charged solid surface. The droplet can maintain its motion even when the hydrophilic surface has defects. Furthermore, we demonstrate controlled manipulation of ionic surfactant‐laden droplets on hydrophilic surfaces with different patterns. We envision that our simple technique for achieving mobile droplets on hydrophilic surfaces can pave the way to novel slippery surfaces for different applications. 

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2. Influence of droplet velocity, spacing, and inter-arrival time on line formation and saturation in binder jet additive manufacturing

   https://doi.org/10.1016/j.addma.2020.101711  

   Colton, T; Crane, Nathan B. (January 2021, Additive manufacturing)

   null (Ed.)

   Binder Jetting (BJ) is a low-cost Additive Manufacturing (AM) process that uses inkjet technology to selectively bind particles in a powder bed. BJ relies on the ability to control, not only the placement of binder on the surface but also its imbibition into the powder bed. This is a complex process in which picoliter-sized droplets impact powder beds at velocities of 1–10 m/s. However, the effects of printing parameters such as droplet velocity, size, spacing, and inter-arrival time on saturation level (fraction of pore space filled with binder) and line formation (merging of droplets to form a line) are unknown. Prior attempts to predict saturation levels with simple measurements of droplet primitives and capillary pressure assume that droplet/powder interactions are dominated by static equilibrium and neglect the impact of printing parameters. This study analyzes the influence of these parameters on the effective saturation level and conditions for line formation when printing single lines into powder beds of varied materials (316 stainless steel, 420 stainless steel, and alumina) and varied particle size (d50=10–47 µm). Results show that increasing droplet velocity or droplet spacing decreases effective saturation while droplet spacing, velocity, and inter-arrival time affect line formation. At constant printing velocity, the conditions for successful line printing are shown to be a function of droplet spacing and square root of the droplet inter-arrival time analogous to the Washburn model for infiltration into a porous media. The results have implications to maximizing build rates and improving quality of small features in BJ. 

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3. Low-temperature Leidenfrost-like jumping of sessile droplets on microstructured surfaces

   https://doi.org/10.1038/s41567-024-02522-z  

   Huang, Wenge; Zhao, Lei; He, Xukun; Li, Yang; Collier, C Patrick; Zheng, Zheng; Liu, Jiansheng; Briggs, Dayrl P; Cheng, Jiangtao (May 2024, Nature Physics)

   Verberck, Bart (Ed.)

   The Leidenfrost effect—the levitation and hovering of liquid droplets on hot solid surfaces—generally requires a sufficiently high substrate temperature to activate liquid vaporization. Here we report the modulation of Leidenfrost-like jumping of sessile water microdroplets on micropillared surfaces at a relatively low temperature. Compared to traditional Leidenfrost effect occurring above 230 °C, the fin-array-like micropillars enable water microdroplets to levitate and jump off the surface within milliseconds at a temperature of 130 °C by triggering the inertia-controlled growth of individual vapour bubbles at the droplet base. We demonstrate that droplet jumping, resulting from momentum interactions between the expanding vapour bubble and the droplet, can be modulated by tailoring of the thermal boundary layer thickness through pillar height. This enables regulation of the bubble expansion between the inertia-controlled mode and the heat-transfer-limited mode. The two bubble-growth modes give rise to distinct droplet jumping behaviours characterized by constant velocity and constant energy regimes, respectively. This heating strategy allows the straightforward purging of wetting liquid droplets on rough or structured surfaces in a controlled manner, with potential applications including the rapid removal of fouling media, even when located in surface cavities. 

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4. Fate of Exhaled Droplets From Breathing and Coughing in Supermarket Checkouts and Passenger Cars

   https://doi.org/10.1177/11786302221148274  

   Nishandar, Sanika Ravindra; He, Yucheng; Princevac, Marko; Edwards, Rufus D (January 2023, Environmental Health Insights)

   The global pandemic of COVID-19 has highlighted the importance of understanding the role that exhaled droplets play in virus transmission in community settings. Computational Fluid Dynamics (CFD) enables systematic examination of roles the exhaled droplets play in the spread of SARS-CoV-2 in indoor environments. This analysis uses published exhaled droplet size distributions combined with terminal aerosol droplet size based on measured peak concentrations for SARS-CoV-2 RNA in aerosols to simulate exhaled droplet dispersion, evaporation, and deposition in a supermarket checkout area and rideshare car where close proximity with other individuals is common. Using air inlet velocity of 2 m/s in the passenger car and ASHRAE recommendations for ventilation and comfort in the supermarket, simulations demonstrate that exhaled droplets <20 μm that contain the majority of viral RNA evaporated leaving residual droplet nuclei that remain aerosolized in the air. Subsequently ~ 70% of these droplet nuclei deposited in the supermarket and the car with the reminder vented from the space. The maximum surface deposition of droplet nuclei/m²for speaking and coughing were 2 and 819, 18 and 1387 for supermarket and car respectively. Approximately 15% of the total exhaled droplets (aerodynamic diameters 20-700 µm) were deposited on surfaces in close proximity to the individual. Due to the non-linear distribution of viral RNA across droplet sizes, however, these larger exhaled droplets that deposit on surfaces have low viral content. Maximum surface deposition of viral RNA was 70 and 1.7 × 10³virions/m²for speaking and 2.3 × 10⁴and 9.3 × 10⁴virions/m²for coughing in the supermarket and car respectively while the initial airborne concentration of viral RNA was 7 × 10⁶copies per ml. Integrating the droplet size distributions with viral load distributions, this study helps explain the apparent importance of inhalation exposures compared to surface contact observed in the pandemic. 

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5. PIV AND HIGH-SPEED IMAGING INVESTIGATION OF FALLING LIQUID DROPLET PROPERTIES

   Azimy, N; Lichty, E; Anderson, K; Karimi, S (July 2024, Proceedings of the ASME 2024 Fluids Engineering Division Summer Meeting)

   Liquid droplet impact is a subject that has been investigated in both engineering and non-engineering applications to understand and to control this phenomenon. Spray cooling, ink-jet printing, spray coating and painting, soil erosion prevention, pesticide application, and impact erosion are merely a few examples in which droplet impact is involved. Erosion caused by droplet impact on a solid surface is important in numerous elements of industrial equipment, such as pipelines, steam turbines, and wind turbine blades. Though experimental and modeling studies have been performed on this topic, most failed to perform quantitative investigation especially when it came to the erosion of wind turbine blades. Moreover, most approaches assume that the impacting droplets are completely spherical and unaffected by any local turbulence or vortex shedding. As the droplet erosion process could be affected by several parameters, such as the impact velocity, shape and size of the droplets, this study focuses on investigating droplet properties and movement in a controlled lab environment. High speed imaging and Particle Image Velocimetry (PIV) methods are used for this purpose. PIV is used to measure the velocity, circularity, and size of the falling droplets in both disturbed and un-disturbed flow conditions. High-speed camera imaging provides additional insight to the path of the droplets’ movement in the presence of any turbulence. Experiments are performed at a variety of flow rates utilizing a range of blunt needle gauge sizes to create different droplet sizes. It is observed that the blunt needles produce a train of droplets that are different in size following each leading droplet. This is a crucial observation as it will have a direct impact on the magnitude of erosion and should be considered in the future modeling efforts. 

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