Abstract Achieving mobile liquid droplets on solid surfaces is crucial for various practical applications, such as self‐cleaning and anti‐fouling coatings. The last two decades have witnessed remarkable progress in designing functional surfaces, including super‐repellent surfaces and lubricant‐infused surfaces, which allow droplets to roll/slide on the surfaces. However, it remains a challenge to enable droplet motion on hydrophilic solid surfaces. In this work, we demonstrate mobile droplets containing ionic surfactants on smooth hydrophilic surfaces that are charged similarly to surfactant molecules. The ionic surfactant‐laden droplets display ultra‐low contact angle and ultra‐low sliding angle simultaneously on the hydrophilic surfaces. The sliding of the droplet is enabled by the adsorbed surfactant ahead of three‐phase contact line, which is regulated by the electrostatic interaction between ionic surfactant and charged solid surface. The droplet can maintain its motion even when the hydrophilic surface has defects. Furthermore, we demonstrate controlled manipulation of ionic surfactant‐laden droplets on hydrophilic surfaces with different patterns. We envision that our simple technique for achieving mobile droplets on hydrophilic surfaces can pave the way to novel slippery surfaces for different applications.
more »
« less
Consistent optical surface inspection based on open environment droplet size-controlled condensation figures
Condensation figure (CF) is a simple and cost-effective method to inspect patterns and defects on product surfaces. This inspection method is based on energy differentials on surfaces. Due to wettability contrast, water droplets are preferentially nucleated and grown on hydrophilic regions. The formed CF can further be segmented for the recognition and measurement of the patterns on the surfaces. The state-of-the-art CF methods are closeenvironmental, while controlled open-environmental CF has broader applications in manufacturing and quality inspection. The lack of open-environmental CF for such applications is mostly because of the unavailable droplet size control methods. In this paper, we designed a high-resolution optical surface inspection system based on open environment droplet-size-controlled CFs. This is done by real-time imaging and recognizing the condensed droplet sizes and densities on surfaces, and accordingly tuning the vaporization and evaporation of droplets on the surface by the vapor flow rate. Our experimental results show that the average diameter of droplets can be controlled below 3.5 µm in a laboratory setup for different metal substrates. We also test the system for inspecting self-assembled monolayer patterns with linewidth of 5 µm on a gold surface; this can be promisingly used for online quality monitoring and in-process control of printed patterns in flexible devices manufacturing.
more »
« less
- Award ID(s):
- 1916866
- PAR ID:
- 10265911
- Date Published:
- Journal Name:
- Measurement Science and Technology
- ISSN:
- 0957-0233
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
null (Ed.)Binder Jetting (BJ) is a low-cost Additive Manufacturing (AM) process that uses inkjet technology to selectively bind particles in a powder bed. BJ relies on the ability to control, not only the placement of binder on the surface but also its imbibition into the powder bed. This is a complex process in which picoliter-sized droplets impact powder beds at velocities of 1–10 m/s. However, the effects of printing parameters such as droplet velocity, size, spacing, and inter-arrival time on saturation level (fraction of pore space filled with binder) and line formation (merging of droplets to form a line) are unknown. Prior attempts to predict saturation levels with simple measurements of droplet primitives and capillary pressure assume that droplet/powder interactions are dominated by static equilibrium and neglect the impact of printing parameters. This study analyzes the influence of these parameters on the effective saturation level and conditions for line formation when printing single lines into powder beds of varied materials (316 stainless steel, 420 stainless steel, and alumina) and varied particle size (d50=10–47 µm). Results show that increasing droplet velocity or droplet spacing decreases effective saturation while droplet spacing, velocity, and inter-arrival time affect line formation. At constant printing velocity, the conditions for successful line printing are shown to be a function of droplet spacing and square root of the droplet inter-arrival time analogous to the Washburn model for infiltration into a porous media. The results have implications to maximizing build rates and improving quality of small features in BJ.more » « less
-
Verberck, Bart (Ed.)The Leidenfrost effect—the levitation and hovering of liquid droplets on hot solid surfaces—generally requires a sufficiently high substrate temperature to activate liquid vaporization. Here we report the modulation of Leidenfrost-like jumping of sessile water microdroplets on micropillared surfaces at a relatively low temperature. Compared to traditional Leidenfrost effect occurring above 230 °C, the fin-array-like micropillars enable water microdroplets to levitate and jump off the surface within milliseconds at a temperature of 130 °C by triggering the inertia-controlled growth of individual vapour bubbles at the droplet base. We demonstrate that droplet jumping, resulting from momentum interactions between the expanding vapour bubble and the droplet, can be modulated by tailoring of the thermal boundary layer thickness through pillar height. This enables regulation of the bubble expansion between the inertia-controlled mode and the heat-transfer-limited mode. The two bubble-growth modes give rise to distinct droplet jumping behaviours characterized by constant velocity and constant energy regimes, respectively. This heating strategy allows the straightforward purging of wetting liquid droplets on rough or structured surfaces in a controlled manner, with potential applications including the rapid removal of fouling media, even when located in surface cavities.more » « less
-
Abstract In order to improve the quality of products during additive manufacturing, we developed a novel freezing sublimation-based method for inkjet-based three-dimensional (3D) printing technology, which can significantly improve the uniformity of material distribution in printed products. In our previous studies, we used a laboratory prototype with single droplets of inkjet solution containing colloidal particles to prove the concept of this study. However, understanding the interaction between droplets on the printing substrate surface is also crucial for determining the printing resolution and accuracy of this method, which cannot be fully investigated through single droplet-based experimental studies. To fill this knowledge gap, we conducted a series of experiments on colloidal droplet impingement, freezing, and sublimation on substrates using dual droplets. The experimental setup allowed the release of two droplets in quick succession from a modified nozzle with two needles. These droplets coalesced on the substrate surface due to spreading during their impingement processes. Observations revealed that the coalescence pattern of these two droplets varied depending on the time interval between their release. When the second droplet was released immediately after the first, their coalescence was governed by fluid dynamics. However, when the second droplet was released after the first droplet had frozen on the substrate, it spread above the ice surface of the first droplet in a relatively slower process. This observation provides new insights for the continued study and optimization of the proposed novel freezing sublimation-based 3D printing method.more » « less
-
Liquid droplet impact is a subject that has been investigated in both engineering and non-engineering applications to understand and to control this phenomenon. Spray cooling, ink-jet printing, spray coating and painting, soil erosion prevention, pesticide application, and impact erosion are merely a few examples in which droplet impact is involved. Erosion caused by droplet impact on a solid surface is important in numerous elements of industrial equipment, such as pipelines, steam turbines, and wind turbine blades. Though experimental and modeling studies have been performed on this topic, most failed to perform quantitative investigation especially when it came to the erosion of wind turbine blades. Moreover, most approaches assume that the impacting droplets are completely spherical and unaffected by any local turbulence or vortex shedding. As the droplet erosion process could be affected by several parameters, such as the impact velocity, shape and size of the droplets, this study focuses on investigating droplet properties and movement in a controlled lab environment. High speed imaging and Particle Image Velocimetry (PIV) methods are used for this purpose. PIV is used to measure the velocity, circularity, and size of the falling droplets in both disturbed and un-disturbed flow conditions. High-speed camera imaging provides additional insight to the path of the droplets’ movement in the presence of any turbulence. Experiments are performed at a variety of flow rates utilizing a range of blunt needle gauge sizes to create different droplet sizes. It is observed that the blunt needles produce a train of droplets that are different in size following each leading droplet. This is a crucial observation as it will have a direct impact on the magnitude of erosion and should be considered in the future modeling efforts.more » « less
An official website of the United States government

