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  • A non-luminescent polymorph of [(cyclohexyl isocyanide) 2 Au]PF 6 that becomes luminescent upon grinding or exposure to dichloromethane vapor
Title: A non-luminescent polymorph of [(cyclohexyl isocyanide) 2 Au]PF 6 that becomes luminescent upon grinding or exposure to dichloromethane vapor
The discovery of a third, non-luminescent crystalline polymorph of [(C 6 H 11 NC) 2 Au]PF 6 is reported. Remarkably, crystals of this polymorph are sensitive to mechanical pressure or to exposure to dichloromethane vapor. In both cases, the conversion produces the yellow, green luminescent polymorph of [(C 6 H 11 NC) 2 Au]PF 6 and not the colorless, blue luminescent polymorph.  more » « less
Award ID(s):
1807637
PAR ID:
10272478
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
57
Issue:
6
ISSN:
1359-7345
Page Range / eLocation ID:
793 to 796
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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  1. ; ; ; ; ; (, Chemical Science)
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  2. ; ; ; ; ; (, Dalton Transactions)
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  3. ; ; ; ; ; ; ; ; (, Dalton Transactions)
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  4. ; ; (, IUCrData)
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