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1. Spectroscopic study of the 4 f 7 6 s 2 8 S 7/2∘−4 f 7 ( 8 S ∘ )6 s 6 p ( 1 P ∘ ) 8 P 9/2 transition in neutral europium-151 and europium-153: absolute frequency and hyperfine structure

   https://doi.org/10.1364/JOSAB.467968  

   Herd, M_T ; Maruko, C. ; Herzog, M_M ; Brand, A. ; Cannon, G. ; Duah, B. ; Hollin, N. ; Karani, T. ; Wallace, A. ; Whitmore, M. ; et al ( September 2022 , Journal of the Optical Society of America B)

   We report on spectroscopic measurements on the$4f^{7}6s^2{}^8{S}_{7/2}^{\circ <\#comment/>}\to <\#comment/>4f^7{(}^8{S}^{\circ <\#comment/>})6s6p{(}^1{P}^{\circ <\#comment/>}){}^8{P}_{9/2}$transition in neutral europium-151 and europium-153 at 459.4 nm. The center of gravity frequencies for the 151 and 153 isotopes, reported for the first time in this paper, to our knowledge, were found to be 652,389,757.16(34) MHz and 652,386,593.2(5) MHz, respectively. The hyperfine coefficients for the$6s6p{(}^1{P}^{\circ <\#comment/>}){}^8{P}_{9/2}$state were found to be$\mathrm{A}(151)=-<\#comment/>228.84(2)\mathrm{M}\mathrm{H}\mathrm{z}$,$\mathrm{B}(151)=226.9(5)\mathrm{M}\mathrm{H}\mathrm{z}$and$\mathrm{A}(153)=-<\#comment/>101.87(6)\mathrm{M}\mathrm{H}\mathrm{z}$,$\mathrm{B}(153)=575.4(1.5)\mathrm{M}\mathrm{H}\mathrm{z}$, which all agree with previously published results except for A(153), which shows a small discrepancy. The isotope shift is found to be 3163.8(6) MHz, which also has a discrepancy with previously published results.

    

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2. [La(η x -B x )La] − ( x = 7–9): a new class of inverse sandwich complexes

   https://doi.org/10.1039/c8sc05443f  

   Chen, Teng-Teng ; Li, Wan-Lu ; Li, Jun ; Wang, Lai-Sheng ( February 2019 , Chemical Science)

   Despite the importance of bulk lanthanide borides, nanoclusters of lanthanide and boron have rarely been investigated. Here we show that lanthanide–boron binary clusters, La 2 B x − , can form a new class of inverse-sandwich complexes, [Ln(η x -B x )Ln] − ( x = 7–9). Joint experimental and theoretical studies reveal that the monocyclic B x rings in the inverse sandwiches display similar bonding, consisting of three delocalized σ and three delocalized π bonds. Such monocyclic boron rings do not exist for bare boron clusters, but they are stabilized by the sandwiching lanthanide atoms. An electron counting rule is proposed to predict the sizes of the B x ring that can form stable inverse sandwiches. A unique (d-p)δ bond is found to play important roles in the stability of all three inverse-sandwich complexes. 

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3. Layered and Cubic Semiconductors A Ga M ′ Q 4 ( A + = K + , Rb + , Cs + , Tl + ; M ′ 4+ = Ge 4+ , Sn 4+ ; Q 2– = S 2– , Se 2– ) and High Third-Harmonic Generation

   https://doi.org/10.1021/jacs.0c08638  

   Friedrich, Daniel ; Byun, Hye Ryung ; Hao, Shiqiang ; Patel, Shane ; Wolverton, Chris ; Jang, Joon Ik ; Kanatzidis, Mercouri G. ( October 2020 , Journal of the American Chemical Society)

   null (Ed.)
4. Interpretation of the Na + Ionic Conductivity in Na 4 P 2 S 7–x O x Mixed Oxy-Sulfide Glasses: Effects of Oxygen Doping

   https://doi.org/10.1021/acs.chemmater.2c01934  

   Kmiec, Steven ; Olson, Madison ; Kenney, Matthew ; Martin, Steve W. ( November 2022 , Chemistry of Materials)
5. Synthesis of N4 ‐Methylcytidine (m 4 C) and N4,N4‐ Dimethylcytidine (m 4 2 C) Modified RNA

   https://doi.org/10.1002/cpz1.248  

   Zheng, Ya Ying ; Mao, Song ; Sheng, Jia ( September 2021 , Current Protocols)