A theoretical analysis on crack formation and propagation was performed based on the coupling between the electrochemical process, classical elasticity, and fracture mechanics. The chemical potential of oxygen, thus oxygen partial pressure, at the oxygen electrode-electrolyte interface (
We have discovered a peculiar form of fracture that occurs in polymer network formed by covalent adaptable bonds. Due to the dynamic feature of the bonds, fracture of this network is rate dependent, and the crack propagates in a highly nonsteady manner. These phenomena cannot be explained by the existing fracture theories, most of which are based on steady-state assumption. To explain these peculiar characteristics, we first revisit the fundamental difference between the transient network and the covalent network in which we highlighted the transient feature of the cracks. We extend the current fracture criterion for crack initiation to a time-evolution scheme that allows one to track the nonsteady propagation of a crack. Through a combined experimental modeling effort, we show that fracture in transient networks is governed by two parameters: the Weissenberg number
- Award ID(s):
- 1761918
- NSF-PAR ID:
- 10275946
- Publisher / Repository:
- Proceedings of the National Academy of Sciences
- Date Published:
- Journal Name:
- Proceedings of the National Academy of Sciences
- Volume:
- 118
- Issue:
- 29
- ISSN:
- 0027-8424
- Page Range / eLocation ID:
- Article No. e2105974118
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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) was investigated as a function of transport properties, electrolyte thickness and operating conditions (e.g., steam concentration, constant current, and constant voltage). Our analysis shows that: a lower ionic area specific resistance (ASR), and a higher electronic ASR ( ) of the oxygen electrode/electrolyte interface are in favor of suppressing crack formation. The thus local pO2, are sensitive towards the operating parameters under galvanostatic or potentiostatic electrolysis. Constant current density electrolysis provides better robustness, especially at a high current density with a high steam content. While constant voltage electrolysis leads to greater variations of Constant current electrolysis, however, is not suitable for an unstable oxygen electrode because can reach a very high value with a gradually increased A crack may only occur under certain conditions when -
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