An official website of the United States government
We carry out Monte Carlo simulations on fluid membranes with orientational order and multiple edges in the presence and absence of external forces. The membrane resists bending and has an edge tension, the orientational order couples with the membrane surface normal through a cost for tilting, and there is a chiral liquid crystalline interaction. In the absence of external forces, a membrane initialized as a vesicle will form a disk at low chirality, with the directors forming a smectic-A phase with alignment perpendicular to the membrane surface except near the edge. At large chirality a catenoid-like shape or a trinoid-like shape is formed, depending on the number of edges in the initial vesicle. This shape change is accompanied by cholesteric ordering of the directors and multiple p walls connecting the membrane edges and wrapping around the membrane neck. If the membrane is initialized instead in a cylindrical shape and stretched by an external force, it maintains a nearly cylindrical shape but additional liquid crystalline phases appear. For large tilt coupling and low chirality, a smectic-A phase forms where the directors are normal to the surface of the membrane. For lower values of the tilt coupling, a nematic phase appears at zero chirality with the average director oriented perpendicular to the long axis of the membrane, while for nonzero chirality a cholesteric phase appears. The p walls are tilt walls at low chirality and transition to twist walls as chirality is increased. We construct a continuum model of the director field to explain this behavior.
more »
« less
Deformation and orientational order of chiral membranes with free edges
Motivated by experiments on colloidal membranes composed of chiral rod-like viruses, we use Monte Carlo methods to simulate these systems and determine the phase diagram for the liquid crystalline order of the rods and the membrane shape. We generalize the Lebwohl–Lasher model for a nematic with a chiral coupling to a curved surface with edge tension and a resistance to bending, and include an energy cost for tilting of the rods relative to the local membrane normal. The membrane is represented by a triangular mesh of hard beads joined by bonds, where each bead is decorated by a director. The beads can move, the bonds can reconnect and the directors can rotate at each Monte Carlo step. When the cost of tilt is small, the membrane tends to be flat, with the rods only twisting near the edge for low chiral coupling, and remaining parallel to the normal in the interior of the membrane. At high chiral coupling, the rods twist everywhere, forming a cholesteric state. When the cost of tilt is large, the emergence of the cholesteric state at high values of the chiral coupling is accompanied by the bending of the membrane into a saddle shape. Increasing the edge tension tends to flatten the membrane. These results illustrate the geometric frustration arising from the inability of a surface normal to have twist.
more »
« less
- PAR ID:
- 10279289
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 17
- Issue:
- 27
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 6580 to 6588
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Using a combination of theory and experiments we study the interface between two immiscible domains in a colloidal membrane composed of rigid rods of different lengths. Geometric considerations of rigid rod packing imply that a domain of sufficiently short rods in a background membrane of long rods is more susceptible to twist than the inverse structure, a long-rod domain in a short-rod membrane background. The tilt at the inter-domain edge forces splay, which in turn manifests as a spontaneous edge curvature whose energetics are controlled by the length asymmetry of constituent rods. A thermodynamic model of such tilt-curvature coupling at inter-domain edges explains a number of experimental observations, including a non-monotonic dependence of the edge twist on the domain radius, and annularly shaped domains of long rods. Our work shows how coupling between orientational and compositional degrees of freedom in two-dimensional fluids give rise to complex shapes and thermodynamics of domains, analogous to shape transitions in 3D fluid vesicles.more » « less
-
null (Ed.)Abstract Elastic gridshell is a class of net-like structure formed by an ensemble of elastically deforming rods coupled through joints, such that the structure can cover large areas with low self-weight and allow for a variety of aesthetic configurations. Gridshells, also known as X-shells or Cosserat Nets, are a planar grid of elastic rods in its undeformed configuration. The end points of the rods are constrained and positioned on a closed curve—the final boundary—to actuate the structure into a 3D shape. Here, we report a discrete differential geometry-based numerical framework to study the geometrically nonlinear deformation of gridshell structures, accounting for non-trivial bending-twisting coupling at the joints. The form-finding problem of obtaining the undeformed planar configuration given the target convex 3D topology is then investigated. For the forward (2D to 3D) physically based simulation, we decompose the gridshell structure into multiple one-dimensional elastic rods and simulate their deformation by the well-established discrete elastic rods (DER) algorithm. A simple penalty energy between rods and linkages is used to simulate the coupling between two rods at the joints. For the inverse problem associated with form-finding (3D to 2D), we introduce a contact-based algorithm between the elastic gridshell and a rigid 3D surface, where the rigid surface describes the target shape of the gridshell upon actuation. This technique removes the need of several forward simulations associated with conventional optimization algorithms and provides a direct solution to the inverse problem. Several examples—hemispherical cap, paraboloid, and hemi-ellipsoid—are used to show the effectiveness of the inverse design process.more » « less
-
In lyotropic chromonic liquid crystals (LCLCs), twist distortion of the nematic director costs much less energy than splay or bend distortion. This feature leads to novel mirror-symmetry breaking director configurations when the LCLCs are confined by interfaces or contain suspended particles. Spherical colloids in an aligned LCLC nematic phase, for example, induce chiral director perturbations (“twisted tails”). The asymmetry of rod-like particles in an aligned LCLC offer a richer set of possibilities due to their aspect ratio ( α ) and mean orientation angle (〈 θ 〉) between their long axis and the uniform far-field director. Here we report on the director configuration, equilibrium orientation, and angular diffusion of rod-like particles with planar anchoring suspended in an aligned LCLC. Video microscopy reveals, counterintuitively, that two-thirds of the rods have an angled equilibrium orientation (〈 θ 〉 ≠ 0) that decreases with increasing α , while only one-third of the rods are aligned (〈 θ 〉 = 0). Polarized optical video-microscopy and Landau–de Gennes numerical modeling demonstrate that the angled and aligned rods are accompanied by distinct chiral director configurations. Angled rods have a longitudinal mirror plane (LMP) parallel to their long axis and approximately parallel to the substrate walls. Aligned rods have a transverse and longitudinal mirror plane (TLMP), where the transverse mirror plane is perpendicular to the rod's long axis. Effectively, the small twist elastic constant of LCLCs promotes chiral director configurations that modify the natural tendency of rods to orient along the far-field director. Additional diffusion experiments confirm that rods are angularly confined with strength that depends on α .more » « less
-
Abstract A constant angle of twist was applied to silica glass rods in order to produce a torsional shear strain and a reduction in torque representative of the stress state in the glass was measured as a function of time when rods were heat‐treated in air at temperatures, 550‐700°C, far below the glass transition temperature. The monotonic decrease of torque with time was explained by surface stress relaxation, which can be described by a relaxation of stress at the surface of glass which is promoted by water. The obtained surface stress relaxation diffusion coefficients were consistent with those obtained earlier from silica glass fiber bending under a similar water vapor pressure. The observed relaxation in torsion supports the mechanism of surface stress relaxation over the swelling‐based mechanism for applications including glass fiber strengthening.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/d1sm00629k
