More Like this

1. Wetting Behavior of A -block- (B- random -C) Copolymers with Equal Block Surface Energies on Surfaces Functionalized with B- random -C Copolymers

   https://doi.org/10.1021/acs.langmuir.3c02065  

   Feng, Hongbo; Kash, Benjamin; Yim, Soonmin; Bagchi, Kushal; Craig, Gordon S.; Chen, Wen; Rowan, Stuart J.; Nealey, Paul F. (October 2023, Langmuir)
2. Nanoscale Q -Resolved Phonon Dynamics in Block Copolymers

   https://doi.org/10.1021/acsanm.8b01087  

   Bolmatov, Dima; Zhang, Qi; Soloviov, Dmytro; Li, Yuk Mun; Werner, Jörg G.; Suvorov, Alexey; Cai, Yong Q.; Wiesner, Ulrich; Zhernenkov, Mikhail; Katsaras, John (August 2018, ACS Applied Nano Materials)
3. Ethyl cellulose- block -poly(benzyl glutamate) block copolymer compatibilizers for ethyl cellulose/poly(ethylene terephthalate) blends

   https://doi.org/10.1039/D4PY00688G  

   Chinn, Abigail F; Trindade_Coutinho, Isabela; Kethireddy, Saipranavi Reddy; Williams, Noah R; Knott, Kenneth M; Moore, Robert B; Matson, John B (August 2024, Polymer Chemistry)

   Luscombe, Christine; Anastasaki, Athina; Du_Prez, Filip; Frey, Holger; Hu, Rongrong; Klausen, Rebekka; Konkolewicz; Li, Zhibo; Li, Zi_Chen; Sardon, Haritz (Ed.)

   A block copolymer with the structure ethylcellulose-block-poly(benzy glutamate) was synthesizedviaring-opening polymerization and used as a compatibilizer to produce blends of ethylcellulose and poly(ethylene terephthalate). 

   more » « less
4. High- χ , low- N micelles from partially perfluorinated block polymers

   https://doi.org/10.1039/d2sm00513a  

   Williams, Eric R.; van den Bergh, Wessel; Stefik, Morgan (October 2022, Soft Matter)

   Kinetically trapped (“persistent”) micelles enable emerging applications requiring a constant core diameter. Preserving a χN barrier to chain exchange with low- N requires a commensurately higher χ core–solvent for micelle persistence. Low- N , high- χ micelles containing fluorophobic interactions were studied using poly(ethylene oxide- b -perfluorooctyl acrylate)s (O 45 F X , x = 8, 11) in methanolic solutions. DLS analysis of micelles revealed chain exchange only for O 45 F 8 while SAXS analysis suggested elongated core block conformations commensurate with the contour lengths. Micelle chain exchange from solution perturbations were examined by characterizing their behavior as templates for inorganic materials via SAXS and SEM. In contrast to the F 8 analog, the larger χN barrier for the O 45 F 11 enabled persistent micelle behavior in both thin films and bulk samples despite the low T g micelle core. Careful measures of micelle core diameters and pore sizes revealed that the nanoparticle distribution extended through the corona and 0.52 ± 0.15 nm into the core–corona interface, highlighting thermodynamics favoring both locations simultaneously. 

   more » « less
5. RALF peptide signaling controls the polytubey block in Arabidopsis

   https://doi.org/10.1126/science.abl4683  

   Zhong, Sheng; Li, Ling; Wang, Zhijuan; Ge, Zengxiang; Li, Qiyun; Bleckmann, Andrea; Wang, Jizong; Song, Zihan; Shi, Yihao; Liu, Tianxu; et al (January 2022, Science)

   Signaling between pollen tube and female gametophyte ensures that only one pollen tube gets through but can re-establish access in case of failure. 

   more » « less