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1. Discovery of Super-enriched Gas ∼1 Gyr after the Big Bang

   Huyan, J; Kulkarni, V P; Poudel, S; Tejos, N; Peroux, C; Lopez, S (September 2023, The astrophysical journal Letters)

   Abundances of chemical elements in the interstellar and circumgalactic media of high-redshift galaxies offer important constraints on the nucleosynthesis by early generations of stars. Damped Lyα absorbers (DLAs) in spectra of high-redshift background quasars are excellent sites for obtaining robust measurements of element abundances in distant galaxies. Past studies of DLAs at redshifts z > 4 have measured abundances of 0.01 solar. Here we report the discovery of a DLA at z = 4.7372 with an exceptionally high degree of chemical enrichment. We estimate the H I column density in this absorber to be log (NH I/cm^−2) = 20.48 ± 0.15. Our analysis shows unusually high abundances of carbon and oxygen ([C/H] = 0.88 ± 0.17, [O/H] = 0.71 ± 0.16). Such a high level of enrichment a mere 1.2 Gyr after the Big Bang is surprising because of insufficient time for the required amount of star formation. To our knowledge, this is the first supersolar absorber found at z > 4.5. We find the abundances of Si and Mg to be [Si/H] = -0.56-0.35+0.40 and [Mg/H] = -0.59-0.50+0.27, confirming the metal-rich nature of this absorber. By contrast, Fe shows a much lower abundance ([Fe/H] = -1.53 ± 0.15). We discuss implications of our results for galactic chemical evolution models. The metallicity of this absorber is higher than that of any other known DLA and is >2 orders of magnitude above predictions of chemical evolution models and the NH I-weighted mean metallicity from previous studies at z > 4.5. The relative abundances (e.g., [O/Fe] = 2.29 ± 0.05, [C/Fe] = 2.46 ± 0.08) are also highly unusual compared to predictions for enrichment by early stars. 

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2. The Diversity of Metal Enrichment and Abundance Patterns at High Redshift: A Magellan Survey of Gas-rich Galaxies Traced by Damped Ly α Absorbers at z  ∼ 5

   https://doi.org/10.3847/1538-4357/adf63e  

   Huyan, J; Kulkarni, V P; Poudel, S; Tejos, N; Péroux, C; Lopez, S (September 2025, The Astrophysical Journal)

   A powerful technique to trace the signatures of the first stars is through the metal enrichment in concentrated reservoirs of hydrogen, such as the damped Lyα absorbers (DLAs) in the early Universe. We conducted a survey aimed at discovering DLAs along sight lines to high-z quasars in order to measure element abundances at z > 4. Here we report our first results from this survey for 10 DLAs with redshifts of ≈4.2–5.0. We determine abundances of C, O, Si, S, and Fe, and thereby the metallicities and dust depletions. We find that DLA metallicities at z > 4.5 show a wide diversity spanning ∼3 orders of magnitude. The metallicities of DLAs at 3.7 < z < 5.3 show a larger dispersion compared to that at lower redshifts. Combining our sample with the literature, we find a relatively smooth evolution of metallicity with redshift out to z ∼ 5.3, with a tentative (∼2 sigma) indication of a slight rise in metallicity at 4.5 < z < 5.3. The relative abundances exhibit C enhancement for both metal-poor and metal-enriched DLAs. In addition, α-element enhancement is evident in some DLAs, including a DLA at z = 4.7 with a supersolar metallicity. Comparing [C/O] and [Si/O] with model predictions, four DLAs in our survey seem consistent with a nonzero Population III contribution (three with >~30% Population III contribution). Combining our sample and the literature, we find the dust depletion strength and dust-to-metal ratios to correlate positively with the total (gas+solid phase) metallicity, confirming the presence of metal-rich, dusty DLAs even at ∼1 billion years after the Big Bang. 

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3. The dust-to-gas mass ratio of luminous galaxies as a function of their metallicity at cosmic noon

   Popping, Gergö; Shivaei, Irene; Sanders, Ryan L.; Jones, Tucker; Pope, Alexandra; Reddy, Naveen A.; Shapley, Alice E.; Coil, Alison L.; Kriek, Mariska (February 2023, Astronomy & Astrophysics)

   Aims. We aim to quantify the relation between the dust-to-gas mass ratio (DTG) and gas-phase metallicity of z  = 2.1 − 2.5 luminous galaxies and contrast this high-redshift relation against analogous constraints at z  = 0. Methods. We present a sample of ten star-forming main-sequence galaxies in the redshift range 2.1 <  z  < 2.5 with rest-optical emission-line information available from the MOSDEF survey and with ALMA 1.2 millimetre and CO J  = 3 − 2 follow-up observations. The galaxies have stellar masses ranging from 10 10.3 to 10 10.6   M ⊙ and cover a range in star-formation rate from 35 to 145 M ⊙ yr −1 . We calculated the gas-phase oxygen abundance of these galaxies from rest-optical nebular emission lines (8.4 < 12 + log(O/H) < 8.8, corresponding to 0.5−1.25 Z ⊙ ). We estimated the dust and H 2 masses of the galaxies (using a metallicity-dependent CO-to-H 2 conversion factor) from the 1.2 mm and CO J  = 3 − 2 observations, respectively, from which we estimated a DTG. Results. We find that the galaxies in this sample follow the trends already observed between CO line luminosity and dust-continuum luminosity from z  = 0 to z  = 3, extending such trends to fainter galaxies at 2.1 <  z  < 2.5 than observed to date. We find no second-order metallicity dependence in the CO – dust-continuum luminosity relation for the galaxies presented in this work. The DTGs of main-sequence galaxies at 2.1 <  z  < 2.5 are consistent with an increase in the DTG with gas-phase metallicity. The metallicity dependence of the DTG is driven by the metallicity dependence of the CO-to-H 2 conversion factor. Galaxies at z  = 2.1 − 2.5 are furthermore consistent with the DTG-metallicity relation found at z  = 0 (i.e. with no significant evolution), providing relevant constraints for galaxy formation models. These results furthermore imply that the metallicity of galaxies should be taken into account when estimating cold-gas masses from dust-continuum emission, which is especially relevant when studying metal-poor low-mass or high-redshift galaxies. 

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4. A [C ii ] 158 μ m Survey of Damped Lyα Absorber Galaxies at z  ∼ 4: Observations of Dense and Metal-enriched Neutral Gas within the Circumgalactic Medium of Star-forming Galaxies

   https://doi.org/10.3847/1538-4357/adbbd1  

   Neeleman, Marcel; Kanekar, Nissim; Prochaska, J Xavier; Rafelski, Marc A; Kahinga, Lordrick A (April 2025, The Astrophysical Journal)

   Abstract We present a survey undertaken with the Atacama Large Millimeter/submillimeter Array (ALMA) to study the galaxies associated with a representative sample of 16 damped Lyαabsorbers (DLAs) atz ≈ 4.1–4.5, using the [Cii] 158μm ([Cii]) line. We detect seven [Cii]-emitting galaxies in the fields of five DLAs, all of which have absorption metallicity [M/H] > −1.5. We find that the detectability of these Hi-selected galaxies with ALMA is a strong function of DLA metallicity, with a detection rate of $71_{-20}^{+11}$% for DLAs with [M/H] > −1.5 and 0⁺¹⁸% for DLAs with [M/H] < −1.5. The identified DLA galaxies have far-IR properties similar to those of typical star-forming galaxies atz ∼ 4, with estimated obscured star formation rates ranging from ≲6M_⊙yr⁻¹to 110M_⊙yr⁻¹. High-metallicity DLAs therefore provide an efficient way to identify and study samples of high-redshift, star-forming galaxies, without preselecting the galaxies by their emission properties. The agreement between the velocities of the metal absorption lines of the DLA and the [Cii] emission line of the DLA galaxy indicates that the metals within the DLA originated in the galaxy. With observed impact parameters between 14 and 59 kpc, this indicates that star-forming galaxies atz ∼ 4 have a substantial reservoir of dense, cold, neutral gas within their circumgalactic medium that has been enriched with metals from the galaxy. 

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5. A Massive, Dusty, Hi Absorption–Selected Galaxy at z ≈ 2.46 Identified in a CO Emission Survey

   https://doi.org/10.3847/1538-4357/ac7b2c  

   Kaur, B.; Kanekar, N.; Revalski, M.; Rafelski, M.; Neeleman, M.; Prochaska, J. X.; Walter, F. (July 2022, The Astrophysical Journal)

   Abstract We report a NOrthern Extended Millimeter Array (NOEMA) and Atacama Large Millimeter/submillimeter Array search for redshifted CO emission from the galaxies associated with seven high-metallicity ([M/H] ≥ −1.03) damped Lyαabsorbers (DLAs) atz≈ 1.64–2.51. Our observations yielded one new detection of CO(3–2) emission from a galaxy atz= 2.4604 using NOEMA, associated with thez= 2.4628 DLA toward QSO B0201+365. Including previous searches, our search results in detection rates of CO emission of $\approx {56}_{-24}^{+38}$% and $\approx {11}_{-9}^{+26}$%, respectively, in the fields of DLAs with [M/H] > −0.3 and [M/H] < −0.3. Further, the Hi–selected galaxies associated with five DLAs with [M/H] > −0.3 all have high molecular gas masses, ≳5 × 10¹⁰M_⊙. This indicates that the highest-metallicity DLAs atz≈ 2 are associated with the most massive galaxies. The newly identifiedz≈ 2.4604 Hi–selected galaxy, DLA0201+365g, has an impact parameter of ≈7 kpc to the QSO sightline, and an implied molecular gas mass of (5.04 ± 0.78) × 10¹⁰× (α_CO/4.36) × (r₃₁/0.55)M_⊙. Archival Hubble Space Telescope Wide Field and Planetary Camera 2 imaging covering the rest-frame near-ultraviolet (NUV) and far-ultraviolet (FUV) emission from this galaxy yield nondetections of rest-frame NUV and FUV emission, and a 5σupper limit of 2.3M_⊙yr⁻¹on the unobscured star formation rate (SFR). The low NUV-based SFR estimate, despite the very high molecular gas mass, indicates that DLA0201+365g either is a very dusty galaxy, or has a molecular gas depletion time that is around 2 orders of magnitude larger than that of star-forming galaxies at similar redshifts. 

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