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1. Acadian, Neo-Acadian, and Alleghenian tectonic reactivation of Taconic thrusts in the northern New England Appalachians

   Webb, LE; Karabinos, P; Long, M; Khadka, S (January 2024, Geological Society of America Abstracts with Programs)

   We present results of integrated 40Ar/39Ar geochronology and microstructural analyses of samples from Taconic thrust faults of the northern New England Appalachians that provide evidence for reactivation during the Acadian, Neo-Acadian, and Alleghenian orogenies. 40Ar/39Ar ages c. 420 Ma from western frontal thrusts of the Green Mountains and Berkshire Massif have been interpreted previously to reflect partial resetting of Taconic ages during Acadian metamorphism. In Massachusetts and southern Vermont, these W-directed thrusts transport Grenville basement and its cover sequences over Cambrian-to-Ordovician phyllites and graphitic schists. Our recent investigations of these faults, however, yield a suite of c. 420 Ma 40Ar/39Ar ages obtained from syn-tectonic mica in mylonites and footwall schist/phyllite that are interpreted, rather, to reflect a pulse of W-directed thrusting. This interpretation that these ages record the timing of deformation is based, in part, on the preservation of quartz and feldspar dislocation creep microstructures (i.e., lack of evidence for static recrystallization), as well as the regional distribution of these data relative to Acadian metamorphic isograds. These results align with recent findings for the timing of formation of the Green Mountain Anticlinorium in northern Vermont, as well as detrital zircon data that require isolation of the Catskill Basin from the Connecticut Valley-Gaspe Basin (CVGB) at the onset of deposition around that time. Mylonites and samples from the adjacent footwall schists and phyllites also locally record evidence for minor to wholesale resetting c. 355 Ma associated with a younger phase of ductile deformation. Further evidence for partial resetting of 40Ar/39Ar ages c. 250 is associated with hematite-rich seams parallel to the mylonitic foliation and cross-cutting fractures. We explore how these age populations relate to those obtained from, for example, the CVGB and Chester and Athens Domes, and their implications for correlating surface geology with results from seismic imaging of the lithospheric and mantle structure in the northern New England Appalachians. 

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2. RECONSTRUCTING THE PALEOZOIC STRUCTURAL, METAMORPHIC, AND EXHUMATIONAL HISTORY OF THE SOUTHERN APPALACHIAN BLUE RIDGE AND INNER PIEDMONT

   https://doi.org/10.1130/abs/2023SE-385547  

   Thigpen, Ryan; Merschat, Arthur; Hatcher, Robert; Moecher, David; Powell, Nicholas E.; Spencer, Brandon; Stowell, Harold; Bollen, Elizabeth (March 2023, Abstracts Geological Society of America)

   The southern Appalachians preserve evidence for three Paleozoic orogenies that contributed to construction of the composite southern Appalachian orogen, including the Taconic (480-440 Ma), Neoacadian (380-340 Ma), and Alleghanian (330-280 Ma) events. However, the complexity of thermal-metamorphic overprinting and polydeformation has impeded efforts to examine questions related to tectonic processes such as the crustal escape flow hypothesis in the southern Appalachians. To address this, new monazite and xenotime laser ablation split-stream U-Pb and hornblende 40Ar/39Ar dates have been produced for the Blue Ridge (BR) and Inner Piedmont (IP), and these data are being compiled with all previously available geo-thermochronological and quantitative P-T data to construct P-T-t histories for different parts of the orogen. Monazite U-Pb dates from prograde monazites in the North Carolina BR yield a clear Taconic (464-441 Ma) metamorphic signal for conditions up to granulite facies, which is interpreted to result from development of a Taconic accretion-subduction complex. Following the Taconic arcs collision, this part of the BR was cooled during Neoacadian and Alleghanian uplift and exhumation pulses, as indicated by thermochronologic dates spanning a wide range of closure temperatures (~550-220 °C). In the IP and Sauratown Mountains window, U-Pb dates of mostly prograde monazite growth yield a dominant Neoacadian signal (369-358 Ma), which corroborates previous age estimates for IP Barrovian metamorphism up to sillimanite II grade. In the IP, hornblende 40Ar/39Ar ages of 380-345 Ma generally indicate syn-Neoacadian cooling below ~500 °C. In the IP between the Brevard and Brindle Creek fault zones, Y-rich monazites yield younger dates (~330 Ma) that overlap with hornblende 40Ar/39Ar yield ages (335-324 Ma). Combined, these ages are interpreted to reflect post-Neoacadian reactivation and retrogression of the Brevard fault zone and potential folding(?) of the Brindle Creek fault zones during early Alleghanian deformation. This retrograde deformation persists until at least 297 Ma, as reflected by xenotime dates in the Brevard zone (311-297 Ma). Future work will address how the timing and extent of metamorphism, deformation, and exhumation may vary south of the present study area. 

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3. Precambrian to Pleistocene 40Ar/39Ar dating of clinopyroxene-hosted melt inclusions

   https://doi.org/10.1130/G51777.1  

   Jicha, Brian R; Schaen, Allen J; Wathen, Bryan; Nachlas, William O (February 2024, Geology)

   Abstract Clinopyroxene is a rock-forming mineral that commonly hosts melt inclusions in mafic to intermediate composition volcanic and plutonic rocks. It is highly resistant to alteration compared to other co-existing phenocrysts such as plagioclase. Several recent studies have 40Ar/39Ar dated clinopyroxene in Neoproterozoic to Miocene basalts and dolerites. To assess the viability of the technique at the youngest end of the geologic time scale, we performed 40Ar/39Ar incremental heating experiments on clinopyroxene-hosted melt inclusions from a variety of mafic lithologies and tectonic settings. Most samples produced precise plateau ages including several Quaternary basalts to andesites as young as 0.6 Ma. All data are indistinguishable from new and/or published 40Ar/39Ar ages on groundmass or plagioclase from the same samples. The source of potassium (K) and resulting 40Ar* within clinopyroxene has been debated, but thus far has only been inferred based on 40Ar/39Ar data. Using electron probe microanalysis (EPMA) we show that there is negligible K in the clinopyroxene host, but substantial K (e.g., 1–4 wt%) in trapped melt inclusions and minor amounts in plagioclase inclusions. Thus, melt inclusions, which are common in phenocrysts in basaltic magmas, can be used to obtain accurate and precise 40Ar/39Ar ages for difficult-to-date volcanic and plutonic rocks from the Precambrian to the Pleistocene. 

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4. Geochronology of late Albian–Cenomanian strata in the U.S. Western Interior

   https://doi.org/10.1130/B35794.1  

   Singer, Brad S; Jicha, Brian R; Sawyer, David; Walaszczyk, Ireneusz; Buchwaldt, Robert; Mutterlose, Jorg (December 2020, GSA Bulletin)

   Abstract Since the publication of 40Ar/39Ar dates from Cretaceous bentonites in the Western Interior Basin by J.D. Obradovich in 1993 and in Japan by J.D. Obradovich and colleagues in 2002, improvements in the 40Ar/39Ar method have included a shift to astronomically calibrated ages for standard minerals and development of a new generation of multi-collector mass spectrometers. Thus, the 40Ar/39Ar chronometer can yield results that are synchronous with U-Pb zircon dates and astrochronologic age models for Cretaceous strata. Ages determined by Obradovich have ± 2σ analytical uncertainties of ± 400 ka (excluding J value or systematic contributions) that have been used to discriminate stratigraphic events at ca. 1 Ma resolution. From among several dozen sanidine samples, 32 of which were dated by Obradovich in 1993, we present new multi-collector 40Ar/39Ar ages that reduce the average analytical uncertainties by nearly an order of magnitude. These new ages (where the uncertainties also include the contribution of the neutron fluence J value) include: Topmost Bentonite, Mowry Shale, Kaycee, Wyoming, USA, 97.52 ± 0.09 Ma Clay Spur Bentonite, Mowry Shale, Casper, Wyoming, 98.17 ± 0.11 Ma Arrow Creek Bentonite, Colorado Shale, Montana, USA, 99.12 ± 0.14 Ma Upper Newcastle Sandstone, Black Hills, Wyoming, 99.49 ± 0.07 Ma Middle Newcastle Sandstone, Black Hills, Wyoming, 99.58 ± 0.12 Ma Shell Creek Shale, Bighorn Basin, Crow Reservation, Wyoming, 99.62 ± 0.07 Ma Shell Creek Shale, Bighorn Basin, Greybull, Wyoming, 99.67 ± 0.13 Ma Shell Creek Shale, Bighorn Basin, Lander, Montana, 100.07 ± 0.07 Ma Muddy Sandstone, Wind River Basin, Wyoming, 101.23 ± 0.09 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 101.36 ± 0.11 Ma Vaughn Member, Blackleaf Formation, Sweetgrass Arch, Montana, 102.68 ± 0.07 Ma Taft Hill Member, Blackleaf Formation, Sweetgrass Arch, Montana, 103.08 ± 0.11 Ma Base of the Skull Creek Shale, Black Hills, Wyoming, 104.87 ± 0.10 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 106.37 ± 0.11 Ma A new U-Pb zircon age of 104.69 ± 0.07 Ma from the Skull Creek Shale at Dinosaur Ridge, Colorado, USA, is close to the new 40Ar/39Ar age of the Skull Creek Shale in the Black Hills, Wyoming, but 5 m.y. is missing in the unconformity between the Skull Creek Shale of the Black Hills and the overlying Newcastle Sandstone. Considering the average total uncertainties that include decay constant and standard age or tracer composition for the 40Ar/39Ar (± 0.19 Ma) and the U-Pb (± 0.13 Ma) ages does not alter this finding. Moreover, the lower Thermopolis Shale in the Bighorn Basin is 1.5 Ma older than the Skull Creek Shale in the Black Hills. The 100.07 ± 0.07 Ma Shell Creek Bentonite in Montana is close to the Albian–Cenomanian boundary age of 100.2 ± 0.2 Ma of Obradovich and colleagues from Hokkaido, Japan, and 100.5 ± 0.5 Ma adopted in the 2012 geological time scale of J.G. Ogg and L.A. Hinnov. Our findings indicate that correlations based on similarity of lithology, without independent radioisotopic ages or detailed biostratigraphic constraints, can be problematic or invalid. There is much more time missing in unconformities than has been previously recognized in these important, petroleum-bearing reservoir strata. 

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5. ORIGIN OF VOLCANIC-HOSTED MAGNETITE AT THE LAGUNA DEL MAULE COMPLEX, CHILE: A NEW EXAMPLE OF ANDEAN IRON OXIDE-APATITE MINERALIZATION

   https://doi.org/10.5382/econgeo.5093  

   Cofré, Ernesto; Reich, Martin; Tomás_Ovalle, J; Palma, Gisella; Barra, Fernando; Deditius, Artur; Simon, Adam C; Roberts, Malcolm; Jicha, Brian R (September 2024, Economic Geology)

   Iron oxide-apatite (IOA) deposits, also known as magnetite-apatite or Kiruna-type deposits, are a major source of iron and potentially of rare earth elements and phosphorus. To date, the youngest representative of this group is the Pleistocene (~2 Ma) El Laco deposit, located in the Andean Cordillera of northern Chile. El Laco is considered a unique type of IOA deposit because of its young age and its volcanic-like features. Here we report the occurrence of similarly young IOA-type mineralization hosted within the Laguna del Maule Volcanic Complex, an unusually large and recent silicic volcanic system in the south-central Andes. We combined field observations and aerial drone images with detailed petrographic observations, electron microprobe analysis (EMPA), and 40Ar/39Ar dating to characterize the magnetite mineralization—named here “Vetas del Maule”—hosted within andesites of the now extinct La Zorra volcano (40Ar/39Ar plateau age of 1.013 ± 0.028 Ma). Five different styles of magnetite mineralization were identified: (1) massive magnetite, (2) pyroxene-actinolite-magnetite veins, (3) magnetite hydrothermal breccias, (4) disseminated magnetite, and (5) pyroxene-actinolite veins with minor magnetite. Field observations and aerial drone imaging, coupled with microtextural and microanalytical data, suggest a predominantly hydrothermal origin for the different types of mineralization. 40Ar/39Ar incremental heating of phlogopite associated with the magnetite mineralization yielded a plateau age of 873.6 ± 30.3 ka, confirming that the emplacement of Vetas del Maule postdated that of the host andesite rocks. Our data support the hypothesis that the magnetite mineralization formed in a volcanic setting from Fe-rich fluids exsolved from a magma at depth. Ultimately, Vetas del Maule provides evidence that volcanic-related IOA mineralization may be more common than previously thought, opening new opportunities of research and exploration for this ore deposit type in active volcanic arcs. 

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