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Title: Photoreductive chlorine elimination from a Ni( iii )Cl 2 complex supported by a tetradentate pyridinophane ligand
Herein we report the isolation, characterization, and photoreactivity of a stable Ni III dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the Ni III Cl 2 species can be regenerated via a reaction with PhICl 2 .  more » « less
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Date Published:
Journal Name:
Chemical Communications
Page Range / eLocation ID:
7264 to 7267
Medium: X
Sponsoring Org:
National Science Foundation
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