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Title: Photoreductive chlorine elimination from a Ni( iii )Cl 2 complex supported by a tetradentate pyridinophane ligand
Herein we report the isolation, characterization, and photoreactivity of a stable Ni III dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the Ni III Cl 2 species can be regenerated via a reaction with PhICl 2 .  more » « less
Award ID(s):
1925751
NSF-PAR ID:
10293313
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
57
Issue:
59
ISSN:
1359-7345
Page Range / eLocation ID:
7264 to 7267
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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