Paper diagnostics are of growing interest due to their low cost and easy accessibility. Conductive inks, necessary for manufacturing the next generation diagnostic devices, currently face challenges such as high cost, high sintering temperatures, or harsh conditions required to remove stabilizers. Here we report an effective, inexpensive, and environmentally friendly approach to graphene ink that is suitable for screen printing onto paper substrates. The ink formulation contains only pristine graphite, water, and non-toxic alkanes formed by an interfacial trapping method in which graphite spontaneously exfoliates to graphene. The result is a viscous graphene stabilized water-in-oil emulsion-based ink. This ink does not require sintering, but drying at 90 °C or brief microwaving can improve the conductivity. The production requires only 40 s of shaking to form the emulsion. The sheet resistance of the ink is approximately 600 Ω/sq at a thickness of less than 6 µm, and the ink can be stabilized by as little as 1 wt% graphite.
Graphene has transformed the fields of plasmonics and photonics, and become an indispensable component for devices operating in the terahertz to mid-infrared range. Here, for instance, graphene surface plasmons can be excited, and their extreme interfacial confinement makes them vastly effective for sensing and detection. The rapid, robust, and accurate numerical simulation of optical devices featuring graphene is of paramount importance and many groups appeal to Black-Box Finite Element solvers. While accurate, these are quite computationally expensive for problems with simplifying geometrical features such as multiple homogeneous layers, which can be recast in terms of interfacial (rather than volumetric) unknowns. In either case, an important modeling consideration is whether to treat the graphene as a material of small (but non-zero) thickness with an effective permittivity, or as a vanishingly thin sheet of current with an effective conductivity. In this contribution we ponder the correct relationship between the effective conductivity and permittivity of graphene, and propose a new relation which is based upon a concrete mathematical calculation that appears to be missing in the literature. We then test our new model both in the case in which the interface deformation is non-trivial, and when there are two layers of graphene with non-flat interfacial deformation.
more » « less- Award ID(s):
- 1813033
- NSF-PAR ID:
- 10306180
- Publisher / Repository:
- Optical Society of America
- Date Published:
- Journal Name:
- Journal of the Optical Society of America A
- Volume:
- 38
- Issue:
- 10
- ISSN:
- 1084-7529; JOAOD6
- Page Range / eLocation ID:
- Article No. 1511
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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