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1. Designing multicomponent hydrides with potential high T _c superconductivity

   https://doi.org/10.1073/pnas.2413096121  

   Denchfield, Adam; Park, Hyowon; Hemley, Russell J (November 2024, Proceedings of the National Academy of Sciences)

   While hydrogen-rich materials have been demonstrated to exhibit high T_csuperconductivity at high pressures, there is an ongoing search for ternary, quaternary, and more chemically complex hydrides that achieve such high critical temperatures at much lower pressures. First-principles searches are impeded by the computational complexity of solving the Eliashberg equations for large, complex crystal structures. Here, we adopt a simplified approach using electronic indicators previously established to be correlated with superconductivity in hydrides. This is used to study complex hydride structures, which are predicted to exhibit promisingly high critical temperatures for superconductivity. In particular, we propose three classes of hydrides inspired by the Fm $\overline{3}$m RH ${}_3$structures that exhibit strong hydrogen network connectivity, as defined through the electron localization function. The first class [RH ${}_{11}$X ${}_3$Y] is based on a Pm $\overline{3}$m structure showing moderately high T_c, where the T_cestimate from electronic properties is compared with direct Eliashberg calculations and found to be surprisingly accurate. The second class of structures [(RH ${}_{11}$) ${}_2$X ${}_6$YZ] improves on this with promisingly high density of states with dominant hydrogen character at the Fermi energy, typically enhancing T_c. The third class [(R ${}^1$H ${}_{11}$)(R ${}^2$H ${}_{11}$)X ${}_6$YZ] improves the strong hydrogen network connectivity by introducing anisotropy in the hydrogen network through a specific doping pattern. These design principles and associated model structures provide flexibility to optimize both T_cand the structural stability of complex hydrides. 

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2. Observation of a pseudoscalar excess at the top quark pair production threshold

   https://doi.org/10.1088/1361-6633/adf7d3  

   Collaboration, The_CMS (August 2025, Reports on Progress in Physics)

   Abstract A search for resonances in top quark pair ( $\mathrm{t}\bar{\mathrm{t}}$) production in final states with two charged leptons and multiple jets is presented, based on proton–proton collision data collected by the CMS experiment at the CERN LHC at $\sqrt{s}=13\text{TeV}$, corresponding to 138 fb⁻¹. The analysis explores the invariant mass of the $\mathrm{t}\bar{\mathrm{t}}$system and two angular observables that provide direct access to the correlation of top quark and antiquark spins. A significant excess of events is observed near the kinematic $\mathrm{t}\bar{\mathrm{t}}$threshold compared to the non-resonant production predicted by fixed-order perturbative quantum chromodynamics (pQCD). The observed enhancement is consistent with the production of a color-singlet pseudoscalar ( ${}^1{\text{S}}_0^{\left[1\right]}$) quasi-bound toponium state, as predicted by non-relativistic quantum chromodynamics. Using a simplified model for ${}^1{\text{S}}_0^{\left[1\right]}$toponium, the cross section of the excess above the pQCD prediction is measured to be $8.8{}_{-1.4}^{+1.2}\text{pb}$. 

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3. Universal trimers with p-wave interactions and the faux-Efimov effect

   https://doi.org/10.1088/1361-6455/ad987b  

   Chen, Yu-Hsin; Greene, Chris_H (December 2024, Journal of Physics B: Atomic, Molecular and Optical Physics)

   Abstract An unusual class of equal massp-wave universal trimers with symmetry $L^{\mathrm{\Pi }}=1^{\pm }$is identified, for both a two-component fermionic trimer withs- andp-wave scattering length close to unitarity and for a one-component fermionic trimer atp-wave unitarity. Moreover, fermionic trimers made of atoms with two internal spin components are found for $L^{\mathrm{\Pi }}=1^{\pm }$, when thep-wave interaction between spin-up and spin-down fermions is close to unitarity and/or when the interaction between two spin-up fermions is close to thep-wave unitary limit. The universality of thesep-wave universal trimers is tested here by considering van der Waals interactions in a Lennard–Jones potential with different numbers of two-body bound states; our calculations also determine the value of the scattering volume or length where the trimer state hits zero energy and can be observed as a recombination resonance. The faux-Efimov effect appears with trimer symmetry $L^{\mathrm{\Pi }}=1^{-}$when the two fermion interactions are close top-wave unitarity and the lowest $1/R^2$coefficient gets modified, thereby altering the usual Wigner threshold law for inelastic processes involving three-body continuum channels. 

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4. Anomalous quantum criticality in the electron-doped cuprates

   https://doi.org/10.1073/pnas.1817653116  

   Mandal, P. R.; Sarkar, Tarapada; Greene, Richard L. (March 2019, Proceedings of the National Academy of Sciences)

   In the physics of condensed matter, quantum critical phenomena and unconventional superconductivity are two major themes. In electron-doped cuprates, the low critical field (H_C2) allows one to study the putative quantum critical point (QCP) at low temperature and to understand its connection to the long-standing problem of the origin of the high-T_Csuperconductivity. Here we present measurements of the low-temperature normal-state thermopower (S) of the electron-doped cuprate superconductor La_2−xCe_xCuO₄(LCCO) fromx= 0.11–0.19. We observe quantum critical $\mathit{S}/\mathit{T}$versus $\mathbf{l}\mathbf{n}\left(\mathbf{1}/\mathit{T}\right)$behavior over an unexpectedly wide doping rangex= 0.15–0.17 above the QCP (x= 0.14), with a slope that scales monotonically with the superconducting transition temperature (T_Cwith H = 0). The presence of quantum criticality over a wide doping range provides a window on the criticality. The thermopower behavior also suggests that the critical fluctuations are linked withT_C. Above the superconductivity dome, atx= 0.19, a conventional Fermi-liquid $\mathit{S}\propto \mathit{T}$behavior is found for $\mathit{T}\le$40 K. 

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5. Stabilizing Ti ₃ C ₂ T _x MXene flakes in air by removing confined water

   https://doi.org/10.1073/pnas.2400084121  

   Fang, Hui; Thakur, Anupma; Zahmatkeshsaredorahi, Amirhossein; Fang, Zhenyao; Rad, Vahid; Shamsabadi, Ahmad A; Pereyra, Claudia; Soroush, Masoud; Rappe, Andrew M; Xu, Xiaoji G; et al (July 2024, Proceedings of the National Academy of Sciences)

   MXenes have demonstrated potential for various applications owing to their tunable surface chemistry and metallic conductivity. However, high temperatures can accelerate MXene film oxidation in air. Understanding the mechanisms of MXene oxidation at elevated temperatures, which is still limited, is critical in improving their thermal stability for high-temperature applications. Here, we demonstrate that Ti ${}_3$C ${}_2$T ${}_x$MXene monoflakes have exceptional thermal stability at temperatures up to 600 ${}^{°}$C in air, while multiflakes readily oxidize in air at 300 ${}^{°}$C. Density functional theory calculations indicate that confined water between Ti ${}_3$C ${}_2$T ${}_x$flakes has higher removal energy than surface water and can thus persist to higher temperatures, leading to oxidation. We demonstrate that the amount of confined water correlates with the degree of oxidation in stacked flakes. Confined water can be fully removed by vacuum annealing Ti ${}_3$C ${}_2$T ${}_x$films at 600 ${}^{°}$C, resulting in substantial stability improvement in multiflake films (can withstand 600 ${}^{°}$C in air). These findings provide fundamental insights into the kinetics of confined water and its role in Ti ${}_3$C ${}_2$T ${}_x$oxidation. This work enables the use of stable monoflake MXenes in high-temperature applications and provides guidelines for proper vacuum annealing of multiflake films to enhance their stability. 

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