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1. Thermal Management Systems and Waste Heat Recycling by Thermoelectric Generators—An Overview

   https://doi.org/10.3390/en14185646  

   Hooshmand Zaferani, Sadeq ; Jafarian, Mehdi ; Vashaee, Daryoosh ; Ghomashchi, Reza ( September 2021 , Energies)

   null (Ed.)

   With the fast evolution in greenhouse gas (GHG) emissions (e.g., CO2, N2O) caused by fossil fuel combustion and global warming, climate change has been identified as a critical threat to the sustainable development of human society, public health, and the environment. To reduce GHG emissions, besides minimizing waste heat production at the source, an integrated approach should be adopted for waste heat management, namely, waste heat collection and recycling. One solution to enable waste heat capture and conversion into useful energy forms (e.g., electricity) is employing solid-state energy converters, such as thermoelectric generators (TEGs). The simplicity of thermoelectric generators enables them to be applied in various industries, specifically those that generate heat as the primary waste product at a temperature of several hundred degrees. Nevertheless, thermoelectric generators can be used over a broad range of temperatures for various applications; for example, at low temperatures for human body heat harvesting, at mid-temperature for automobile exhaust recovery systems, and at high temperatures for cement industries, concentrated solar heat exchangers, or NASA exploration rovers. We present the trends in the development of thermoelectric devices used for thermal management and waste heat recovery. In addition, a brief account is presented on the scientific development of TE materials with the various approaches implemented to improve the conversion efficiency of thermoelectric compounds through manipulation of Figure of Merit, a unitless factor indicative of TE conversion efficiency. Finally, as a case study, work on waste heat recovery from rotary cement kiln reactors is evaluated and discussed. 

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2. A comprehensive and synthetic dataset for global, regional, and national greenhouse gas emissions by sector 1970–2018 with an extension to 2019

   https://doi.org/10.5194/essd-13-5213-2021  

   Minx, Jan C. ; Lamb, William F. ; Andrew, Robbie M. ; Canadell, Josep G. ; Crippa, Monica ; Döbbeling, Niklas ; Forster, Piers M. ; Guizzardi, Diego ; Olivier, Jos ; Peters, Glen P. ; et al ( January 2021 , Earth System Science Data)

   Abstract. To track progress towards keeping global warming well below 2 ∘C or even 1.5 ∘C, as agreed in the Paris Agreement, comprehensiveup-to-date and reliable information on anthropogenic emissions and removalsof greenhouse gas (GHG) emissions is required. Here we compile a new synthetic dataset on anthropogenic GHG emissions for 1970–2018 with afast-track extension to 2019. Our dataset is global in coverage and includesCO2 emissions, CH4 emissions, N2O emissions, as well as those from fluorinated gases (F-gases: HFCs, PFCs, SF6, NF3) andprovides country and sector details. We build this dataset from the version 6 release of the Emissions Database for Global Atmospheric Research (EDGAR v6) and three bookkeeping models for CO2 emissions from land use,land-use change, and forestry (LULUCF). We assess the uncertainties of global greenhouse gases at the 90 % confidence interval (5th–95thpercentile range) by combining statistical analysis and comparisons ofglobal emissions inventories and top-down atmospheric measurements with anexpert judgement informed by the relevant scientific literature. We identifyimportant data gaps for F-gas emissions. The agreement between our bottom-up inventory estimates and top-downatmospheric-based emissions estimates is relatively close for some F-gasspecies (∼ 10 % or less), but estimates can differ by an order of magnitude or more for others. Our aggregated F-gas estimate is about 10 % lower than top-down estimates in recent years. However, emissions from excluded F-gas species such aschlorofluorocarbons (CFCs) or hydrochlorofluorocarbons (HCFCs) arecumulatively larger than the sum of the reported species. Using globalwarming potential values with a 100-year time horizon from the Sixth Assessment Report by the Intergovernmental Panel on Climate Change (IPCC),global GHG emissions in 2018 amounted to 58 ± 6.1 GtCO2 eq.consisting of CO2 from fossil fuel combustion and industry (FFI) 38 ± 3.0 GtCO2, CO2-LULUCF 5.7 ± 4.0 GtCO2, CH4 10 ± 3.1 GtCO2 eq., N2O2.6 ± 1.6 GtCO2 eq., and F-gases 1.3 ± 0.40 GtCO2 eq. Initial estimates suggest further growth of 1.3 GtCO2 eq. in GHG emissions to reach 59 ± 6.6 GtCO2 eq. by 2019. Our analysis ofglobal trends in anthropogenic GHG emissions over the past 5 decades (1970–2018) highlights a pattern of varied but sustained emissions growth. There is high confidence that global anthropogenic GHG emissions haveincreased every decade, and emissions growth has been persistent across the different (groups of) gases. There is also high confidence that globalanthropogenic GHG emissions levels were higher in 2009–2018 than in any previous decade and that GHG emissions levels grew throughout the most recent decade. While the average annual GHG emissions growth rate slowed between2009 and 2018 (1.2 % yr−1) compared to 2000–2009 (2.4 % yr−1), the absolute increase in average annual GHG emissions by decade was neverlarger than between 2000–2009 and 2009–2018. Our analysis further revealsthat there are no global sectors that show sustained reductions in GHGemissions. There are a number of countries that have reduced GHG emissionsover the past decade, but these reductions are comparatively modest andoutgrown by much larger emissions growth in some developing countries suchas China, India, and Indonesia. There is a need to further develop independent, robust, and timely emissions estimates across all gases. As such, tracking progress in climate policy requires substantial investmentsin independent GHG emissions accounting and monitoring as well as in national and international statistical infrastructures. The data associatedwith this article (Minx et al., 2021) can be found at https://doi.org/10.5281/zenodo.5566761. 

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3. Quantifying the Potential of Renewable Natural Gas to Support a Reformed Energy Landscape: Estimates for New York State

   https://doi.org/10.3390/en14133834  

   Taboada, Stephanie ; Clark, Lori ; Lindberg, Jake ; Tonjes, David J ; Mahajan, Devinder ( July 2021 , Energies)

   null (Ed.)

   Public attention to climate change challenges our locked-in fossil fuel-dependent energy sector. Natural gas is replacing other fossil fuels in our energy mix. One way to reduce the greenhouse gas (GHG) impact of fossil natural gas is to replace it with renewable natural gas (RNG). The benefits of utilizing RNG are that it has no climate change impact when combusted and utilized in the same applications as fossil natural gas. RNG can be injected into the gas grid, used as a transportation fuel, or used for heating and electricity generation. Less common applications include utilizing RNG to produce chemicals, such as methanol, dimethyl ether, and ammonia. The GHG impact should be quantified before committing to RNG. This study quantifies the potential production of biogas (i.e., the precursor to RNG) and RNG from agricultural and waste sources in New York State (NYS). It is unique because it is the first study to provide this analysis. The results showed that only about 10% of the state’s resources are used to generate biogas, of which a small fraction is processed to RNG on the only two operational RNG facilities in the state. The impact of incorporating a second renewable substitute for fossil natural gas, “green” hydrogen, is also analyzed. It revealed that injecting RNG and “green” hydrogen gas into the pipeline system can reduce up to 20% of the state’s carbon emissions resulting from fossil natural gas usage, which is a significant GHG reduction. Policy analysis for NYS shows that several state and federal policies support RNG production. However, the value of RNG can be increased 10-fold by applying a similar incentive policy to California’s Low Carbon Fuel Standard (LCFS). 

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4. Life cycle greenhouse gas emissions for irrigated corn production in the U.S. great plains

   https://doi.org/10.1016/j.envc.2023.100750  

   Koushki, Raana ; Sharma, Sumit ; Warren, Jason ; Foltz, Mary E. ( December 2023 , Environmental Challenges)

   Agricultural management practices improve crop yields to satisfy food demand of the growing population. However, these activities can have negative consequences, including the release of greenhouse gas (GHG) emissions that contribute to global climate change. To mitigate this global environmental problem, the management practices that contribute the most to system GHG emissions should be identified and targeted to mitigate emissions. Accordingly, we estimated the cradle-to-product GHG emissions of irrigated corn production under various farmer-selected scenarios at an experimental testing field in the semi-arid U.S. Great Plains. We applied a carbon footprint approach to quantify life cycle GHG emissions associated with pre-field (e.g., energy production, fertilizer production) and in-field (e.g., groundwater pumping, fertilizer application) activities within fourteen scenarios in the 2020 Oklahoma Testing Ag Performance Solutions (TAPS) sprinkler corn competition. We determined that 63% of the total GHG emission from corn production was associated with in- field activities and that agricultural soil emissions were the overall driving factor. Soil biochemical processes within agricultural soils were expected to contribute an average of 89 ± 18 g CO2-eq kg− 1 corn of the total 271 ± 46 g CO2-eq kg− 1 corn estimated from these systems. On-site natural gas combustion for agricultural groundwater pumping, pre-field fertilizer production, and pre-field energy production for groundwater pumping were the next most influential parameters on total GHG emissions. Diesel fuel, seed, and herbicide production had insignificant contributions to total GHG emissions from corn production. The model was most sensitive to the modeled GHG emissions from agricultural soil, which had significant uncertainty in the emission factor. Therefore, future efforts should target field measurements to better predict the contribution of direct soil emissions to total GHG emissions, particularly under different managements. In addition, identifying the optimal application rate of irrigation water and fertilizer will help to decrease GHG emissions from groundwater irrigated crops. 

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5. Performance-advantaged ether diesel bioblendstock production by a priori design

   https://doi.org/10.1073/pnas.1911107116  

   Huq, Nabila A. ; Huo, Xiangchen ; Hafenstine, Glenn R. ; Tifft, Stephen M. ; Stunkel, Jim ; Christensen, Earl D. ; Fioroni, Gina M. ; Fouts, Lisa ; McCormick, Robert L. ; Cherry, Patrick A. ; et al ( December 2019 , Proceedings of the National Academy of Sciences)

   Lignocellulosic biomass offers a renewable carbon source which can be anaerobically digested to produce short-chain carboxylic acids. Here, we assess fuel properties of oxygenates accessible from catalytic upgrading of these acids a priori for their potential to serve as diesel bioblendstocks. Ethers derived from C₂and C₄carboxylic acids are identified as advantaged fuel candidates with significantly improved ignition quality (>56% cetane number increase) and reduced sooting (>86% yield sooting index reduction) when compared to commercial petrodiesel. The prescreening process informed conversion pathway selection toward a C₁₁branched ether, 4-butoxyheptane, which showed promise for fuel performance and health- and safety-related attributes. A continuous, solvent-free production process was then developed using metal oxide acidic catalysts to provide improved thermal stability, water tolerance, and yields. Liter-scale production of 4-butoxyheptane enabled fuel property testing to confirm predicted fuel properties, while incorporation into petrodiesel at 20 vol % demonstrated 10% improvement in ignition quality and 20% reduction in intrinsic sooting tendency. Storage stability of the pure bioblendstock and 20 vol % blend was confirmed with a common fuel antioxidant, as was compatibility with elastomeric components within existing engine and fueling infrastructure. Technoeconomic analysis of the conversion process identified major cost drivers to guide further research and development. Life-cycle analysis determined the potential to reduce greenhouse gas emissions by 50 to 271% relative to petrodiesel, depending on treatment of coproducts.

    

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