Atomic layer deposited Pt/TiO2-SiO2 and Pt/ZrO2-SiO2 for sequential adsorption and oxidation of VOCs
- Award ID(s):
- 1802049
- PAR ID:
- 10325898
- Date Published:
- Journal Name:
- Chemical Engineering Journal
- Volume:
- 444
- Issue:
- C
- ISSN:
- 1385-8947
- Page Range / eLocation ID:
- 136603
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
Self-aligned metal-oxide-semiconductor (MOS) capacitors are studied with several low-temperature, wet chemical silicon dioxide (SiO2) interlayers to understand their impact on electrical performance. Self-aligned MOS capacitors are fabricated with a bottom-up patterning technique that uses a poly(methyl methacrylate) brush and dopant-selective KOH etch combined with area-selective atomic layer deposition of hafnium dioxide (HfO2) and Pt. The wet chemical pretreatments used to form the SiO2 interlayer include hydrofluoric acid (HF) etch, 80 °C H2O, and SC-2. Capacitance-voltage measurements of these area-selective capacitors exhibit a HfO2 dielectric constant of ∼19, irrespective of pretreatment. After a forming gas anneal, the average interface state density decreased between 1.8 and 7.5 times. The minimum observed Dit is 1 × 1011 eV−1 cm−2 for the HF-last treatment. X-ray photoelectron spectroscopy shows an increase in stoichiometric SiO2 in the interfacial layer after the anneal. Additional carbon is also observed; however, comparison with capacitors fabricated in a nonselective process reveals minimal impact on performance.more » « less
-
The crystallization of complex oxide thin films on amorphous substrates presents a significant challenge because of the lack of long-range order in these substrates and the subsequent difficulty in controlling crystal growth. Nanocrystals with similar crystal structure have the potential to serve as nucleation sites for crystallization and can facilitate this integration. Isolated nanocrystals of strontium titanate (SrTiO3) can be produced on amorphous SiO2 surfaces through crystallization and ripening of initially amorphous layers of SrTiO3. The resulting SrTiO3 nanocrystals exhibit characteristic lateral radii ranging from tens to hundreds of nm and a consistent average height of 1–2 nm across this range. The area density and mean radii of the nanocrystals can be selected by adjusting the deposition and heating parameters, including the amount of deposited SrTiO3 and the heating duration. The heating-time dependence of the area density and mean radii of the nanocrystals is consistent with predictions based on Ostwald ripening kinetics. The selection of these parameters facilitates the use of SrTiO3 nanocrystals as nucleation sites to crystallize the subsequently deposited layer.more » « less
An official website of the United States government

