skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


Title: Antimony diiminopyridine complexes
The stoichiometric reactions of antimony trichloride, trimethylsilyl trifluoromethanesulfonate, and diiminopyridine ligands lead to the formation of N , N ′, N ′′-chelated SbCl 2 cationic complexes. Methyl and phenyl substituents on the imine carbons of the ligand yielded structures with a lone pair on antimony and the hydrogen substituted variant was notably different as it forms a Menshutkin complex with meta -xylene in the solid-state.  more » « less
Award ID(s):
1753025
PAR ID:
10326451
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Dalton Transactions
Volume:
50
Issue:
34
ISSN:
1477-9226
Page Range / eLocation ID:
11716 to 11719
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; (, Metals)
    Bertruol, Daniel (Ed.)
    Demand and prices for antimony have increased over the last few years. Recycling supplied 15% of domestic consumption in the US, while the remaining 85% was imported. Hydrometallurgical processes have long used alkaline sulfide systems and hydrochloric acid, closing doors on new approaches. Bromine compounds have been recently used to recover PGMs and REEs successfully; thus, antimony leaching with bromine compounds is theoretically feasible. This research was conducted to develop a viable technology for hydrobromic acid between 50 °C and 70 °C as a leaching reagent on dross through single- and two-stage leaching using design of experiment (DoE) and adding sustainability to current industrial processes while minimizing waste products in recycling processes. The preliminary results showed that bromine, specifically hydrobromic acid, can be used as a leaching reagent for antimony dissolution. By decreasing the lead content in the solids and increasing the concentration, temperature, and reaction time, antimony leaching from the dross was increased from 20% to 50%. The findings, coupled with acid regeneration, can be implemented as an alternative to other reagents in industrial plants. 
    more » « less
  2. ; ; ; ; ; ; ; (, Solar)
    The tandem solar cell presents a potential solution to surpass the Shockley–Queisser limit observed in single-junction solar cells. However, creating a tandem device that is both cost-effective and highly efficient poses a significant challenge. In this study, we present proof of concept for a four-terminal (4T) tandem solar cell utilizing a wide bandgap (1.6–1.8 eV) perovskite top cell and a narrow bandgap (1.2 eV) antimony selenide (Sb2Se3) bottom cell. Using a one-dimensional (1D) solar cell capacitance simulator (SCAPS), our calculations indicate the feasibility of this architecture, projecting a simulated device performance of 23% for the perovskite/Sb2Se3 4T tandem device. To validate this, we fabricated two wide bandgap semitransparent perovskite cells with bandgaps of 1.6 eV and 1.77 eV, respectively. These were then mechanically stacked with a narrow bandgap antimony selenide (1.2 eV) to create a tandem structure, resulting in experimental efficiencies exceeding 15%. The obtained results demonstrate promising device performance, showcasing the potential of combining perovskite top cells with the emerging, earth-abundant antimony selenide thin film solar technology to enhance overall device efficiency. 
    more » « less
  3. ; ; ; ; ; ; ; ; (, Geochronology)
    Abstract. The Marysvale volcanic field in southwestern Utah hosts three large-volume gravity slides: the Sevier (SGS), the Markagunt (MGS), and the Black Mountains (BGS). The gravity slides are composed of lahar deposits, lava flows, and ash-flow tuffs erupted from former stratovolcanoes and other vents during the Oligocene and Miocene. The ash-flow tuffs are prime targets for dating to constrain the age of the gravity slides because some ash-flow tuffs are deformed within the slides, whereas others are undeformed and cap the slides. Furthermore, the gravity slides produced pseudotachylyte during slide motion, a direct indicator for the timing of each slide. This work provides new 40Ar/39Ar dates for several ash-flow tuffs and pseudotachylyte for the SGS, along with U/Pb zircon dates for one deformed tuff and alluvium near the slide plane. Results show that the slide was emplaced at 25.25 ± 0.05 Ma and was immediately followed by the eruption of the Antimony Tuff at 25.19 ± 0.02 Ma. The model presented here suggests that the intrusion of magma related to the Antimony Tuff acted as a triggering mechanism for the slide and that slide movement itself led to decompression melting and eruption of the Antimony Tuff. This sequence of events occurred on a geologically rapid timescale and may have been virtually instantaneous. 
    more » « less
  4. ; ; ; ; (, New Journal of Chemistry)
    Pnictogen bonding is beginning to emerge as a useful supramolecular interaction. The design strategies for these systems are still in the early stages of development and much attention has been focused on the lighter pnictogens. Pnictogen bond donors can have up to three independent sites for binding which can result in triple pnictogen bonding. This has been observed in the self-assembly of antimony alkoxide cages, but not with the lighter congeners. This work reports structural characterization of an analogous arsenic alkoxide cage that engages in a single pnictogen bond and synthetic explorations of the bismuth congener. DFT calculations are used to evaluate the differences between the structures. Ultimately the partial charge on the pnictogen and the energy of the pnictogen lone pair dictate the strength, orientation and number of pnictogen bonds that these cages form. Antimony cages strike the best balance between strength and directionality, allowing them to achieve triple pnictogen bonding where the other congeners do not. 
    more » « less
  5. ; ; (, Journal of The Electrochemical Society)
    Tin antimonide (SnSb) is a promising alloying anode for sodium-ion batteries due to its high theoretical capacity and relative stability. The material is popular in the battery field, but, to our knowledge, few studies have been conducted on the influence of altering Sn and Sb stoichiometry on anode capacity retention and efficiency over time. Here, Sn-Sb electrodes were synthesized with compositional control by optimizing electrodeposition parameters and stoichiometry in solution and the alloys were cycled in sodium-ion half-cells to investigate the effects of stoichiometry on both performance and electrochemical phenomena. Higher concentrations of antimony deposited into the films were found to best maintain specific capacity over 270 cycles in the tin-antimony alloys, with each cell showing a slow, gradual decrease in capacity. We identified that a 1:3 ratio of Sn:Sb retained a specific capacity of 486 mAh g−1after 270 cycles, highlighting a need to explore this material further. These results demonstrate how control over stoichiometry in Sn-Sb electrodes is a viable method for tuning performance. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email