- Award ID(s):
- 1953708
- NSF-PAR ID:
- 10332243
- Date Published:
- Journal Name:
- Chemical Science
- Volume:
- 13
- Issue:
- 8
- ISSN:
- 2041-6520
- Page Range / eLocation ID:
- 2391 to 2404
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract The incorporation of CO2into organometallic and organic molecules represents a sustainable way to prepare carboxylates. The mechanism of reductive carboxylation of alkyl halides has been proposed to proceed through the reduction of NiIIto NiIby either Zn or Mn, followed by CO2insertion into NiI‐alkyl species. No experimental evidence has been previously established to support the two proposed steps. Demonstrated herein is that the direct reduction of (
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