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1. The impact of site selectivity and disorder on the thermoelectric properties of Yb ₂₁ Mn ₄ Sb ₁₈ solid solutions: Yb ₂₁ Mn _4−x Cd _x Sb ₁₈ and Yb _21−y Ca _y Mn ₄ Sb ₁₈

   https://doi.org/10.1039/d1ma00497b  

   He, Allan ; Cerretti, Giacomo ; Kauzlarich, Susan M. ( August 2021 , Materials Advances)

   Thermoelectric materials can convert heat into electricity. They are used to generate electricity when other power sources are not available or to increase energy efficiency by recycling waste heat. The Yb 21 Mn 4 Sb 18 phase was previously shown to have good thermoelectric performance due to its large Seebeck coefficient (∼290 μV K −1 ) and low thermal conductivity (0.4 W m −1 K −1 ). These characteristics stem respectively from the unique [Mn 4 Sb 10 ] 22− subunit and the large unit cell/site disorder inherent in this phase. The solid solutions, Yb 21 Mn 4− x Cd x Sb 18 ( x = 0, 0.5, 1.0, 1.5) and Yb 21− y Ca y Mn 4 Sb 18 ( y = 3, 6, 9, 10.5) have been prepared, their structures characterized and thermoelectric properties from room temperature to 800 K measured. A detailed look into the structural disorder for the Cd and Ca solid solutions was performed using synchrotron powder X-ray diffraction and pair distribution function methods and shows that these are highly disordered structures. The substitution of Cd gives rise to more metallic behavior whereas Ca substitution results in high resistivity. As both Cd and Ca aremore »isoelectronic substitutions, the changes in properties are attributed to changes in the electronic structure. Both solid solutions show that the thermal conductivities remain extremely low (∼0.4 W m −1 K −1 ) and that the Seebeck coefficients remain high (>200 μV K −1 ). The temperature dependence of the carrier mobility with increased Ca substitution, changing from approximately T −1 to T −0.5 , suggests that another scattering mechanism is being introduced. As the bonding changes from polar covalent with Yb to ionic for Ca, polar optical phonon scattering becomes the dominant mechanism. Experimental studies of the Cd solid solutions result in a max zT of ∼1 at 800 K and, more importantly for application purposes, a ZT avg ∼ 0.6 from 300 K to 800 K.« less
2. Thermal Development of an Impinging Jet Using Planar Laser Induced Fluorescence (PLIF)

   Wright, L. ; Seitz, S. ( June 2019 , ASME Turbo Expo 2019: Turbomachinery Technical Conference and Exposition)

   Planar Laser Induced Fluorescence (PLIF) has been demonstrated to investigate a round jet impinging on a flat surface. Detailed thermal field distributions have been obtained near the flat target surface to characterize the wall jet development ensuing from the stagnation point. While PLIF has been demonstrated for combustion applications to measure concentration gradients within a mixture, its application for temperature field measurements is less established. Therefore, the technique was applied to a simple, cylindrical impinging jet. The jet Reynolds number varied with Rejet = 5,000 – 15,000 while the jet – to – target surface spacing varied from H / D = 4 – 10. The cooling jet (Tjet ~ 300 K) impinged on a flat, heated surface. The PLIF technique was able to capture the free jet structure and jet development along the target surface. With a short impingement length (H / D = 4), the potential core of the jet strikes the target surface. The thermal gradients captured during the experiments demonstrate the fully turbulent nature of the impinging jet with H / D = 10. The thermal boundary development along the target surface is clearly captured using this fluorescence method. The near wall temperature gradients acquired withmore »the PLIF method have been used to calculate heat transfer coefficients on the heated surface, and these values compare favorably to those measured using a well-established steady state, heat transfer method. The PLIF technique has been demonstrated for this fundamental impingement setup, and it has proven to be applicable to more complex heat transfer and cooling applications.« less
3. An Instance Segmentation and Clustering Model for Energy Audit Assessments in Built Environments: A Multi-Stage Approach

   https://doi.org/10.3390/s21134375  

   Arjoune, Youness ; Peri, Sai ; Sugunaraj, Niroop ; Biswas, Avhishek ; Sadhukhan, Debanjan ; Ranganathan, Prakash ( July 2021 , Sensors)

   Heat loss quantification (HLQ) is an essential step in improving a building’s thermal performance and optimizing its energy usage. While this problem is well-studied in the literature, most of the existing studies are either qualitative or minimally driven quantitative studies that rely on localized building envelope points and are, thus, not suitable for automated solutions in energy audit applications. This research work is an attempt to fill this gap of knowledge by utilizing intensive thermal data (on the order of 100,000 plus images) and constitutes a relatively new area of analysis in energy audit applications. Specifically, we demonstrate a novel process using deep-learning methods to segment more than 100,000 thermal images collected from an unmanned aerial system (UAS). To quantify the heat loss for a building envelope, multiple stages of computations need to be performed: object detection (using Mask-RCNN/Faster R-CNN), estimating the surface temperature (using two clustering methods), and finally calculating the overall heat transfer coefficient (e.g., the U-value). The proposed model was applied to eleven academic campuses across the state of North Dakota. The preliminary findings indicate that Mask R-CNN outperformed other instance segmentation models with an mIOU of 73% for facades, 55% for windows, 67% for roofs, 24%more »for doors, and 11% for HVACs. Two clustering methods, namely K-means and threshold-based clustering (TBC), were deployed to estimate surface temperatures with TBC providing consistent estimates across all times of the day over K-means. Our analysis demonstrated that thermal efficiency not only depended on the accurate acquisition of thermal images but also relied on other factors, such as the building geometry and seasonal weather parameters, such as the outside/inside building temperatures, wind, time of day, and indoor heating/cooling conditions. Finally, the resultant U-values of various building envelopes were compared with recommendations from the American Society of Heating, Refrigerating, and Air-conditioning Engineers (ASHRAE) building standards.« less
4. Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration

   https://doi.org/10.1038/s42005-019-0145-5  

   Yuan, Chao ; Li, Jiahan ; Lindsay, Lucas ; Cherns, David ; Pomeroy, James W. ; Liu, Song ; Edgar, James H. ; Kuball, Martin ( May 2019 , Communications Physics)

   Hexagonal boron nitride (h-BN) has been predicted to exhibit an in-plane thermal conductivity as high as ~ 550 W m⁻¹K⁻¹at room temperature, making it a promising thermal management material. However, current experimental results (220–420 W m⁻¹K⁻¹) have been well below the prediction. Here, we report on the modulation of h-BN thermal conductivity by controlling the B isotope concentration. For monoisotopic¹⁰B h-BN, an in-plane thermal conductivity as high as 585 W m⁻¹K⁻¹is measured at room temperature, ~ 80% higher than that of h-BN with a disordered isotope concentration (52%:48% mixture of¹⁰B and¹¹B). The temperature-dependent thermal conductivities of monoisotopic h-BN agree well with first principles calculations including only intrinsic phonon-phonon scattering. Our results illustrate the potential to achieve high thermal conductivity in h-BN and control its thermal conductivity, opening avenues for the wide application of h-BN as a next-generation thin-film material for thermal management, metamaterials and metadevices.
5. Relative Effects of Velocity- and Mixture-Coupling in a Thermoacoustically Unstable, Partially-Premixed Flame

   Karmarkar, A. ; Boxx, I. ; O'Connor, J. ( January 2021 , ASME Turbo Expo)

   Combustion instability, which is the result of a coupling between combustor acoustic modes and unsteady flame heat release rate, is a severely limiting factor in the operability and performance of modern gas turbine engines. This coupling can occur through different coupling pathways, such as flow field fluctuations or equivalence ratio fluctuations. In realistic combustor systems, there are complex hydrodynamic and thermo-chemical processes involved, which can lead to multiple coupling pathways. In order to understand and predict the mechanisms that govern the onset of combustion instability in real gas turbine engines, we consider the influences that each of these coupling pathways can have on the stability and dynamics of a partially-premixed, swirl-stabilized flame. In this study, we use a model gas turbine combustor with two concentric swirling nozzles of air, separated by a ring of fuel injectors, operating at an elevated pressure of 5 bar. The flow split between the two streams is systematically varied to observe the impact on the flow and flame dynamics. High-speed stereoscopic particle image velocimetry, OH planar laser-induced fluorescence, and acetone planar laser-induced fluorescence are used to obtain information about the velocity field, flame, and fuel-flow behavior, respectively. Depending on the flow conditions, a thermoacoustic oscillationmore »mode or a hydrodynamic mode, identified as the precessing vortex core, is present. The focus of this study is to characterize the mixture coupling processes in this partially-premixed flame as well as the impact that the velocity oscillations have on mixture coupling. Our results show that, for this combustor system, changing the flow split between the two concentric nozzles can alter the dominant harmonic oscillation modes in the system, which can significantly impact the dispersion of fuel into air, thereby modulating the local equivalence ratio of the flame. This insight can be used to design instability control mechanisms in real gas turbine engines.« less