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1. Highly stereoselective syntheses of ( E )-δ-boryl- anti -homoallylic alcohols via allylation with α-boryl-( E )-crotylboronate

   https://doi.org/10.1039/d1cc04058h  

   Liu, Jiaming; Chen, Ming (October 2021, Chemical Communications)

   A highly stereoselective synthesis of ( E )-δ-boryl- anti -homoallylic alcohols is developed. In the presence of a Lewis acid, aldehyde allylation with α-boryl-( E )-crotylboronate gave δ-boryl- anti -homoallylic alcohols in good yields with excellent E -selectivity. The E -vinylboronate group in the products provides a useful handle for cross-coupling reactions as illustrated in the fragment synthesis of chaxamycins. 

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2. Modeling E ‐Region Artificial Periodic Inhomogeneity

   https://doi.org/10.1029/2023RS007710  

   Hysell, D. L.; Rojas, E. (June 2023, Radio Science)

   Abstract Artificial periodic inhomogeneity or API experiments were conducted at the HAARP facility in Gakona, Alaska, in October 2022. The experiments concentrated on measuring ionospheric irregularities induced in theE‐region. The irregularities exhibited characteristics regarding their occurrence altitudes, rise and fall times, and Doppler shifts comparable to results from experiments conducted previously at HAARP and elsewhere. The irregularities also occurred in discrete altitude bands. Seeking to quantify these results, we constructed a simple, one‐dimensional fluid model which includes the effects of HF wave heating (direct and indirect) together with electron and ion cooling and thermal conduction, ion production, loss, and diffusion. Critically, the model includes a potential solver and can represent the ambipolar electric field. The model produced API irregularities in three distinct altitude bands which decayed according to the ambipolar diffusion rate. 

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3. Stereoselective Synthesis of ( E )- and ( Z )-Isocyanoalkenes

   https://doi.org/10.1021/acs.orglett.2c03461  

   Tian, Huan; Holyoke, Caleb W.; Fleming, Fraser F. (December 2022, Organic Letters)
4. L oo p D e l t a : E m b e dd i n g L o c a li t y - a w a r e O pp o r t un i s t i c D e l t a C o m p r e ss i o n i n I n li n e D e dup li c a t i o n f o r Hi g h l y E ffic i e n t D a t a R e du c t i o n

   Zhang, Yucheng; Jiang, Hong; Feng, Dan; Jiang Nan; Qui, Taorong; Huang, Wei (July 2023, USENIX annual technical conference)

   A s a c om pl e men t t o da ta d edupli cat ion , de lta c om p ress i on fu r- t he r r edu c es t h e dat a vo l u m e by c o m pr e ssi n g n o n - dup li c a t e d ata chunk s r e l a t iv e to t h e i r s i m il a r chunk s (bas e chunk s). H ow ever, ex is t i n g p o s t - d e dup li c a t i o n d e l t a c o m pr e ssi o n a p- p ro a ches fo r bac kup s t or ag e e i t h e r su ffe r f ro m t h e l ow s i m - il a r i t y b e twee n m any de te c ted c hun ks o r m i ss so me po t e n - t i a l s i m il a r c hunks , o r su ffer f r om l ow (ba ckup and r es t ore ) th r oug hpu t du e t o extr a I/ Os f or r e a d i n g b a se c hun ks o r a dd a dd i t i on a l s e r v i c e - d i s r up t ive op e r a t i on s to b a ck up s ys t em s. I n t h i s pa p e r, w e pr opo se L oop D e l t a t o a dd ress the above - m e n t i on e d prob l e m s by an e nha nced em b e ddi n g d e l t a c o m p - r e ss i on sc heme i n d e dup li c a t i on i n a non - i n t ru s ive way. T h e e nha nce d d elt a c o mpr ess ion s che m e co m b in e s f our key t e c h - ni qu e s : (1) du a l - l o c a li t y - b a s e d s i m il a r i t y t r a c k i n g to d e t ect po t e n t i a l si m il a r chun k s b y e x p l o i t i n g both l o g i c a l and ph y - s i c a l l o c a li t y, ( 2 ) l o c a li t y - a wa r e pr e f e t c h i n g to pr efe tc h ba se c hun ks to a vo i d ex t ra I/ Os fo r r e a d i n g ba s e chun ks on t h e w r i t e p at h , (3) c a che -aware fil t e r to avo i d ext r a I/Os f or b a se c hunk s on t he read p at h, a nd (4) i nver sed de l ta co mpressi on t o perf orm de lt a co mpress i o n fo r d at a chunk s t hat a re o th e r wi se f o r b i dd e n to s er ve as ba se c hunk s by r ew r i t i n g t e c hn i qu e s d e s i g n e d t o i m p r ove r es t o re pe rf o rma nc e. E x p e r i m e n t a l re su lts indi ca te t hat L oop D e l t a i ncr ea se s t he c o m pr e ss i o n r a t i o by 1 .2410 .97 t i m e s on t op of d e dup li c a - t i on , wi t hou t no t a b l y a ffe c t i n g th e ba ck up th rou ghpu t, a nd i t i m p r ove s t he res to re p er fo r m an ce b y 1.23.57 t i m e 

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5. Nonrefoldability is Pervasive Across the E. coli Proteome

   https://doi.org/10.1021/jacs.1c03270  

   To, Philip; Whitehead, Briana; Tarbox, Haley E.; Fried, Stephen D. (August 2021, Journal of the American Chemical Society)