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ABSTRACT Our understanding of reionization has advanced considerably over the past decade, with several results now demonstrating that the intergalactic medium transitioned from substantially neutral at z = 7 to largely reionized at z = 6. However, little remains known about the sizes of ionized bubbles at z ≳ 7 as well as the galaxy overdensities which drive their growth. Fortunately, rest-ultraviolet (UV) spectroscopic observations offer a pathway towards characterizing these ionized bubbles thanks to the resonant nature of Lyman-alpha photons. In a previous work, we presented Ly α detections from three closely separated Lyman-break galaxies at z ≃ 6.8, suggesting the presence of a large (R > 1 physical Mpc) ionized bubble in the 1.5 deg2 COSMOS field. Here, we present new deep Ly α spectra of 10 UV-bright ($$\mathrm{\mathit{ M}}_{\mathrm{UV}}^{} \le -20.4$$) z ≃ 6.6–6.9 galaxies in the surrounding area, enabling us to better characterize this potential ionized bubble. We confidently detect (S/N > 7) Ly α emission at z = 6.701–6.882 in nine of ten observed galaxies, revealing that the large-scale volume spanned by these sources (characteristic radius R = 3.2 physical Mpc) traces a strong galaxy overdensity (N/〈N〉 ≳ 3). Our data additionally confirm that the Ly α emission of UV-bright galaxies in this volume is significantly enhanced, with 40 per cent (4/10) showing strong Ly α emission (equivalent width >25 Å) compared to the 8–9 per cent found on average at z ∼ 7. The median Ly α equivalent width of our observed galaxies is also ≈2 times that typical at z ∼ 7, consistent with expectations if a very large (R ∼ 3 physical Mpc) ionized bubble is allowing the Ly α photons to cosmologically redshift far into the damping wing before encountering H i.
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Catalytic asymmetric transformations of racemic α-borylmethyl-( E )-crotylboronate via kinetic resolution or enantioconvergent reaction pathways
We report herein catalytic asymmetric transformations of racemic α-borylmethyl-( E )-crotylboronate. The Brønsted acid-catalyzed kinetic resolution–allylboration reaction sequence of the racemic reagent gave ( Z )-δ-hydroxymethyl- anti -homoallylic alcohols with high Z -selectivities and enantioselectivities upon oxidative workup. In parallel, enantioconvergent pathways were utilized to synthesize chiral nonracemic 1,5-diols and α,β-unsaturated aldehydes with excellent optical purity.
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- Award ID(s):
- 2042353
- PAR ID:
- 10339428
- Date Published:
- Journal Name:
- Chemical Science
- Volume:
- 12
- Issue:
- 40
- ISSN:
- 2041-6520
- Page Range / eLocation ID:
- 13398 to 13403
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/d1sc04047b
