Additive manufacturing (AM) as a disruptive technique has offered great potential to design and fabricate many metallic components for aerospace, medical, nuclear, and energy applications where parts have complex geometry. However, a limited number of materials suitable for the AM process is one of the shortcomings of this technique, in particular laser AM of copper (Cu) is challenging due to its high thermal conductivity and optical reflectivity, which requires higher heat input to melt powders. Fabrication of composites using AM is also very challenging and not easily achievable using the current powder bed technologies. Here, the feasibility to fabricate pure copper and copper-carbon nanotube (Cu-CNT) composites was investigated using laser powder bed fusion additive manufacturing (LPBF-AM), and 10 × 10 × 10 mm3 cubes of Cu and Cu-CNTs were made by applying a Design of Experiment (DoE) varying three parameters: laser power, laser speed, and hatch spacing at three levels. For both Cu and Cu-CNT samples, relative density above 90% and 80% were achieved, respectively. Density measurement was carried out three times for each sample, and the error was found to be less than 0.1%. Roughness measurement was performed on a 5 mm length of the sample to obtain statistically significant results. As-built Cu showed average surface roughness (Ra) below 20 µm; however, the surface of AM Cu-CNT samples showed roughness values as large as 1 mm. Due to its porous structure, the as-built Cu showed thermal conductivity of ~108 W/m·K and electrical conductivity of ~20% IACS (International Annealed Copper Standard) at room temperature, ~70% and ~80% lower than those of conventionally fabricated bulk Cu. Thermal conductivity and electrical conductivity were ~85 W/m·K and ~10% IACS for as-built Cu-CNT composites at room temperature. As-built Cu-CNTs showed higher thermal conductivity as compared to as-built Cu at a temperature range from 373 K to 873 K. Because of their large surface area, light weight, and large energy absorbing behavior, porous Cu and Cu-CNT materials can be used in electrodes, catalysts and their carriers, capacitors, heat exchangers, and heat and impact absorption.
more »
« less
Effects of Build Angle on Additively Manufactured Aluminum Alloy Surface Roughness and Wettability
Abstract Laser powder bed fusion (LPBF) was utilized to create a series of aluminum alloy (i.e., AlSi10Mg) 5 mm-diameter support pillars with a fixed height of 5 mm containing varying filet angles and build orientations (i.e., 0 deg, 10 deg, 20 deg, 30 deg, 40 deg, 50 deg, and 60 deg from the normal surface) to determine surface roughness and water wettability effects. From experiments, anisotropic wetting was observed due in part to the surface heterogeneity created by the LPBF process. The powder-sourced AlSi10Mg alloy, typically hydrophobic, exhibited primarily hydrophilic behavior for build angles of 0 deg and 60 deg, a mix of hydrophobic and hydrophilic behavior at build angles of 10 deg and 20 deg, and hydrophobic behavior at 30 deg, 40 deg, and 50 deg build angles. Measured surface roughness, Ra, ranged from 5 to 36 µm and varied based on location. 3D-topography maps were generated, and arithmetic mean heights, Sa, of 15.52–21.71 µm were observed; the anisotropy of roughness altered the wetting behavior, thereby prompting some hydrophilic behavior. Build angles of 30 deg and 40 deg provided for the smoothest surfaces. A significantly rougher surface was found for the 50 deg build angle. This abnormally high roughness is attributed to the melt pool contact angle having maximal capillarity with the surrounding powder bed. In this study, the critical melt pool contact angle was near equal to the build angle, suggesting that a critical build angle exists, which gives rise to pronounced melt pool wetting behavior and increased surface roughness due to enhanced wicking followed by solidification.
more »
« less
- Award ID(s):
- 1828571
- PAR ID:
- 10341174
- Date Published:
- Journal Name:
- Journal of Manufacturing Science and Engineering
- Volume:
- 144
- Issue:
- 8
- ISSN:
- 1087-1357
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
The dynamic phenomenon of a melt pool during the laser powder bed fusion (LPBF) process is complex and sensitive to process parameters. As the energy density input exceeds a certain threshold, a huge vapor depression may form, known as the keyhole. This study focuses on understanding the keyhole behavior and related pore formation during the LPBF process through numerical analysis. For this purpose, a thermo-fluid model with discrete powder particles is developed. The powder distribution, obtained from a discrete element method (DEM), is incorporated into the computational domain to develop a 3D process physics model using flow-3d. The melt pool formation during the conduction mode and the keyhole mode of melting has been discerned and explained. The high energy density leads to the formation of a vapor column and consequently pores under the laser scan track. Further, the keyhole shape resulted from different laser powers and scan speeds is investigated. The numerical results indicated that the keyhole size increases with the increase in the laser power even with the same energy density. The keyhole becomes stable at a higher power, which may reduce the occurrence of pores during laser scanning.more » « less
-
This study investigated the influence of diverse laser processing parameters on the thermophysical properties of Ti-6Al-4V and AlSi10Mg alloys manufactured via laser powder bed fusion. During fabrication, the laser power (50 W, 75 W, 100 W) and laser scanning speed (0.2 m/s, 0.4 m/s, 0.6 m/s) were adjusted while keeping other processing parameters constant. Besides laser processing parameters, this study also explored the impact of test temperatures on the thermophysical properties of the alloys. It was found that the thermophysical properties of L-PBF Ti-6Al-4V alloy samples were sensitive to laser processing parameters, while L-PBF AlSi10Mg alloy showed less sensitivity. In general, for the L-PBF Ti-6Al-4V alloy, as the laser power increased and laser scan speed decreased, both thermal diffusivity and conductivity increased. Both L-PBF Ti-6Al-4V and L-PBF AlSi10Mg alloys demonstrated similar dependence on test temperatures, with thermal diffusivity and conductivity increasing as the test temperature rose. The CALPHAD software Thermo-Calc (2023b), applied in Scheil Solidification Mode, was utilized to calculate the quantity of solution atoms, thus enhancing our understanding of observed thermal conductivity variations. A detailed analysis revealed how variations in laser processing parameters and test temperatures significantly influence the alloy’s resulting density, specific heat, thermal diffusivity, and thermal conductivity. This research not only highlights the importance of processing parameters but also enriches comprehension of the mechanisms influencing these effects in the domain of laser powder bed fusion.more » « less
-
Understanding the wetting properties of shale reservoirs can benefit their development for energy-related purposes and their potential for long-term carbon dioxide injection and storage. Given its potential volumetric abundance and high surface area, the wetting behavior of kerogen in shale requires assessment. Despite their known limitations, wettability studies are commonly limited to static contact angle (θ) measurements. In this Article, the conflicting factors related to the analysis and interpretation of kerogen wetting via static contact angle measurements are discussed. Contact angle data for deionized water, brine (5% NaCl), and n-dodecane are presented for seven paleomarine type-II kerogens spanning a wide range of thermal maturities (vitrinite reflectance, Ro: 0.55 to 2.75%) and chemical composition (aromatic carbon content, H/C ratio, O/C ratio). Droplets of n-dodecane instantaneously absorbed (θ* ≈ 0°) upon contact with all kerogen pellet surfaces, showing the oleophilic nature of kerogen for all maturities tested. Apparent contact angles of water with kerogen surfaces were positively correlated with H/C ratios and inversely correlated with aromatic carbon content, while the bulk and surface oxygen concentrations did not strongly correlate with the measured data. Kerogen exhibited hydrophobic (θwater > 90°) behavior, except at the highest thermal maturities. For example, the least thermally mature and most thermally mature samples studied presented apparent contact angles for water of 123 ± 15 and 59 ± 10°, respectively. Profilometry analyses showed roughness average values ranging from 0.4 ± 0.1 to 3.9 ± 0.7 μm, with the indication that sample topology can affect measured contact angles, albeit in second order as compared to sample chemistry in this study. We recommend caution when associating contact angle data alone with wetting behavior, as data obtained through sessile droplet analysis are subject to known but not always considered, caveats.more » « less
-
Purpose: To investigate the effect of dry coating the amount and type of silica on powder flowability enhancement using a comprehensive set of 19 pharmaceutical powders having different sizes, surface roughness, morphology, and aspect ratios, as well as assess flow predictability via Bond number estimated using a mechanistic multi-asperity particle contact model. Method: Particle size, shape, density, surface energy and area, SEM-based morphology, and FFC were assessed for all powders. Hydrophobic (R972P) or hydrophilic (A200) nano-silica were dry coated for each powder at 25%, 50%, and 100% surface area coverage (SAC). Flow predictability was assessed via particle size and Bond number. Results: Nearly maximal flow enhancement, one or more flow category, was observed for all powders at 50% SAC of either type of silica, equivalent to 1 wt% or less for both the hydrophobic R972P or hydrophilic A200, while R972P generally performed slightly better. Silica amount as SAC better helped understand the relative performance. The power-law relation between FFC and Bond number was observed. Conclusion: Significant flow enhancements were achieved at 50% SAC, validating previous models. Most uncoated very cohesive powders improved by two flow categories, attaining easy flow. Flowability could not be predicted for both the uncoated and dry coated powders via particle size alone. Prediction was significantly better using Bond number computed via the mechanistic multi-asperity particle contact model accounting for the particle size, surface energy, roughness, and the amount and type of silica. The widely accepted 200 nm surface roughness was not valid for most pharmaceutical powders.more » « less
An official website of the United States government

