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1. Isogeochemical Characterization of Mountain System Recharge Processes in the Sierra Nevada, California

   https://doi.org/10.1029/2023WR035719  

   Armengol, Sandra; Ajami, Hoori; Acero_Triana, Juan_S; O_Sickman, James; Ortega, Lucia (July 2024, Water Resources Research)

   Abstract Mountain System Recharge processes are significant natural recharge pathways in many arid and semi‐arid mountainous regions. However, Mountain System Recharge processes are often poorly understood and characterized in hydrologic models. Mountains are the primary water supply source to valley aquifers via lateral groundwater flow from the mountain block (Mountain Block Recharge) and focused recharge from mountain streams contributing to focused Mountain Front Recharge at the piedmont zone. Here, we present a multi‐tool isogeochemical approach to characterize mountain flow paths and Mountain System Recharge in the northern Tulare Basin, California. We used groundwater chemistry data to delineate hydrochemical facies and explain the chemical evolution of groundwater from the Sierra Nevada to the Central Valley aquifer. Stable isotopes and radiogenic groundwater tracers validated Mountain System Recharge processes by differentiating focused from diffuse recharge, and estimating apparent groundwater age, respectively. Novel application of End‐Member Mixing Analysis using conservative chemical components revealed three Mountain System Recharge end‐members: (a) evaporated Ca‐HCO₃water type associated with focused Mountain Front Recharge, (b) non‐evaporated Ca‐HCO₃and Na‐HCO₃water types with short residence times associated with shallow Mountain Block Recharge, and (c) Na‐HCO₃groundwater type with long residence time associated with deep Mountain Block Recharge. We quantified the contribution of each Mountain System Recharge process to the valley aquifer by calculating mixing ratios. Our results show that deep Mountain Block Recharge is a significant recharge component, representing 31%–53% of the valley groundwater. Greater hydraulic connectivity between the Sierra Nevada and Central Valley has significant implications for parameterizing groundwater flow models. Our framework is useful for understanding Mountain System Recharge processes in other snow‐dominated mountain watersheds. 

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2. Characterising TOI-732 b and c: New insights into the M-dwarf radius and density valley

   https://doi.org/10.1051/0004-6361/202348180  

   Bonfanti, A; Brady, M; Wilson, T G; Venturini, J; Egger, J A; Brandeker, A; Sousa, S G; Lendl, M; Simon, A E; Queloz, D; et al (February 2024, Astronomy & Astrophysics)

   Context. TOI-732 is an M dwarf hosting two transiting planets that are located on the two opposite sides of the radius valley. Inferring a reliable demographics for this type of systems is key to understanding their formation and evolution mechanisms. Aims. By doubling the number of available space-based observations and increasing the number of radial velocity (RV) measurements, we aim at refining the parameters of TOI-732 b and c. We also use the results to study the slope of the radius valley and the density valley for a well-characterised sample of M-dwarf exoplanets. Methods. We performed a global Markov chain Monte Carlo analysis by jointly modelling ground-based light curves and CHEOPS and TESS observations, along with RV time series both taken from the literature and obtained with the MAROON-X spectrograph. The slopes of the M-dwarf valleys were quantified via a support vector machine (SVM) procedure. Results. TOI-732b is an ultrashort-period planet (P= 0.76837931_-0.00000042^+0.0000039days) with a radiusR_b= 1.325_-0.058^+0.057R_⊕, a massM_b= 2.46 ± 0.19M_⊕, and thus a mean densityρ_b= 5.8_-0.8^+1.0g cm^-3, while the outer planet atP= 12.252284 ± 0.000013 days hasR_c= 2.39_-0.11^+0.10R_⊕,M_c= 8.04_-0.48^+0.50M_⊕, and thusρ_c= 3.24_-0.43^+0.55g cm^-3. Even with respect to the most recently reported values, this work yields uncertainties on the transit depths and on the RV semi-amplitudes that are smaller up to a factor of ~1.6 and ~2.4 for TOI-732 b and c, respectively. Our calculations for the interior structure and the location of the planets in the mass-radius diagram lead us to classify TOI-732 b as a super-Earth and TOI-732 c as a mini-Neptune. Following the SVM approach, we quantified d logR_p,valley/ d logP= -0.065_-0.013^+0.024, which is flatter than for Sun-like stars. In line with former analyses, we note that the radius valley for M-dwarf planets is more densely populated, and we further quantify the slope of the density valley as d log ρ^_valley/ d logP= -0.02_-0.04^+0.12. Conclusions. Compared to FGK stars, the weaker dependence of the position of the radius valley on the orbital period might indicate that the formation shapes the radius valley around M dwarfs more strongly than the evolution mechanisms. 

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3. Synthesis of Co‐Doped MoS ₂ Monolayers with Enhanced Valley Splitting

   https://doi.org/10.1002/adma.201906536  

   Zhou, Jiadong; Lin, Junhao; Sims, Hunter; Jiang, Chongyun; Cong, Chunxiao; Brehm, John_A; Zhang, Zhaowei; Niu, Lin; Chen, Yu; Zhou, Yao; et al (February 2020, Advanced Materials)

   Abstract Internal magnetic moments induced by magnetic dopants in MoS₂monolayers are shown to serve as a new means to engineer valley Zeeman splitting (VZS). Specifically, successful synthesis of monolayer MoS₂doped with the magnetic element Co is reported, and the magnitude of the valley splitting is engineered by manipulating the dopant concentration. Valley splittings of 3.9, 5.2, and 6.15 meV at 7 T in Co‐doped MoS₂with Co concentrations of 0.8%, 1.7%, and 2.5%, respectively, are achieved as revealed by polarization‐resolved photoluminescence (PL) spectroscopy. Atomic‐resolution electron microscopy studies clearly identify the magnetic sites of Co substitution in the MoS₂lattice, forming two distinct types of configurations, namely isolated single dopants and tridopant clusters. Density functional theory (DFT) and model calculations reveal that the observed enhanced VZS arises from an internal magnetic field induced by the tridopant clusters, which couples to the spin, atomic orbital, and valley magnetic moment of carriers from the conduction and valence bands. The present study demonstrates a new method to control the valley pseudospin via magnetic dopants in layered semiconducting materials, paving the way toward magneto‐optical and spintronic devices. 

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4. Optical Manipulation of Layer–Valley Coherence via Strong Exciton–Photon Coupling in Microcavities

   https://doi.org/10.1002/adom.202202631  

   Khatoniar, Mandeep; Yama, Nicholas; Ghazaryan, Areg; Guddala, Sriram; Ghaemi, Pouyan; Majumdar, Kausik; Menon, Vinod (April 2023, Advanced Optical Materials)

   Abstract Coherent control and manipulation of quantum degrees of freedom such as spins forms the basis of emerging quantum technologies. In this context, the robust valley degree of freedom and the associated valley pseudospin found in two‐dimensional transition metal dichalcogenides is a highly attractive platform. Valley polarization and coherent superposition of valley states have been observed in these systems even up to room temperature. Control of valley coherence is an important building block for the implementation of valley qubit. Large magnetic fields or high‐power lasers have been used in the past to demonstrate the control (initialization and rotation) of the valley coherent states. Here, the control of layer–valley coherence via strong coupling of valley excitons in bilayer WS₂to microcavity photons is demonstrated by exploiting the pseudomagnetic field arising in optical cavities owing to the transverse electric–transverse magnetic (TE–TM)mode splitting. The use of photonic structures to generate pseudomagnetic fields which can be used to manipulate exciton‐polaritons presents an attractive approach to control optical responses without the need for large magnets or high‐intensity optical pump powers. 

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5. The EDGE-CALIFA Survey: Molecular Gas and Star Formation Activity across the Green Valley

   https://doi.org/10.3847/1538-4357/ad1387  

   Villanueva, Vicente; Bolatto, Alberto D.; Vogel, Stuart N.; Wong, Tony; Leroy, Adam K.; Sánchez, Sebastian F.; Levy, Rebecca C.; Rosolowsky, Erik; Colombo, Dario; Kalinova, Veselina; et al (February 2024, The Astrophysical Journal)

   Abstract We present a¹²CO(J= 2−1) survey of 60 local galaxies using data from the Atacama Compact Array as part of the Extragalactic Database for Galaxy Evolution: the ACA EDGE survey. These galaxies all have integral field spectroscopy from the CALIFA survey. Compared to other local galaxy surveys, ACA EDGE is designed to mitigate selection effects based on CO brightness and morphological type. Of the 60 galaxies in ACA EDGE, 36 are on the star formation main sequence, 13 are on the red sequence, and 11 lie in the “green valley” transition between these sequences. We test how star formation quenching processes affect the star formation rate (SFR) per unit molecular gas mass, SFE_mol= SFR/M_mol, and related quantities in galaxies with stellar masses 10 ≤ log[M_⋆/M_⊙] ≤ 11.5 covering the full range of morphological types. We observe a systematic decrease of the molecular-to-stellar mass fraction ( $R_{\star }^{\mathrm{mol}}$) with a decreasing level of star formation activity, with green valley galaxies also having lower SFE_molthan galaxies on the main sequence. On average, we find that the spatially resolved SFE_molwithin the bulge region of green valley galaxies is lower than in the bulges of main-sequence galaxies if we adopt a constant CO-to-H₂conversion factor,α_CO. While efficiencies in main-sequence galaxies remain almost constant with galactocentric radius, in green valley galaxies, we note a systematic increase of SFE_mol, $R_{\star }^{\mathrm{mol}}$, and specific SFR with increasing radius. As shown in previous studies, our results suggest that although gas depletion (or removal) seems to be the most important driver of the star formation quenching in galaxies transiting through the green valley, a reduction in star formation efficiency is also required during this stage. 

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