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1. Soybean growth and production as affected by struvite as a phosphorus source in eastern Arkansas

   https://doi.org/10.1002/csc2.20852  

   Omidire, Niyi S.; Brye, Kristofor R.; English, Leah; Kekedy‐Nagy, Laszlo; Greenlee, Lauren; Popp, Jennie; Roberts, Trenton L. (January 2023, Crop Science)

   Abstract Struvite (MgNH₄PO₄·6H₂O) has been precipitated from liquid waste streams to recover valuable nutrients, such as phosphorus (P) and nitrogen (N), that can be used as an alternative fertilizer‐P source. Because prior research has focused on greenhouse studies, it is necessary to expand struvite evaluations to the field‐scale to include row‐crop responses. The objective of this field study was to evaluate the effects of two struvite materials (electrochemically precipitated struvite, ECST; and chemically precipitated struvite, CPST) relative to other common fertilizer‐P sources (diammonium phosphate, DAP; triple superphosphate, TSP; rock phosphate, RP; and monoammonium phosphate, MAP) on soybean [Glycine max(L.) Merr.] response and economics in two consecutive growing seasons in a P‐deficient, silt‐loam soil (Aquic Fraglossudalfs) in eastern Arkansas. Averaged across years, soybean aboveground tissue P uptake was largest (P < .05) from ECST (28.4 kg ha⁻¹), which was similar to CPST (26.7 kg ha⁻¹) and TSP (25.9 kg ha⁻¹) and was smallest from RP (21.4 kg ha⁻¹). In 2019, seed yield was largest (P < .05) from ECST (4.1 Mg ha⁻¹), which was similar to DAP, CPST, RP, TSP, and MAP, and was smallest from the unamended control (3.6 Mg ha⁻¹). In 2020, seed yield was numerically greatest from CPST (2.8 Mg ha⁻¹) and was numerically smallest from ECST (2.2 Mg ha⁻¹). Results showed that wastewater‐recovered struvite materials have the potential to be a viable, alternative fertilizer‐P source for soybean production in a P‐deficient, silt‐loam soil, but further work is needed to confirm struvite's cost effectiveness. 

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2. Assessment of Struvite as an Alternative Sources of Fertilizer-Phosphorus for Flood-Irrigated Rice

   https://doi.org/10.3390/su14159621  

   Brye, Kristofor R.; Omidire, Niyi S.; English, Leah; Parajuli, Ranjan; Kekedy-Nagy, Laszlo; Sultana, Ruhi; Popp, Jennie; Thoma, Greg; Roberts, Trenton L.; Greenlee, Lauren F. (August 2022, Sustainability)

   Phosphorus (P) recovery from wastewaters as struvite (MgNH4PO4·6H2O) may be a viable alternative fertilizer-P source for agriculture. The objective of this study was to evaluate the economic and environmental implications of struvite as a fertilizer-P source for flood-irrigated rice (Oryza sativa) relative to other commonly used commercially available fertilizer-P sources. A field study was conducted in 2019 and 2020 to evaluate the effects of wastewater-recovered struvite (chemically precipitated struvite (CPST) and electrochemically precipitated struvite (ECST)) on rice yield response in a P-deficient, silt–loam soil in eastern Arkansas relative to triple superphosphate, monoammonium and diammonium phosphate, and rock phosphate. A life cycle assessment methodology was used to estimate the global warming potentials associated with rice produced with the various fertilizer-P sources. Life cycle inventory data were based on the field trials conducted with and without struvite application for both years. A partial budget analysis showed that, across both years, net revenues for ECST and CPST were 1.4 to 26.8% lower than those associated with the other fertilizer-P sources. The estimated greenhouse gas emissions varied between 0.58 and 0.70 kg CO2 eq kg rice−1 from CPST and between 0.56 and 0.81 kg CO2 eq kg rice−1 from ECST in 2019 and 2020, respectively, which were numerically similar to those for the other fertilizer-P sources in 2019 and 2020. The similar rice responses compared to commercially available fertilizer-P sources suggest that wastewater-recovered struvite materials might be an alternative fertilizer-P-source option for flood-irrigated rice production if struvite can become price-competitive to other fertilizer-P sources. 

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3. Recovery of struvite for organic production: Mineral-based magnesium supplementation and pH elevation

   https://doi.org/10.1016/j.jclepro.2024.142244  

   Iftikhar, Aysha; Tao, Wendong (May 2024, Journal of Cleaner Production)

   Phosphate in wastewater can be recovered in the form of struvite crystals for use as slow-release fertilizer. Currently, struvite recovery often requires supplementing magnesium ions and raising pH with chemicals, making the recovered struvite unfavorable for organic production. In an effort for cleaner production, this study developed a versatile approach employing two mineral products in variable combinations for optimal supplementation of magnesium and elevation of pH. Magnesite, a mineral of MgCO3, was ground and calcined without use of any catalysts. The magnesite calcined under the optimum conditions (800 ◦C for 30 min) can be dissolved in near-neutral filtrate of sludge digestate to supplement magnesium and raise pH for effective struvite formation. The OMRI-listed Epsom salts (MgSO4•7H2O), mineral-based water-soluble commercial products, can be used to supplement magnesium without changing pH of alkaline wastewater. Six-hour batch operation of an airlift crystallizer removed 85.7% and 94.7% of phosphate in hydrolyzed human urine when magnesium was amended to 1.2 × molar concentration of phosphate with calcined magnesite and an OMRI-listed Epsom salt, respectively. More than 98% of phosphate was removed from filtrate of sludge digestate in 3-h batch operation using calcined magnesite to raise pH to 8.5 and the Epsom salt for further magnesium supplementation. Struvite accounted for 85.7%, 90.5%, and 81.5% of the crystals recovered from urine with calcined magnesite, urine with Epsom salt, and filtrate with both mineral products, respectively. The material and energy costs of this green process were estimated to be $0.16/kg struvite from urine with calcined magnesite, $1.37/kg struvite from urine with Epsom salt, and $0.94/kg struvite from filtrate with both mineral products. This study proved the technical and economic feasibility of chemical-free magnesium supplementation and pH elevation, making the recovered struvite potentially certifiable for organic production. 

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4. Transition metal-doped MgO nanoparticles for nutrient recycling: an alternate Mg source for struvite synthesis from wastewater

   https://doi.org/10.1039/D0EN00660B  

   Silva, Manoj; Murzin, Vadim; Zhang, Lihua; Baltrus, John; Baltrusaitis, Jonas (November 2020, Environmental Science: Nano)

   null (Ed.)

   Nutrient nitrogen (N) and phosphorus (P) recovery from wastewater is an important challenge for enhanced environmental sustainability. Herein we report the synthesis and properties of mesoporous MgO nanoparticles doped with copper (Cu), iron (Fe), and zinc (Zn) as an alternative low-solubility high-abundance magnesium (Mg) source for crystalline struvite precipitation from nutrient-laden wastewater. Undoped MgO was shown to have the fastest phosphate (PO 4 3− ) adsorption kinetics with a k 2 value of 0.9 g g −1 min −1 at room temperature. The corresponding rate constant decreased for Cu–MgO (0.175 g g −1 min −1 ), Zn–MgO (0.145 g g −1 min −1 ), and Fe–MgO (0.02 g g −1 min −1 ). Undoped MgO resulted in the highest PO 4 3− removal at 94%, while Cu–MgO, Fe–MgO, and Zn–MgO resulted in 90%, 66% and 66%, respectively, under equivalent reaction conditions. All dopants resulted in the production of struvite as the main product with the incorporation of the transition metals into the struvite crystal lattice. X-ray absorption spectroscopy (XAS) showed that the majority of the Cu, Fe, and Zn were primarily in the +2, +3, and +2 oxidation states, respectively. XAS also showed that the Cu atoms exist in elongated octahedral coordination, while Fe was shown to be in octahedral coordination. Zn was shown to be in a complex disordered environment with octahedral sites coexisting with the majority of the tetrahedral sites. Finally, X-ray photoelectron spectroscopy data suggest a two-fold struvite surface enrichment with dopant metals, with Cu exhibiting an interesting new local binding structure. The dopant concentrations utilized were consistent with those found in natural Mg minerals, suggesting that (a) utilizing natural mineral periclase as the Mg source for struvite production can result in struvite formation, albeit at the expense of the reaction kinetics and overall yields, while also (b) supplying essential micronutrients, such as Zn and Cu, necessary for balanced nutrient uptake. 

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5. Cotton Response to Foliar Potassium Application in South Texas Dryland

   https://doi.org/10.3390/agronomy14102422  

   Kommineni, Varshith; Bhandari, Ammar B; Schuster, Greta; Nelson, Shad D (October 2024, Agronomy)

   Potassium (K) deficiency is common in cotton (Gossypium hirsutum L.)-growing areas. This study aims to investigate the effects of different rates of foliar K fertilizer application on three cotton varieties: NG 5711 B3XF (V1), PHY 480 W3FE (V2), and FM 1953GLTP (V3). Potassium fertilizer was dissolved in water and was foliar-applied at 34, 50, and 67 kg ha−1. Cotton plant height (CH) and canopy width (CW) were monitored throughout the growing season. The results showed that foliar K fertilizer application significantly impacted the CH and CW in dry years. Although insignificant, the cotton lint yield increased by 15% and 20% with 34 and 50 kg ha−1 in 2020 and by 9% and 7% with 50 and 67 kg ha−1 in 2021, indicating the potential for improved lint yield with foliar K application in rainfed production systems. Similarly, variety V3 had significantly greater lint and seed yields than V1 in 2020. The average lint yield among the varieties was 32%, and the seed yield was 27% greater in 2020 than in 2021. The cotton fiber color grade was significantly greater at 50 kg ha−1 in 2020 and 67 kg ha−1 in 2021. Cotton variety significantly affected color grade, uniformity, staple length, Col, RD, and Col-b contents in 2020 and 2021. The results suggest that foliar K application can enhance cotton production in rainfed production systems. However, more research is required to quantify varietal and foliar K application rates for improved lint yield and quality. 

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