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Double-network gels are a class of tough soft materials comprising two elastic networks with contrasting structures. The formation of a large internal damage zone ahead of the crack tip by the rupturing of the brittle network accounts for the large crack resistance of the materials. Understanding what determines the damage zone is the central question of the fracture mechanics of double-network gels. In this work, we found that at the onset of crack propagation, the size of necking zone, in which the brittle network breaks into fragments and the stretchable network is highly stretched, distinctly decreases with the increase of the solvent viscosity, resulting in a reduction in the fracture toughness of the material. This is in sharp contrast to the tensile behavior of the material that does not change with the solvent viscosity. This result suggests that the dynamics of stretchable network strands, triggered by the rupture of the brittle network, plays a role. To account for this solvent viscosity effect on the crack initiation, a delayed blunting mechanism regarding the polymer dynamics effect is proposed. The discovery on the role of the polymer dynamic adds an important missing piece to the fracture mechanism of this unique material.
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Rigidity and fracture of biopolymer double networks
Tunable mechanics and fracture resistance are hallmarks of biological tissues whose properties arise from extracellular matrices comprised of double networks. To elucidate the origin of these desired properties, we study the shear modulus and fracture properties of a rigidly percolating double network model comprised of a primary network of stiff fibers and a secondary network of flexible fibers. We find that when the primary network density is just above its rigidity percolation threshold, the secondary network density can be tuned to facilitate stress relaxation via non-affine deformations and provide mechanical reinforcement. In contrast, when the primary network is far above its rigidity threshold, the double network is always stiff and brittle. These results highlight an important mechanism behind the tunability and resilience of biopolymer double networks: the secondary network can dramatically alter mechanical properties from compliant and ductile to stiff and brittle only when the primary network is marginally rigid.
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- PAR ID:
- 10353853
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 18
- Issue:
- 2
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 322 to 327
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D1SM00802A
