Abstract Carbon dioxide is an important tracer of the chemistry and physics in the terrestrial planet-forming zone. Using a thermochemical model that has been tested against the mid-infrared water emission, we reinterpret the CO 2 emission as observed with Spitzer. We find that both water UV-shielding and extra chemical heating significantly reduce the total CO 2 column in the emitting layer. Water UV-shielding is the more efficient effect, reducing the CO 2 column by ∼2 orders of magnitude. These lower CO 2 abundances lead to CO 2 -to-H 2 O flux ratios that are closer to the observed values, but CO 2 emission is still too bright, especially in relative terms. Invoking the depletion of elemental oxygen outside of the water midplane ice line more strongly impacts the CO 2 emission than it does the H 2 O emission, bringing the CO 2 -to-H 2 O emission in line with the observed values. We conclude that the CO 2 emission observed with Spitzer-IRS is coming from a thin layer in the photosphere of the disk, similar to the strong water lines. Below this layer, we expect CO 2 not to be present except when replenished by a physical process. This would be visible in the 13 CO 2 spectrum as well as certain 12 CO 2 features that can be observed by JWST-MIRI.
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Water UV-shielding in the Terrestrial Planet-forming Zone: Implications from Water Emission
Abstract Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestrial planet-forming zone, the inner few astronomical units, of protoplanetary disks. The species currently detected in the disk atmosphere, for example, CO, CO 2 , H 2 O, and C 2 H 2 , are theoretically enough to constrain the C/O ratio on the disk surface. However, thermochemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into the thermochemical code Dust and Lines. We find that both are required to match the observed emission spectrum. Efficient chemical heating, in addition to traditional heating from UV photons, is necessary to elevate the temperature of the water-emitting layer to match the observed excitation temperature of water. We find that water UV-shielding stops UV photons from reaching deep into the disk, cooling down the lower layers with a higher column. These two effects create a hot emitting layer of water with a column of 1–10 × 10 18 cm −2 . This is only 1%–10% of the water column above the dust τ = 1 surface at mid-infrared wavelengths in the models and represents <1% of the total water column.
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- Award ID(s):
- 1907653
- PAR ID:
- 10356081
- Date Published:
- Journal Name:
- The Astrophysical Journal Letters
- Volume:
- 930
- Issue:
- 2
- ISSN:
- 2041-8205
- Page Range / eLocation ID:
- L26
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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