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1. Deciphering the sensitivity of urban canopy air temperature to anthropogenic heat flux with a forcing-feedback framework

   https://doi.org/10.1088/1748-9326/ace7e0  

   Wang, Linying; Sun, Ting; Zhou, Wenyu; Liu, Maofeng; Li, Dan (August 2023, Environmental Research Letters)

   Abstract The sensitivity of urban canopy air temperature ( $T_a$) to anthropogenic heat flux ( $Q_{AH}$) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$(where $\mathrm{\Delta }$represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is around 0.01 $\text{K\hspace{0.17em}}{\left(\text{W\hspace{0.17em}}{\text{m}}^{-\text{2}}\right)}^{-1}$over the CONUS. Besides the direct effect of $Q_{AH}$on $T_a$, there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ( $c_a$), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is mostly controlled by the direct effect in summer. In winter, $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with $c_a$. The spatial and temporal (both seasonal and diurnal) variability of $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$as well as the nonlinear response of $\mathrm{\Delta }{T}_a$to $\mathrm{\Delta }{Q}_{AH}$are strongly related to the variability of $c_a$, highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models. 

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2. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian; Takahashi, Yuiki; Pilgram, Nickolas H; Conn, Chandler J; Zeng, Yi; Zhang, Chi; Hutzler, Nicholas R (July 2023, New Journal of Physics)

   Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of ${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$ $\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state and fit the molecule-frame dipole moment to $D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16\left(1\right)$Dand the effective electrong-factor to $g_S=2.07\left(2\right)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited $\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 

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3. Efficient pathway to NaCs ground state molecules

   https://doi.org/10.1088/1367-2630/acd411  

   Warner, Claire; Bigagli, Niccolò; Lam, Aden Z.; Yuan, Weijun; Zhang, Siwei; Stevenson, Ian; Will, Sebastian (June 2023, New Journal of Physics)

   Abstract We present a study of two-photon pathways for the transfer of NaCs molecules to their rovibrational ground state. Starting from NaCs Feshbach molecules, we perform bound-bound excited state spectroscopy in the wavelength range from 900 nm to 940 nm, covering more than 30 vibrational states of the $c^3{\mathrm{\Sigma }}^{+}$, $b^3\mathrm{\Pi }$, and $B^1\mathrm{\Pi }$electronic states. Analyzing the rotational substructure, we identify the highly mixed $c^3{\mathrm{\Sigma }}_1^{+}|v=22⟩\sim b^3{\mathrm{\Pi }}_1|v=54⟩$state as an efficient bridge for stimulated Raman adiabatic passage. We demonstrate transfer into the NaCs ground state with an efficiency of up to 88(4)%. Highly efficient transfer is critical for the realization of many-body quantum phases of strongly dipolar NaCs molecules and high fidelity detection of single molecules, for example, in spin physics experiments in optical lattices and quantum information experiments in optical tweezer arrays. 

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4. Local-in-time existence of a free-surface 3D Euler flow with H ^2+δ initial vorticity in a neighborhood of the free boundary

   https://doi.org/10.1088/1361-6544/aca5e3  

   Kukavica, I; Ożański, W S (December 2022, Nonlinearity)

   Abstract We consider the three-dimensional Euler equations in a domain with a free boundary with no surface tension. We assume that $u_0\in H^{2.5+\delta }$is such that $\mathrm{c}\mathrm{u}\mathrm{r}\mathrm{l}{u}_0\in H^{2+\delta }$in an arbitrarily small neighborhood of the free boundary, and we use the Lagrangian approach to derive an a priori estimate that can be used to prove local-in-time existence and uniqueness of solutions under the Rayleigh–Taylor stability condition. 

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5. Validation of Elemental and Isotopic Abundances in Late-M Spectral Types with the Benchmark HIP 55507 AB System

   https://doi.org/10.3847/1538-4357/ad1243  

   Xuan, Jerry W.; Wang, Jason; Finnerty, Luke; Horstman, Katelyn; Grimm, Simon; Peck, Anne E.; Nielsen, Eric; Knutson, Heather A.; Mawet, Dimitri; Isaacson, Howard; et al (February 2024, The Astrophysical Journal)

   Abstract M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similarT_eff∼ 2300–2800 K. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution (R∼ 35,000)K-band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B={88.0}_{-3.2}^{+3.4}{M}_{\mathrm{Jup}}$, putting HIP 55507 B above the stellar–substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a={38}_{-3}^{+4}$au ande= 0.40 ± 0.04. From atmospheric retrievals of HIP 55507 B, we measure [C/H] = 0.24 ± 0.13, [O/H] = 0.15 ± 0.13, and C/O = 0.67 ± 0.04. Moreover, we strongly detect¹³CO (7.8σsignificance) and tentatively detect ${\mathrm{H}}_2^{18}\mathrm{O}$(3.7σsignificance) in the companion’s atmosphere and measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={98}_{-22}^{+28}$and ${\mathrm{H}}_2^{16}\mathrm{O}/{\mathrm{H}}_2^{18}\mathrm{O}={240}_{-80}^{+145}$after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={79}_{-16}^{+21}$and ${\mathrm{C}}^{16}\mathrm{O}/{\mathrm{C}}^{18}\mathrm{O}={288}_{-70}^{+125}$for the primary star. These results demonstrate that HIP 55507 A and B have consistent¹²C/¹³C and¹⁶O/¹⁸O to the <1σlevel, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young substellar companions, our results open the door to systematically measuring¹³CO and ${\mathrm{H}}_2^{18}\mathrm{O}$abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types. 

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