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1. Kinetics of the Topochemical Transformation of (PbSe) _m (TiSe ₂ ) _n (SnSe ₂ ) _m (TiSe ₂ ) _n to (Pb _0.5 Sn _0.5 Se) _m (TiSe ₂ ) _n

   https://doi.org/10.1021/jacs.8b10681  

   Sutherland, Duncan R.; Merrill, Devin R.; Ditto, Jeffrey; Moore, Daniel B.; Medlin, Douglas; Johnson, David C. (January 2019, Journal of the American Chemical Society)
2. Optical Properties of Electrochemically Gated La _{1− x} Sr _x CoO _3−δ as a Topotactic Phase‐Change Material

   https://doi.org/10.1002/adom.202300098  

   Chakraborty, Rohan_D; Postiglione, William_M; Ghosh, Supriya; Mkhoyan, K_Andre; Leighton, Chris; Ferry, Vivian_E (May 2023, Advanced Optical Materials)

   Abstract Materials with tunable infrared refractive index changes have enabled active metasurfaces for novel control of optical circuits, thermal radiation, and more. Ion‐gel‐gated epitaxial films of the perovskite cobaltite La_1−xSr_xCoO_3−δ(LSCO) with 0.00 ≤x≤ 0.70 offer a new route to significant, voltage‐tuned, nonvolatile refractive index modulation for infrared active metasurfaces, shown here through Kramers–Kronig‐consistent dispersion models, structural and electronic transport characterization, and electromagnetic simulations before and after electrochemical reduction. As‐grown perovskite films are high‐index insulators forx< 0.18 but lossy metals forx> 0.18, due to a percolation insulator‐metal transition. Positive‐voltage gating of LSCO transistors withx> 0.18 reveals a metal‐insulator transition from the metallic perovskite phase to a high‐index (n> 2.5), low‐loss insulating phase, accompanied by a perovskite to oxygen‐vacancy‐ordered brownmillerite transformation at highx. Atx< 0.18, despite nominally insulating character, the LSCO films undergo remarkable refractive index changes to another lower‐index, lower‐loss insulating perovskite state with Δn >0.6. In simulations of plasmonic metasurfaces, these metal‐insulator and insulator‐insulator transitions support significant, varied mid‐infrared reflectance modulation, thus framing electrochemically gated LSCO as a diverse library of room‐temperature phase‐change materials for applications including dynamic thermal imaging, camouflage, and optical memories. 

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3. Identification of a Fe-Dependent Optical Mode in CuAl _1–x Fe _x O ₂

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4. The rapid A-C _i response: photosynthesis in the phenomic era: Rapid A-C _i response (RACiR)

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5. Experimental and computational investigations of TiIrB: a new ternary boride with Ti _1+x Rh _2−x+y Ir _3−y B ₃ -type structure

   https://doi.org/10.1515/znb-2021-0121  

   Scheifers, Jan P.; Gibson, Kate A.; Fokwa, Boniface P. (October 2021, Zeitschrift für Naturforschung B)

   Abstract A new ternary phase, TiIrB, was synthesized by arc-melting of the elements and characterized by powder X-ray diffraction. The compound crystallizes in the orthorhombic Ti 1+ x Rh 2− x + y Ir 3− y B 3 structure type, space group Pbam (no. 55) with the lattice parameters a  = 8.655(2), b  = 15.020(2), and c  = 3.2271(4) Å. Density Functional Theory (DFT) calculations were carried out to understand the electronic structure, including a Bader charge analysis. The charge distribution of TiIrB in the Ti 1+ x Rh 2− x + y Ir 3− y B 3 -type phase has been evaluated for the first time, and the results indicate that more electron density is transferred to the boron atoms in the zigzag B 4 units than to isolated boron atoms. 

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