In recent years, the excitation of surface phonon polaritons (SPhPs) in van der Waals materials received wide attention from the nanophotonics community. Alpha-phase Molybdenum trioxide (
Sample suspension is a valuable method to improve the mechanical, thermal, electronic, and optical properties of low-dimensional materials. In terms of confined light-matter waves—the polaritons, sample suspension can elongate the wavelength of polaritons with a positive phase velocity. Previous work demonstrates a wavelength elongation of ∼10% for hyperbolic phonon polaritons (HPPs) in uniaxial crystals of hexagonal boron nitride (hBN). In this work, we report the alteration of HPPs in biaxial α-phase molybdenum trioxide (α-MoO3) by sample suspension. Our combined infrared nano-imaging experiments and electromagnetic theory reveal a wavelength elongation > 60% and a propagation length increase > 140%, due to the simultaneous wavelength elongation and dissipation elimination in the suspended specimen. We have also examined HPPs in α-MoO3with a negative phase velocity. The sample suspension shortens the HPP wavelength and simultaneously reduces the dissipation due to the unique permittivity tensor. The HPPs with improved figures of merits in the suspended specimen may be developed for nano-polaritonic circuits, biochemical sensing, emission engineering, and energy transfer.
more » « less- NSF-PAR ID:
- 10363949
- Publisher / Repository:
- American Institute of Physics
- Date Published:
- Journal Name:
- Applied Physics Letters
- Volume:
- 120
- Issue:
- 11
- ISSN:
- 0003-6951
- Page Range / eLocation ID:
- Article No. 113101
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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