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ABSTRACT Determining the level of chemical complexity within dense starless and gravitationally bound pre-stellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We have searched for complex organic molecules (COMs) in the young starless core L1521E, and report the first clear detection of dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), and vinyl cyanide (CH2CHCN). Eight transitions of acetaldehyde (CH3CHO) were also detected, five of which (A states) were used to determine an excitation temperature to then calculate column densities for the other oxygen-bearing COMs. If source size was not taken into account (i.e. if filling fraction was assumed to be one), column density was underestimated, and thus we stress the need for higher resolution mapping data. We calculated L1521E COM abundances and compared them to other stages of low-mass star formation, also finding similarities to other starless/pre-stellar cores, suggesting related chemical evolution. The scenario that assumes formation of COMs in gas-phase reactions between precursors formed on grains and then ejected to the cold gas via reactive desorption was tested and was unable to reproduce observed COM abundances, with the exception of CH3CHO. These results suggest that COMs observed in cold gas are formed not by gas-phase reactions alone, but also through surface reactions on interstellar grains. Our observations present a new, unique challenge for existing theoretical astrochemical models.
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A survey of deuterated ammonia in the Cepheus star-forming region L1251
ABSTRACT Understanding the chemical processes during starless core and prestellar core evolution is an important step in understanding the initial stages of star and disc formation. This project is a study of deuterated ammonia, o-NH2D, in the L1251 star-forming region towards Cepheus. Twenty-two dense cores (20 of which are starless or prestellar, and two of which have a protostar), previously identified by p-NH3 (1,1) observations, were targeted with the 12m Arizona Radio Observatory telescope on Kitt Peak. o-NH2D J$$_{\rm {K_a} \rm {K_c}}^{\pm } =$$1_{11}^{+} \rightarrow 1_{01}^{-}$$ was detected in 13 (59 per cent) of the NH3-detected cores with a median sensitivity of $$\sigma _{T_{mb}} = 17$$ mK. All cores detected in o-NH2D at this sensitivity have p-NH3 column densities >1014 cm−2. The o-NH2D column densities were calculated using the constant excitation temperature (CTEX) approximation while correcting for the filling fraction of the NH3 source size. The median deuterium fraction was found to be 0.11 (including 3σ upper limits). However, there are no strong, discernible trends in plots of deuterium fraction with any physical or evolutionary variables. If the cores in L1251 have similar initial chemical conditions, then this result is evidence of the cores physically evolving at different rates.
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- PAR ID:
- 10369634
- Publisher / Repository:
- Oxford University Press
- Date Published:
- Journal Name:
- Monthly Notices of the Royal Astronomical Society
- Volume:
- 515
- Issue:
- 4
- ISSN:
- 0035-8711
- Page Range / eLocation ID:
- p. 5219-5234
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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