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Abstract Basaltic watersheds such as those found in Iceland are thought to be important sites of CO2sequestration via silicate weathering. However, determining the magnitude of CO2uptake depends on accurately interpreting river chemistry. Here, we compile geochemical data from Iceland and use them to constrain weathering processes. Specifically, we use a newly developed inverse model to quantify solute supply from rain and hydrothermal fluids as well as allow for variable silicate end‐member compositions, solutes to be removed via secondary phase formation, and some Ca to be sourced from carbonate dissolution. While some of these processes have been considered previously, they have not been considered together allowing us to newly determine their relative contributions. We find that weathering in Iceland is incongruent in two ways. First, solute release from primary silicates is characterized by a higher proportion of Na than would be expected from bulk basalts, which may reflect preferential weathering or some contribution from rhyolites. This Na enrichment is further enhanced by preferential Mg and K uptake by secondary phases. No samples in our data set (n = 537) require carbonate dissolution even if isotopic data (δ26Mg,δ30Si,δ44Ca, and/or87Sr/86Sr) are included. While some carbonate weathering is allowable, silicate weathering likely dominates. The complexity we observe in Iceland underscores the need for inverse models to account for a wide range of processes and end‐members. Given that riverine fluxes from Iceland are more Na‐rich than expected for congruent basalt weathering, the characteristic timescale of CO2drawdown is likely affected.
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The Geochemistry of Englacial Brine From Taylor Glacier, Antarctica
Abstract Blood Falls is a hypersaline, iron‐rich discharge at the terminus of the Taylor Glacier in the McMurdo Dry Valleys, Antarctica. In November 2014, brine in a conduit within the glacier was penetrated and sampled using clean‐entry techniques and a thermoelectric melting probe called the IceMole. We analyzed the englacial brine sample for filterable iron (fFe), total Fe, major cations and anions, nutrients, organic carbon, and perchlorate. In addition, aliquots were analyzed for minor and trace elements and isotopes including δD and δ18O of water, δ34S and δ18O of sulfate,234U,238U, δ11B,87Sr/86Sr, and δ81Br. These measurements were made in order to (1) determine the source and geochemical evolution of the brine and (2) compare the chemistry of the brine to that of nearby hypersaline lake waters and previous supraglacially sampled collections of Blood Falls outflow that were interpreted asend‐memberbrines. The englacial brine had higher Cl−concentrations than the Blood Falls end‐member outflow; however, other constituents were similar. The isotope data indicate that the water in the brine is derived from glacier melt. The H4SiO4concentrations and U and Sr isotope suggest a high degree of chemical weathering products. The brine has a low N:P ratio of ~7.2 with most of the dissolved inorganic nitrogen in the form of NH4+. Dissolved organic carbon concentrations are similar to end‐member outflow values. Our results provide strong evidence that the original source of solutes in the brine was ancient seawater, which has been modified with the addition of chemical weathering products.
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- Award ID(s):
- 1637708
- PAR ID:
- 10371536
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Biogeosciences
- Volume:
- 124
- Issue:
- 3
- ISSN:
- 2169-8953
- Page Range / eLocation ID:
- p. 633-648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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