skip to main content


Title: 3D Seismic Anatomy of a Watershed Reveals Climate‐Topography Coupling That Drives Water Flowpaths and Bedrock Weathering
Abstract

To investigate how bedrock transforms to soil, we mapped the topography of the interface demarcating onset of weathering under an east‐west trending shale watershed in the Valley and Ridge province in the USA Using wave equation travel‐time tomography from a seismic array of >4,000 geophones, we obtained a 3D P‐wave velocity (Vp) model that resolves structures ∼20 m below land surface (mbls). The depth of mobile soil and the onset of dissolution of chlorite roughly match Vp = 600 m/s and Vp = 2,700 m/s, respectively. Chlorite dissolution initiates porosity growth in the shale matrix. Depth to the 2,700 m/s contour is greater under the N‐ as compared to S‐facing hillslopes and under sub‐planar as compared to concave‐up land surfaces. Broadly, the geometries of the ‘soil’ and ‘chlorite’ Vp contours are consistent with the calculated potential for shear fracture opening under weak regional compression. However, this calculated fracture potential does not consistently explain observations related to N‐ versus S‐facing aspect nor fracture density observed by borehole televiewer. Apparently, regional compression is only a secondary influence on Vp: the primary driver of P‐wave slowing in the upper layers of this catchment is topographic control of reactive water flowpaths and their integrated effects on weathering. The Vp result is best explained as the long‐term integrated effect of groundwater flow‐induced geochemical weathering of shale in response to climate‐driven patterns of micro‐ and macro‐topography.

 
more » « less
Award ID(s):
1239285 1331726 1945431 2012073
NSF-PAR ID:
10372470
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Journal of Geophysical Research: Earth Surface
Volume:
126
Issue:
12
ISSN:
2169-9003
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    We used seismic refraction to image the P‐wave velocity structure of a shale watershed experiencing regional compression in the Valley and Ridge Province (USA). From estimates showing strong compressional stress, we expected the depth to unweathered bedrock to mirror the hill‐valley‐hill topography (“bowtie pattern”) by analogy to seismic velocity patterns in crystalline bedrock in the North American Piedmont that also experience compression. Previous researchers used failure potentials calculated for strong compression in the Piedmont to suggest fractures are open deeper under hills than valleys to explain the “bowtie” pattern. Seismic images of the shale watershed, however, show little evidence of such a “bowtie.” Instead, they are consistent with weak (not strong) compression. This contradiction could be explained by the greater importance of infiltration‐driven weathering than fracturing in determining seismic velocities in shale compared to crystalline bedrock, or to local perturbations of the regional stress field due to lithology or structures.

     
    more » « less
  2. The rate of chemical weathering has been observed to increase with the rate of physical erosion in published comparisons of many catchments, but the mechanisms that couple these processes are not well understood. We investigated this question by exam- ining the chemical weathering and porosity profiles from catchments developed on marine shale located in Pennsylvania, USA (Susquehanna Shale Hills Critical Zone Observatory, SSHCZO); California, USA (Eel River Critical Zone Observatory, ERC- ZO); and Taiwan (Fushan Experimental Forest). The protolith compositions, protolith porosities, and the depths of regolith at these sites are roughly similar while the catchments are characterized by large differences in erosion rate (1–3 mm yr􏱝1 in Fushan 􏱞 0.2–0.4 mm yr􏱝1 in ERCZO 􏱞 0.01–0.025 mm yr􏱝1 in SSHCZO). The natural experiment did not totally isolate erosion as a variable: mean annual precipitation varied along the erosion gradient (4.2 m yr􏱝1 in Fushan > 1.9 m yr􏱝1 in ERCZO > 1.1 m yr􏱝1 in SSHCZO), so the fastest eroding site experiences nearly twice the mean annual temperature of the other two. Even though erosion rates varied by about 100􏱟, the depth of pyrite and carbonate depletion (defined here as regolith thickness) is roughly the same, consistent with chemical weathering of those minerals keeping up with erosion at the three sites. These minerals were always observed to be the deepest to react, and they reacted until 100% depletion. In two of three of the catchments where borehole observations were available for ridges, these minerals weathered across narrow reaction fronts. On the other hand, for the rock-forming clay mineral chlorite, the depth interval of weathering was wide and the extent of depletion observed at the land surface decreased with increasing erosion/precipitation. Thus, chemical weathering of the clay did not keep pace with erosion rate. But perhaps the biggest difference among the shales is that in the fast-eroding sites, microfractures account for 30–60% of the total porosity while in the slow-eroding shale, dissolution could be directly related to secondary porosity. We argue that the microfractures increase the influx of oxygen at depth and decrease the size of diffusion-limited internal domains of matrix, accelerating weathering of pyrite and carbonate under high erosion-rate condi- tions. Thus, microfracturing is a process that can couple physical erosion and chemical weathering in shales. 
    more » « less
  3. In weathered bedrock aquifers, groundwater is stored in pores and fractures that open as rocks are exhumed and minerals interact with meteoric fluids. Little is known about this storage because geochemical and geophysical observations are limited to pits, boreholes, or outcrops or to inferences based on indirect measurements between these sites. We trained a rock physics model to borehole observations in a well-constrained ridge and valley landscape and then interpreted spatial variations in seismic refraction velocities. We discovered that P-wave velocities track where a porosity-generating reaction initiates in shale in three boreholes across the landscape. Specifically, velocities of 2.7 ± 0.2 km/s correspond with growth of porosity from dissolution of chlorite, the most reactive of the abundant minerals in the shale. In addition, sonic velocities are consistent with the presence of gas bubbles beneath the water table under valley and ridge. We attribute this gas largely to CO2produced by 1) microbial respiration in soils as meteoric waters recharge into the subsurface and 2) the coupled carbonate dissolution and pyrite oxidation at depth in the rock. Bubbles may nucleate below the water table because waters depressurize as they flow from ridge to valley and because pores have dilated as the deep rock has been exhumed by erosion. Many of these observations are likely to also describe the weathering and flow path patterns in other headwater landscapes. Such combined geophysical and geochemical observations will help constrain models predicting flow, storage, and reaction of groundwater in bedrock systems.

     
    more » « less
  4. null (Ed.)
    Abstract. Carbonate weathering is essential in regulating atmosphericCO2 and carbon cycle at the century timescale. Plant roots accelerateweathering by elevating soil CO2 via respiration. It however remainspoorly understood how and how much rooting characteristics (e.g., depth anddensity distribution) modify flow paths and weathering. We address thisknowledge gap using field data from and reactive transport numericalexperiments at the Konza Prairie Biological Station (Konza), Kansas (USA), asite where woody encroachment into grasslands is surmised to deepen roots. Results indicate that deepening roots can enhance weathering in two ways.First, deepening roots can control thermodynamic limits of carbonatedissolution by regulating how much CO2 transports vertical downward tothe deeper carbonate-rich zone. The base-case data and model from Konzareveal that concentrations of Ca and dissolved inorganic carbon (DIC) areregulated by soil pCO2 driven by the seasonal soil respiration. Thisrelationship can be encapsulated in equations derived in this workdescribing the dependence of Ca and DIC on temperature and soil CO2. The relationship can explain spring water Ca and DIC concentrations from multiple carbonate-dominated catchments. Second, numericalexperiments show that roots control weathering rates by regulating recharge(or vertical water fluxes) into the deeper carbonate zone and exportreaction products at dissolution equilibrium. The numerical experimentsexplored the potential effects of partitioning 40 % of infiltrated waterto depth in woodlands compared to 5 % in grasslands. Soil CO2 datasuggest relatively similar soil CO2distribution over depth, which in woodlands and grasslands leads only to 1 % to∼ 12 % difference inweathering rates if flow partitioning was kept the same between the two landcovers. In contrast, deepening roots can enhance weathering by ∼ 17 % to200 % as infiltration rates increased from 3.7 × 10−2 to 3.7 m/a. Weathering rates in these cases however are more than an order of magnitude higher than a case without roots atall, underscoring the essential role of roots in general. Numericalexperiments also indicate that weathering fronts in woodlands propagated> 2 times deeper compared to grasslands after 300 years at aninfiltration rate of 0.37 m/a. These differences in weathering fronts areultimately caused by the differences in the contact times of CO2-charged water with carbonate in the deep subsurface. Within the limitation of modeling exercises, these data and numerical experiments prompt the hypothesis that (1) deepening roots in woodlands can enhance carbonate weathering by promotingrecharge and CO2–carbonate contact in the deepsubsurface and (2) the hydrological impacts of rooting characteristics canbe more influential than those of soil CO2 distribution in modulatingweathering rates. We call for colocated characterizations of roots,subsurface structure, and soil CO2 levels, as well as their linkage to waterand water chemistry. These measurements will be essential to illuminatefeedback mechanisms of land cover changes, chemical weathering, globalcarbon cycle, and climate. 
    more » « less
  5. Abstract

    Understanding how soil thickness and bedrock weathering vary across ridge and valley topography is needed to constrain the flowpaths of water and sediment production within a landscape. Here, we investigate saprolite and weathered bedrock properties across a ridge‐valley system in the Northern California Coast Ranges, USA, where topography varies with slope aspect such that north‐facing slopes have thicker soils and are more densely vegetated than south‐facing slopes. We use active source seismic refraction surveys to extend observations made in boreholes to the hillslope scale. Seismic velocity models across several ridges capture a high velocity gradient zone (from 1,000 to 2,500 m/s) located ∼4–13 m below ridgetops that coincides with transitions in material strength and chemical depletion observed in boreholes. Comparing this transition depth across multiple north‐ and south‐facing slopes, we find that the thickness of saprolite does not vary with slope aspects. Additionally, seismic survey lines perpendicular and parallel to bedding planes reveal weathering profiles that thicken upslope and taper downslope to channels. Using a rock physics model incorporating seismic velocity, we estimate the total porosity of the saprolite and find that inherited fractures contribute a substantial amount of pore space in the upper 6 m, and the lateral porosity structure varies strongly with hillslope position. The aspect‐independent weathering structure suggests that the contemporary critical zone structure at Rancho Venada is a legacy of past climate and vegetation conditions.

     
    more » « less