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1. Early Diagenesis in the Hypoxic and Acidified Zone of the Northern Gulf of Mexico: Is Organic Matter Recycling in Sediments Disconnected From the Water Column?

   https://doi.org/10.3389/fmars.2021.604330  

   Rabouille, Christophe; Lansard, Bruno; Owings, Shannon M.; Rabalais, Nancy N.; Bombled, Bruno; Metzger, Edouard; Richirt, Julien; Eitel, Eryn M.; Boever, Anthony D.; Beckler, Jordon S.; et al (March 2021, Frontiers in Marine Science)

   null (Ed.)

   Hypoxia and associated acidification are growing concerns for ecosystems and biogeochemical cycles in the coastal zone. The northern Gulf of Mexico (nGoM) has experienced large seasonal hypoxia for decades linked to the eutrophication of the continental shelf fueled by the Mississippi River nutrient discharge. Sediments play a key role in maintaining hypoxic and acidified bottom waters, but this role is still not completely understood. In the summer 2017, when the surface area of the hypoxic zone in the nGoM was the largest ever recorded, we investigated four stations on the continental shelf differentially influenced by river inputs of the Mississippi-Atchafalaya River System and seasonal hypoxia. We investigated diagenetic processes under normoxic, hypoxic, and nearly anoxic bottom waters by coupling amperometric, potentiometric, and voltammetric microprofiling with high-resolution diffusive equilibrium in thin-films (DET) profiles and porewater analyses. In addition, we used a time-series of bottom-water dissolved oxygen from May to November 2017, which indicated intense O 2 consumption in bottom waters related to organic carbon recycling. At the sediment-water interface (SWI), we found that oxygen consumption linked to organic matter recycling was large with diffusive oxygen uptake (DOU) of 8 and 14 mmol m –2 d –1 , except when the oxygen concentration was near anoxia (5 mmol m –2 d –1 ). Except at the station located near the Mississippi river outlet, the downcore pore water sulfate concentration decrease was limited, with little increase in alkalinity, dissolved inorganic carbon (DIC), ammonium, and phosphate suggesting that low oxygen conditions did not promote anoxic diagenesis as anticipated. We attributed the low anoxic diagenesis intensity to a limitation in organic substrate supply, possibly linked to the reduction of bioturbation during the hypoxic spring and summer. 

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2. A Two Decadal (1993–2012) Numerical Assessment of Sediment Dynamics in the Northern Gulf of Mexico

   https://doi.org/10.3390/w11050938  

   Zang, Zhengchen; Xue, Z. George; Xu, Kehui; Bentley, Samuel J.; Chen, Qin; D’Sa, Eurico J.; Ge, Qian (May 2019, Water)

   We adapted the coupled ocean-sediment transport model to the northern Gulf of Mexico to examine sediment dynamics on seasonal-to-decadal time scales as well as its response to decreased fluvial inputs from the Mississippi-Atchafalaya River. Sediment transport on the shelf exhibited contrasting conditions in a year, with strong westward transport in spring, fall, and winter, and relatively weak eastward transport in summer. Sedimentation rate varied from almost zero on the open shelf to more than 10 cm/year near river mouths. A phase shift in river discharge was detected in 1999 and was associated with the El Niño-Southern Oscillation (ENSO) event, after which, water and sediment fluxes decreased by ~20% and ~40%, respectively. Two sensitivity tests were carried out to examine the response of sediment dynamics to high and low river discharge, respectively. With a decreased fluvial supply, sediment flux and sedimentation rate were largely reduced in areas proximal to the deltas, which might accelerate the land loss in down-coast bays and estuaries. The results of two sensitivity tests indicated the decreased river discharge would largely affect sediment balance in waters around the delta. The impact from decreased fluvial input was minimum on the sandy shoals ~100 km west of the Mississippi Delta, where deposition of fluvial sediments was highly affected by winds. 

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3. Dynamic manganese cycling in the northern Gulf of Mexico

   https://doi.org/10.1016/j.marchem.2024.104466  

   Davis, Jessalyn E; Robinson, Rebecca S; Estes, Emily R; Oldham, Veronique E; Solomon, Evan A; Kelly, Roger P; Bell, Katherine E; Resing, Joseph A; Bundy, Randelle M (November 2024, Marine Chemistry)

   Transport processes along the river-ocean continuum influence delivery of nutrients, carbon and trace metals from terrestrial systems to the marine environment, impacting coastal primary productivity and water quality. Although trace metal transformations have been studied extensively in the Mississippi River Delta region of the Northern Gulf of Mexico, investigations of manganese (Mn) and the presence of ligand-stabilized, dissolved manganese (Mn(III)-L) and its role in the transformation of trace elements and organic matter during riverine transport and estuarine mixing have not been considered. This study examined the chemical speciation of dissolved and particulate Mn in the water column and sediment porewaters in the Mississippi River and Northern Gulf of Mexico in March of 2021 to explore transformations in Mn speciation along the river-ocean continuum and the impact of different processes on the distribution of Mn. Total dissolved Mn concentrations were highest in the Mississippi River and decreased offshore, while Mn(III)-L contributed most to the dissolved Mn pool in near-shore waters. Porewater profiles indicated that ligand stabilization prevented dissolved Mn(III) reduction below the depth of oxygen penetration and in the presence of equimolar dissolved iron(II). Dissolved Mn(III)-L was enriched in bottom waters at all Northern Gulf of Mexico stations, and diffusive flux modelling of porewater dissolved Mn suggested that reducing sediments were a source of dissolved Mn to the overlying water column in the form of both reduced Mn(II) and Mn(III)-L. A simple box model of the Mn cycle in the Northern Gulf of Mexico indicates that Mn(III)-L is required to balance the Mn budget in this region and is an integral, and previously unconsidered, piece of the Mn cycle in the Northern Gulf of Mexico. The presence of Mn(III)-L in this system likely has an outsized impact on trace element scavenging rates, oxidative capacity, and the carbon cycle that have not been previously appreciated. 

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4. Dynamical Impact of the Mekong River Plume in the South China Sea

   https://doi.org/10.1029/2021JC017572  

   Zeng, Xiyuan; Bracco, Annalisa; Tagklis, Filippos (April 2022, Journal of Geophysical Research: Oceans)

   Abstract Near the ocean surface, river plumes influence stratification, buoyancy and transport of tracers, nutrients and pollutants. The extent to which river plumes influence the overall circulation, however, is generally poorly constrained. This work focuses on the South China Sea (SCS) and quantifies the dynamical impacts of the Mekong River plume, which is bound to significantly change in strength and seasonality in the next 20 years if the construction of over hundred dams moves ahead as planned. The dynamic impact of the freshwater fluxes on the SCS circulation are quantified by comparing submesoscale permitting and mesoscale resolving simulations with and without riverine input between 2011 and 2016. In the summer and early fall, when the Mekong discharge is at its peak, the greater stratification causes a residual mesoscale circulation through enhanced baroclinic instability. The residual circulation is shaped as an eddy train of positive and negative vorticity. Submesoscale fronts are responsible for transporting the freshwater offshore, shifting eastward the development of the residual mesoscale circulation, and further strengthening the residual eddy train in the submesoscale permitting case. Overall, the northward transport near the surface is intensified in the presence of riverine input. The significance of the mesoscale‐induced and submesoscale‐induced transport associated with the river plume is especially important in the second half of the summer monsoon season, when primary productivity has a secondary maximum. Circulation changes, and therefore productivity changes, should be anticipated if human activities modify the intensity and seasonality of the Mekong River plume. 

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5. Detecting Signals of Large‐Scale Climate Phenomena in Discharge and Nutrient Loads in the Mississippi‐Atchafalaya River Basin

   https://doi.org/10.1029/2018GL081166  

   Smits, A. P.; Ruffing, C. M.; Royer, T. V.; Appling, A. P.; Griffiths, N. A.; Bellmore, R.; Scheuerell, M. D.; Harms, T. K.; Jones, J. B. (April 2019, Geophysical Research Letters)

   Abstract Agricultural runoff from the Mississippi‐Atchafalaya River Basin delivers nitrogen (N) and phosphorus (P) to the Gulf of Mexico, causing hypoxia, and climate drives interannual variation in nutrient loads. Climate phenomena such as El Niño–Southern Oscillation may influence nutrient export through effects on river flow, nutrient uptake, or biogeochemical transformation, but landscape variation at smaller spatial scales can mask climate signals in load or discharge time series within large river networks. We used multivariate autoregressive state‐space modeling to investigate climate signals in the long‐term record (1979–2014) of discharge, N, P, and SiO₂loads at three nested spatial scales within the Mississippi‐Atchafalaya River Basin. We detected significant signals of El Niño–Southern Oscillation and land‐surface temperature anomalies in N loads but not discharge, SiO₂, or P, suggesting that large‐scale climate phenomena contribute to interannual variation in nutrient loads through biogeochemical mechanisms beyond simple discharge‐load relationships. 

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