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1. Data report: marine tephra compositions in proximal and distal drill cores, IODP Expeditions 375, 372, and 329, ODP Leg 181, and DSDP Leg 90, offshore New Zealand, Southwest Pacific

   https://doi.org/10.14379/iodp.proc.372B375.210.2023  

   Pank, K; Kutterolf, S; Hopkins, JL; Wang, KL; Lee, HY (April 2023, Proceedings of the International Ocean Discovery Program Expedition reports)

   We report on a total of 1005 samples analyzed for major and trace element compositions from marine sediments drilled along the Hikurangi subduction zone and within the incoming Pacific plate. The samples are from International Ocean Discovery Program Expeditions 375 and 372; Integrated Ocean Drilling Program Expedition 329; Ocean Drilling Program Leg 181; and Deep Sea Drilling Project Leg 90. All 1005 samples, resulting in a total number of ~20,200 individual measurements, were analyzed for major element compositions with the electron microprobe. A subset of 419 samples, resulting in a total number of ~1820 individual glass shard analyses, were analyzed for trace element compositions using the laser ablation-inductively coupled plasma-mass spectrometer. In total, ~640 samples were identified as primary ash layers based on their homogeneous geochemistry, visual appearance in the core pictures, and high amount of volcanic glass. Based on the biostratigraphy presented in the cruise reports and subsequent work, we can distinguish between Quaternary- and Neogene-derived tephras. The tephra layers of Quaternary age are mostly of rhyolitic composition with occasional andesitic, dacitic, and trachytic glass shards. The Neogene tephras are mostly of basaltic andesite, andesitic, and rhyolitic composition, with a few basaltic and trachytic tephras. Tephras of both age groups follow the calc-alkaline series trend with a tendency to shift into the high-K calc-alkaline series for tephras with >70 wt% SiO2. 

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2. Data report: chemical compositions of marine tephra layers in the Indian Ocean, IODP Expeditions 353 and 362

   https://doi.org/10.14379/iodp.proc.362.207.2023  

   Kutterolf, S; Schindlbeck-Belo, JC; Pank, K; Wang, K-L; Lee, H-Y (April 2023, Proceedings of the International Ocean Discovery Program)

   We report on a total of 310 samples from marine sediments drilled in the Indian Ocean that were analyzed for glass shard compositions. Samples are mainly from International Ocean Discovery Program Expeditions 353 and 362 but are complemented by samples from Expedition 354; Ocean Drilling Program Legs 183, 121, 120, 119, 116, and 115; and Deep Sea Drilling Project Leg 22. We performed 4327 successful single glass shard analyses with the electron microprobe for major element compositions and conducted 937 successful single analyses with laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) for trace element compositions on individual glass shards previously measured with the electron microprobe. In total, we were able to measure glass compositions for 254 samples. Of all the samples, 235 can be classified as tephra layers containing pyroclasts as the predominant component in their clast inventory between the 63 and 125 µm grain size fraction, often exceeding 90 vol%. The compositions of the Indian Ocean marine tephras range from basalt to rhyolite and from basaltic trachyandesite to trachyte and fall into the calc-alkaline, K-rich calc-alkaline, and shoshonitic magmatic series. 

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3. Data report: major and trace element and Nd-Pb-Hf isotope composition of the Site U1504 metamorphic basement in the South China Sea (IODP Expedition 367/368/368X)

   https://doi.org/10.14379/iodp.proc.367368.203.2022  

   Straub, S.M.; Mallick, S.; Gomez-Tuena, A.; Dorais, M.J. (March 2022, Proceedings of the International Ocean Discovery Program)

   During International Ocean Discovery Program (IODP) Expedition 367/368/368X, Holes U1504A and U1504B were cored on the continental shelf (2817–2843 meters below sea level) in the northern South China Sea (SCS). A total of 106 m of metamorphic basement was penetrated that consists of greenish gray, deformed mylonitic, epidote-chlorite to calc-silicate schists containing granofels clasts ("greenschist"). Here we report bulk-rock major and trace element data from 17 greenschist samples, from which a subset of 9 samples was additionally analyzed for Pb-Nd-Hf isotope ratios. Fluid-mobile elements (U, Li, Rb, K, and Cs) behave somewhat erratically, yet tectonic discrimination and primitive mantle–normalized multielement diagrams reveal signatures that are typical for enriched intraplate basalts. These include a negative Pb anomaly (Ce/Pb = 34 ± 10), relative enrichments of Nb and Ta (Nb/La = 1.5 ± 0.3; Th/Nb = 0.07 ± 0.01), and a steep rare earth element pattern (La/Sm = 3.7 ± 0.7; Ho/Lu = 2.9 ± 0.2). The high values of the uranogenic 206Pb/204Pb (21.2–25.9) and 207Pb/204Pb (15.7–16.0) and their strong correlation point to a postformation "U addition event" that took place at 329 Ma ± 2 My (late Carboniferous). 143Nd/144Nd and 176Hf/177Hf data are consistent with the origin from an enriched Paleozoic age mantle source. In summary, our data suggest that the protolith of the Site U1504 metamorphic basement was an ocean-island basalt–type igneous rock that deformed during the late Paleozoic and was part of the prerift crustal basement of the SCS Basin. 

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4. Rhyolite volcanism in the Marie Byrd Land volcanic province, Antarctica: New evidence for pyroclastic eruptions during latest Pliocene icesheet expansion

   https://doi.org/10.5194/egusphere-egu21-9003  

   Iverson, Nels; Siddoway, Christine S.; Zimmerer, Matt; Smellie, John; Dunbar, Nelia; Gohl, Karsten; Scientists, IODP Exp379 (April 2021, vEGU21, the 23rd EGU General Assembly)

   IODP Expedition 379 deep-sea drilling in 2019 (Gohl et al. 2021, doi:10.14379/iodp.proc.379.2021), offered an opportunity to obtain chronostratigraphic control for seismic reflection data for Amundsen Sea shelf and slope deposits that record Miocene to Present fluctuations in volume of the West Antarctic ice sheet. Here we report the age and interpret the provenance of a volcanic ash bed recovered at/near the Plio-Pleistocene boundary at 31.51 meters below sea level in Hole U1533B and 33.94 mbsf in Hole U1533D. With distinctive geochemistry and inferred wide regional distribution, the bed may serve as a reliable age marker. In Hole 1533B, the fresh tephra forms a discrete layer interstratified within uniform brown marine mud. The layer has a sharp base and upper boundary that is gradational over 5 cm into overlying mud. Color reflectance and density data aided identification of the tephra horizon (diffuse) in Hole 1533D, ~1000m away. A possible on-land source for ash is the Miocene to Pleistocene Marie Byrd Land volcanic province, comprising 18 large alkaline volcanoes dominated by effusive lavas. Products of pyroclastic eruptions are uncommon, mainly occurring as distal englacial, and probably marine, tephra. We undertook an offshore-onshore comparison by first characterizing samples of Site U1533 tephra from a petrographic and geochemical standpoint, using thin section observations, EMPA-WDS glass compositions, and 40Ar/39Ar dating. We then identified onshore exposures with similar characteristics. The offshore tephra are composed of coarse (50-300µm) cuspate glass shards with elongated vesicles. The glass composition is rhyolite, with 75-79wt.% SiO2, ~4wt.% FeO and 0.0wt.% MgO. Single-crystal feldspar 40Ar/39Ar dates are 2.55±0.12 and 2.92±0.02 Ma for U1533B and 2.87 ±0.45 Ma for U1533D. The geochemistry, shard morphology, discrete bed expression, and lateral continuity between Holes U1533B-U1533D indicate that the rhyolite tephra formed as airfall settled to the deep seabed. The ca. 2.55 Ma age based on youngest feldspar grains differs slightly from the 2.1 to 2.2 Ma result obtained from in-progress core bio-magnetostratigraphy. Rare exposures of rhyolite are found in the Chang Peak/Mt. Waesche centers, 1080 km from Site U1533. We obtained pumice sample MB.7.3 (prior-published age of 1.6±0.2 Ma), which displays elevated FeO and F content, and MB.8.1, a specimen of porphyritic cryptocrystalline lava. Single-crystal sanidine 40Ar/39Ar dates are 1.315±0.007 Ma (MB.7.3) and 1.385±0.003 Ma (MB.8.1). Site U1533 samples share a geochemical affinity with these on-land rhyolites, expressed as similar SiO2, CaO, TiO2, MgO and FeO content, suggesting an origin for Site U1533 tephra in the Chang-Waesche volcanoes. A possible explanation for the distinctly greater age, and observed contrasts in Al2O3, Na2O and F percentages, is that Site U1533 tephra are older and erupted from a source entirely concealed beneath subsequent eruptions and the ice sheet. Our results suggest that rhyolite volcanism initiated earlier, was of longer duration than previously known (2.92 to 1.315 Ma), and dispersed tephra far offshore. The finding is significant because ash and aerosols produced by large eruptions may influence regional climate. Antarctica cooled significantly and ice sheets expanded in latest Pliocene time (McKay et al. 2012, doi:10.1073/pnas.1112248109). 

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5. South China Sea Rifted Margin

   https://doi.org/10.14379/iodp.proc.367368.2018  

   Sun, Z.; Jian, Z.; Stock, J.M.; Larsen, H.C.; Klaus, A.; Alvarez Zarikian, C.A. (September 2018, Proceedings of the International Ocean Discovery Program)

   null (Ed.)

   The primary objectives of International Ocean Discovery Program (IODP) Expedition 367/368 to the northern South China Sea (SCS) margin were to (1) examine its history of continental breakup and (2) compare it with other nonvolcanic or magma-poor rifted margins with the broader goal of testing models for continental breakup. A secondary objective was to further our understanding of the paleoceanographic and environmental development of the SCS and southeast Asia during the Cenozoic. Four primary sites were selected for the overall program: one in the outer margin high (OMH) and three seaward of the OMH on distinct, margin-parallel basement ridges. These three ridges are informally labeled A, B, and C and are located in the continent–ocean transition (COT) zone ranging from the OMH to the interpreted steady-state oceanic crust (Ridge C) of the SCS. The main scientific objectives include the following: Determining the nature of the basement in crustal units across the COT of the SCS that are critical to constrain style of rifting, Constraining the time interval from initial crustal extension and plate rupture to the initial generation of igneous ocean crust, Constraining vertical crustal movements during breakup, and Examining the nature of igneous activity from rifting to seafloor spreading. In addition, the sediment cores from the drill sites targeting primarily tectonic and basement objectives will provide information on the Cenozoic regional environmental development of the Southeast Asia margin. Site U1499 on Ridge A and Site U1500 on Ridge B were drilled during Expedition 367. Expedition 368 was planned to drill at two primary sites (U1501 and U1503) at the OMH and Ridge C, respectively, but based on drilling results from Expedition 367, Expedition 368 chose to insert an alternate site on Ridge A (Site U1502). In addition, Expedition 368 added two more sites on the OMH (Sites U1504 and U1505). Expedition 367/368 completed operations at six of the seven sites (U1499–U1502, U1504, and U1505). Site U1503, however, was not completed beyond casing without coring to 990 m because of mechanical problems with the drilling equipment that prevented the expedition, after 25 May 2017, from operating with a drill string longer than 3400 m. New alternate Site U1504, proposed during Expedition 367, met this condition. Original Site U1505 also met the operational constraints of the 3400 m drill string (total) and was an alternate site for the already-drilled Site U1501. At Site U1499, we cored to 1081.8 m in 22.1 days with 52% recovery and then logged downhole data from 655 to 1020 m. In 31 days at Site U1500, we penetrated to 1529 m, cored a total of 1012.8 m with 37% recovery, and collected log data from 842 to 1133 m. At Site U1501, we cored to 697.1 m in 9.4 days with 78.5% recovery. We also drilled ahead for 433.5 m in Hole U1501D and then logged downhole data from 78.3 to 399.3 m. In 19.3 days at Site U1502, we penetrated 1679.0 m in Holes U1502A (758 m) and U1502B (921 m), set 723.7 m of casing and cored a total of 576.3 m with 53.5% recovery, and collected downhole log data from 785.3 to 875.3 m and seismic data through the 10¾ inch casing. At Site U1503, we penetrated 995.1 m and set 991.5 m of 10¾ inch casing, but no cores were taken because of a mechanical problem with the drawworks. At Site U1504, we took 40 rotary core barrel (RCB) cores over two holes. The cored interval between both holes was 277.3 m with 26.8% recovery. An 88.2 m interval was drilled in Hole U1504B. At Site U1505, we cored 668.0 m with 101.1% recovery. Logging data was collected from 80.1 to 341.2 m. Operations at this site covered 6.1 days. Except for Sites U1503 and U1505, all sites were drilled to acoustic basement. A total of 6.65 days were lost due to mechanical breakdown or waiting on spare supplies for repair of drilling equipment, but drilling options were severely limited from 25 May to the end of the expedition by the defective drawworks limiting deployment of drill string longer than 3400 m. At Site U1499, coring ~200 m into the interpreted acoustic basement sampled sedimentary rocks, possibly including early Miocene chalks underlain by Oligocene polymict breccias and poorly cemented gravels of unknown age comprising sandstone pebbles and cobbles. Preliminary structural and lithologic analysis suggests that the gravels might be early to late synrift sediment. At Site U1500, the main seismic reflector corresponds to the top of a basalt sequence at ~1379.1 m. We cored 149.90 m into this volcanic package and recovered 114.92 m (77%) of sparsely to moderately plagioclase-phyric basalt comprising numerous lava flows, including pillow lavas with glass, chilled margins, altered veins, hyaloclastites, and minor sediment. Preliminary geochemical analyses indicate that the basalt is tholeiitic. Sampling of the Pleistocene to lower Miocene sedimentary section at Sites U1499 and U1500 was not continuous for two reasons. First, there was extremely poor recovery in substantial intervals interpreted to be poorly lithified sands, possibly turbidites. Second, we chose to drill down without coring in some sections at Site U1500 to ensure sufficient time to achieve this site’s high-priority deep drilling objectives. The upper Miocene basin sequence, which consists of interbedded claystone, siltstone, and sandstone can be correlated between the two sites by seismic stratigraphic mapping and biostratigraphy. At Site U1501 on the OMH, coring ~45 m into the acoustic basement sampled prerift(?) deposits comprising sandstone to conglomerate of presumed Mesozoic age. These deposits are overlain by siliciclastic synrift sediments of Eocene to Oligocene age followed by primarily carbonaceous postrift sediments of early Miocene to Pleistocene age. Site U1502 on Ridge A was cased to 723.7 m. No coring was attempted shallower than 380 m to save operational time and because of low expectations for core recovery in the upper Plio–Pleistocene sequence. At this site, we recovered 180 m of hydrothermally altered brecciated basalts comprising sheet and pillow lavas below deep-marine sediments of Oligocene to late Miocene age. At Site U1503 on Ridge C, 991.5 m of casing was installed in preparation for the planned deep drilling to ~1800 m. No coring was performed due to mechanical failures, and the site was abandoned without further activity except for installation of a reentry cone. Coring at Site U1504 on the OMH, located ~45 km east of Site U1501, recovered mostly foliated, greenschist facies metamorphic rocks below late Eocene(?) carbonate rocks (partly reef debris) and early Miocene to Pleistocene sediments. At Site U1505, we cored to 480.15 m through Pleistocene to late Oligocene mainly carbonaceous ooze followed at depth by early Oligocene siliciclastic sediments. Efforts were made at every drill site to correlate the core with the seismic data and seismic stratigraphic unconformities interpreted in the Eocene to Plio–Pleistocene sedimentary sequence prior to drilling. The predrilling interpretation of ages of these unconformities was in general confirmed by drilling results, although some nontrivial corrections can be expected from detailed postexpedition work on integrating seismic stratigraphic interpretations with detailed bio- and lithostratigraphy. As a result of the limited length of drill string that could be deployed during the later part of Expedition 368, the secondary expedition objectives addressing the environmental history of the SCS and Southeast Asia received more focus than originally planned, allowing Site U1505 (alternate to Site U1501) to be included. Despite this change in focus, Expedition 367/368 provided solid evidence for a process of breakup that included vigorous synrift magmatism as opposed to the often-favored interpretation of the SCS margin as a magma-starved margin or a margin possibly overprinted at a much later stage by plume-related magmatism. In this broader perspective, Expedition 367/368 accomplished a fundamental objective of the two-expedition science program. 

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