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1. Data report: marine tephra compositions in proximal and distal drill cores, IODP Expeditions 375, 372, and 329, ODP Leg 181, and DSDP Leg 90, offshore New Zealand, Southwest Pacific

   Pank, K. ; Kutterolf, S. ; Hopkins, J.L. ; Wang, K.L. ; Lee, H.Y. ( April 2023 , Proceedings of the International Ocean Discovery Program Expedition reports)

   We report on a total of 1005 samples analyzed for major and trace element compositions from marine sediments drilled along the Hikurangi subduction zone and within the incoming Pacific plate. The samples are from International Ocean Discovery Program Expeditions 375 and 372; Integrated Ocean Drilling Program Expedition 329; Ocean Drilling Program Leg 181; and Deep Sea Drilling Project Leg 90. All 1005 samples, resulting in a total number of ~20,200 individual measurements, were analyzed for major element compositions with the electron microprobe. A subset of 419 samples, resulting in a total number of ~1820 individual glass shard analyses, were analyzed for trace element compositions using the laser ablation-inductively coupled plasma-mass spectrometer. In total, ~640 samples were identified as primary ash layers based on their homogeneous geochemistry, visual appearance in the core pictures, and high amount of volcanic glass. Based on the biostratigraphy presented in the cruise reports and subsequent work, we can distinguish between Quaternary- and Neogene-derived tephras. The tephra layers of Quaternary age are mostly of rhyolitic composition with occasional andesitic, dacitic, and trachytic glass shards. The Neogene tephras are mostly of basaltic andesite, andesitic, and rhyolitic composition, with a few basaltic and trachytic tephras. Tephras of both age groups follow the calc-alkaline series trend with a tendency to shift into the high-K calc-alkaline series for tephras with >70 wt% SiO2. 

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2. Data report: marine tephra compositions in the deep drilling cores of the South China Sea, IODP Expeditions 349 and 367/368

   https://doi.org/10.14379/iodp.proc.367368.204.2022  

    Schindlbeck-Belo, J.C. ; Dadd, K. ; Wang, K.L. ; Lee, H.Y. ( October 2022 , Proceedings of the International Ocean Discovery Program)

   We present geochemical major and trace element glass data for tephra samples from International Ocean Discovery Program (IODP) Expeditions 349 and 367/368 from four drilling sites in the South China Sea. Overall, we obtained data for 55 samples and identified 46 as tephra layers, with dominant volcanic glass shards in the component inventory (in the 63–125 µ fraction). In total, we performed 720 single glass shard analyses using an electron microprobe for major element compositions, as well as 130 single glass shard analyses using laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) for trace element compositions. The compositions of the samples range from basaltic, (trachy-) andesitic to trachytic, and rhyolitic and fall mainly into the calc-alkaline and K-rich calc-alkaline magmatic series. One sample falls into the shoshonitic series. Tephras from Expedition 349 Site U1431 span the whole compositional range, whereas tephras from the other sites are limited to rhyolitic composition. Tephra ages, calculated applying sedimentation rates, range to ~2 Ma at Site U1431, ~0.8 Ma at Expedition 367 Site U1499, ~0.6 Ma at Expedition 368 Site U1501, and ~0.9 Ma at Expedition 368 Site U1505. 

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3. Oxygen isotopic and chemical composition of chromites in micrometeorites: Evidence of ordinary chondrite precursors

   https://doi.org/10.1111/maps.13281  

   Rudraswami, N. G. ; Marrocchi, Yves ; Shyam Prasad, M. ; Fernandes, D. ; Villeneuve, Johan ; Taylor, S. ( March 2019 , Meteoritics & Planetary Science)

   We identified 66 chromite grains from 42 of ~5000 micrometeorites collected from Indian Ocean deep‐sea sediments and the South Pole water well. To determine the chromite grains precursors and their contribution to the micrometeorite flux, we combined quantitative electron microprobe analyses and oxygen isotopic analyses by high‐resolution secondary ion mass spectrometry. Micrometeorite chromite grains show variable O isotopic compositions with δ¹⁸O values ranging from −0.8 to 6.0‰, δ¹⁷O values from 0.3 to 3.6‰, and Δ¹⁷O values from −0.9 to 1.6‰, most of them being similar to those of chromites from ordinary chondrites. The oxygen isotopic compositions of olivine, considered as a proxy of chromite in chromite‐bearing micrometeorites where chromite is too small to be measured in ion microprobe have Δ¹⁷O values suggesting a principal relationship to ordinary chondrites with some having carbonaceous chondrite precursors. Furthermore, the chemical compositions of chromites in micrometeorites are close to those reported for ordinary chondrite chromites, but some contribution from carbonaceous chondrites cannot be ruled out. Consequently, carbonaceous chondrites cannot be a major contributor of chromite‐bearing micrometeorites. Based on their oxygen isotopic and elemental compositions, we thus conclude with no ambiguity that chromite‐bearing micrometeorites are largely related to fragments of ordinary chondrites with a small fraction from carbonaceous chondrites, unlike other micrometeorites deriving largely from carbonaceous chondrites.

    

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4. Tristan-Gough-Walvis Ridge Plume System, testing plume-ridge interaction at IODP Expedition 391 Site U1577 on the eastern Flank of Valdivia Bank

   Class, Cornelia ; Nelson, Wendy R ; Potter, Katherine E ; Shervais, John W ; Bolge, L ; IODP_Expedition_391_Scientists ( December 2023 , American Geophysical Union)

   The Tristan-Gough plume system forms age-progressive volcanism on the African plate over ~130 Ma, extending to the active islands of Gough and Tristan-Inaccessible. Walvis Ridge forms massive ridges and plateaus that split into three narrower ridges of the Guyot Province. International Ocean Discovery Program (IODP) Expedition 391 Site U1577 sampled the extreme eastern flank of Valdivia Bank, an oceanic plateau within the Walvis Ridge. Here we report major and trace element data as well as Sr-Nd-Hf-Pb isotopic compositions of IODP 391 Site U1577. Three massive basalt flow subunits were drilled, separated only by thin chilled margins. The lack of any sediment or significant alteration at the contacts, and their consistent paleomagnetic inclination, all suggest that these flows were erupted in relatively quick succession. Accordingly, geochemical variations are minimal. Samples from Site U1577 form tight clusters that overlap in major and trace elements with previous dredge and Deep Sea Drilling Project (DSDP) drill site samples from the Walvis Ridge. All are less enriched in incompatible trace elements, i.e., Ti, K, P, Sr and Zr, relative to samples from Tristan and Gough islands and the Guyot province, consistent with Walvis Ridge samples formed by higher degrees of partial melting. In contrast to Walvis Ridge dredge samples, Site U1577 samples are shifted slightly towards higher 176Hf/177Hf and lower 208Pb/204Pb isotopic compositions, while overlapping in 207Pb/204Pb vs. 206Pb/204Pb as well as Sr-Nd isotopic compositions. Such elevated 176Hf/177Hf combined with lower 208Pb/204Pb isotopic compositions have otherwise only been reported from the Eastern Rio Grande Rise formed in near-/on-ridge position. Magnetic lineations imply formation of Valdivia Bank by seafloor spreading as well. Site U1577 samples provide geochemical support for this hypothesis whereas dredge samples lack signatures of plume-ridge interaction. Also, with Site U1577 on the eastern flank, it is farthest from the mid-Atlantic Ridge at the time of formation compared to the location of near-by dredge samples. With major and trace element data integrated on the same samples as isotopic compositions, we will address the contrasting possibilities of an integral depleted plume component versus evidence for plume-ridge interaction. 

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5. Tephrochronology and Provenance of an Early Pleistocene (Calabrian) Tephra From IODP Expedition 374 Site U1524, Ross Sea (Antarctica)

   https://doi.org/10.1029/2021GC009739  

   Di Roberto, A. ; Scateni, B. ; Di Vincenzo, G. ; Petrelli, M. ; Fisauli, G. ; Barker, S. J. ; Del Carlo, P. ; Colleoni, F. ; Kulhanek, D. K. ; McKay, R. ; et al ( August 2021 , Geochemistry, Geophysics, Geosystems)

   We present a full characterization of a 20 cm‐thick tephra layer found intercalated in the marine sediments recovered at Site U1524 during International Ocean Discovery Program (IODP) Expedition 374, in the Ross Sea, Antarctica. Tephra bedforms, mineral paragenesis, and major‐ and trace‐element composition on individual glass shards were investigated and the tephra age was constrained by⁴⁰Ar‐³⁹Ar on sanidine crystals. The⁴⁰Ar‐³⁹Ar data indicate that sanidine grains are variably contaminated by excess Ar, with the best age estimate of 1.282 ± 0.012 Ma, based on both single‐grain total fusion analyses and step‐heating experiments on multi‐grain aliquots. The tephra is characterized by a very homogeneous rhyolitic composition and a peculiar mineral assemblage, dominated by sanidine, quartz, and minor aenigmatite and arfvedsonite‐riebeckite amphiboles. The tephra from Site U1524 compositionally matches with a ca. 1.3 Ma, rhyolitic pumice fall deposit on the rim of the Chang Peak volcano summit caldera, in the Marie Byrd Land, located ca. 1,300 km from Site U1524. This contribution offers important volcanological data on the eruptive history of Chang Peak volcano and adds a new tephrochronologic marker for the dating, correlation, and synchronization of marine and continental early Pleistocene records of West Antarctica.

    

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