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1. Planar chemical reaction systems with algebraic and non-algebraic limit cycles

   https://doi.org/10.1007/s00285-025-02221-0  

   Craciun, Gheorghe; Erban, Radek (May 2025, Journal of Mathematical Biology)

   Abstract The Hilbert numberH(n) is defined as the maximum number of limit cycles of a planar autonomous system of ordinary differential equations (ODEs) with right-hand sides containing polynomials of degree at most$$n \in {{\mathbb {N}}}$$ $n\in N$. The dynamics of chemical reaction systems with two chemical species can be (under mass-action kinetics) described by such planar autonomous ODEs, wherenis equal to the maximum order of the chemical reactions in the system. Analogues of the Hilbert number H(n) for three different classes of chemical reaction systems are investigated: (i) chemical systems with reactions up to then-th order; (ii) systems with up ton-molecular chemical reactions; and (iii) weakly reversible chemical reaction networks. In each case (i), (ii) and (iii), the question on the number of limit cycles is considered. Lower bounds on the modified Hilbert numbers are provided for both algebraic and non-algebraic limit cycles. Furthermore, given a general algebraic curve$$h(x,y)=0$$ $h(x,y)=0$of degree$$n_h \in {{\mathbb {N}}}$$ $n_h\in N$and containing one or more ovals in the positive quadrant, a chemical system is constructed which has the oval(s) as its stable algebraic limit cycle(s). The ODEs describing the dynamics of the constructed chemical system contain polynomials of degree at most$$n=2\,n_h+1.$$ $n=2n_h+1.$Considering$$n_h \ge 4,$$ $n_h\ge 4,$the algebraic curve$$h(x,y)=0$$ $h(x,y)=0$can contain multiple closed components with the maximum number of ovals given by Harnack’s curve theorem as$$1+(n_h-1)(n_h-2)/2$$ $1+(n_h-1)(n_h-2)/2$, which is equal to 4 for$$n_h=4.$$ $n_h=4.$Algebraic curve$$h(x,y)=0$$ $h(x,y)=0$with$$n_h=4$$ $n_h=4$and the maximum number of four ovals is used to construct a chemical system which has four stable algebraic limit cycles. 

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2. Modular apparatus for nuclear reactions spectroscopy (MARS): characterization and first application to determine $$^{12}$$C($$^6$$Li,$$^4$$He)$$^{14}\hbox {N}^{g.s}$$ nuclear reaction cross sections

   https://doi.org/10.1140/epjp/s13360-025-06305-0  

   Garrido-Gómez, L; Vegas-Díaz, A; Alvarez, M_A G; Fernández-García, J P; Fernández, B; Ferrer, F J; Lopez-Aires, D (May 2025, The European Physical Journal Plus)

   Abstract This work presents MARS (Modular apparatus for nuclear reactions spectroscopy) and its characterization prior to its first application to measure$$^6$$ $_{}^6$Li+$$^{12}$$ $_{}^{12}$C nuclear reactions. Measurements were performed at the 3 MV tandem accelerator of the CNA (National Accelerator Center), in Seville, Spain. The$$^{6}$$ $_{}^6$Li projectiles were accelerated at energies around the$$^6$$ $_{}^6$Li+$$^{12}$$ $_{}^{12}$C Coulomb barrier ($$V^{\text {cm}}_{B}\sim 3.0$$ $V_B^{\text{cm}}\sim 3.0$MeV - center of mass and$$V^{\text {lab}}_{B}\sim 4.5$$ $V_B^{\text{lab}}\sim 4.5$MeV - laboratory frame). Using a$$^{6}\hbox {Li}^{2+}$$ $_{}^6{\text{Li}}^{2+}$beam, we measured at 13 laboratory energies from 4.00 to 7.75 MeV. Thus, we present the excitation function of$$^{12}$$ $_{}^{12}$C($$^6$$ $_{}^6$Li,$$^4$$ $_{}^4$He)$$^{14}\hbox {N}^{g.s.}$$ $_{}^{14}{\text{N}}^{g.s.}$reaction, at 2 backward angles ($$110.0^\circ $$ $110.0^{\circ }$and$$140.0^\circ $$ $140.0^{\circ }$). The projectile dissociation, leading to this reaction, increases with the bombarding energies around the Coulomb barrier. This dissociation is favored at an optimum energy$$E_{b}^{\text {op}}$$ $E_b^{\text{op}}$$$\ge $$ $\ge$$$V_{B}$$ $V_B$+$$|Q_{bu}|$$ $|Q_{\mathrm{bu}}|$, where$$V_{B}$$ $V_B$is the Coulomb barrier of the system, and$$|Q_{bu}|$$ $|Q_{\mathrm{bu}}|$is the module ofQ-value for the$$^6$$ $_{}^6$Li dissociation into$$^4$$ $_{}^4$He+$$^2$$ $_{}^2$H. This result corroborates a systematic analysis of weakly bound projectiles reacting on several targets [1]. 

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3. Restricted spaces of holomorphic sections vanishing along subvarieties

   https://doi.org/10.1007/s00209-025-03706-w  

   Coman, Dan; Marinescu, George; Nguyên, Viêt-Anh (May 2025, Mathematische Zeitschrift)

   Abstract LetXbe a compact normal complex space of dimensionnandLbe a holomorphic line bundle onX. Suppose that$$\Sigma =(\Sigma _1,\ldots ,\Sigma _\ell )$$ $\Sigma =({\Sigma }_1,\dots ,{\Sigma }_{\ell })$is an$$\ell $$ $\ell$-tuple of distinct irreducible proper analytic subsets ofX,$$\tau =(\tau _1,\ldots ,\tau _\ell )$$ $\tau =({\tau }_1,\dots ,{\tau }_{\ell })$is an$$\ell $$ $\ell$-tuple of positive real numbers, and let$$H^0_0(X,L^p)$$ $H_0^0(X,L^p)$be the space of holomorphic sections of$$L^p:=L^{\otimes p}$$ $L^p:=L^{\otimes p}$that vanish to order at least$$\tau _jp$$ ${\tau }_{j}p$along$$\Sigma _j$$ ${\Sigma }_j$,$$1\le j\le \ell $$ $1\le j\le \ell$. If$$Y\subset X$$ $Y\subset X$is an irreducible analytic subset of dimensionm, we consider the space$$H^0_0 (X|Y, L^p)$$ $H_0^0\left(X\right|Y,L^p)$of holomorphic sections of$$L^p|_Y$$ $L^p{|}_Y$that extend to global holomorphic sections in$$H^0_0(X,L^p)$$ $H_0^0(X,L^p)$. Assuming that the triplet$$(L,\Sigma ,\tau )$$ $(L,\Sigma ,\tau )$is big in the sense that$$\dim H^0_0(X,L^p)\sim p^n$$ $dim{H}_0^0(X,L^p)\sim p^n$, we give a general condition onYto ensure that$$\dim H^0_0(X|Y,L^p)\sim p^m$$ $dim{H}_0^0\left(X\right|Y,L^p)\sim p^m$. WhenLis endowed with a continuous Hermitian metric, we show that the Fubini-Study currents of the spaces$$H^0_0(X|Y,L^p)$$ $H_0^0\left(X\right|Y,L^p)$converge to a certain equilibrium current onY. We apply this to the study of the equidistribution of zeros inYof random holomorphic sections in$$H^0_0(X|Y,L^p)$$ $H_0^0\left(X\right|Y,L^p)$as$$p\rightarrow \infty $$ $p\to \infty$. 

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4. Exploring Jahn-Teller distortions: a local vibrational mode perspective

   https://doi.org/10.1007/s00894-024-05882-8  

   Quintano, Mateus; Moura, Renaldo T; Kraka, Elfi (April 2024, Journal of Molecular Modeling)

   AbstractThe characterization of normal mode (CNM) procedure coupled with an adiabatic connection scheme (ACS) between local and normal vibrational modes, both being a part of the Local Vibrational Mode theory developed in our group, can identify spectral changes as structural fingerprints that monitor symmetry alterations, such as those caused by Jahn-Teller (JT) distortions. Employing the PBE0/Def2-TZVP level of theory, we investigated in this proof-of-concept study the hexaaquachromium cation case,$$\mathrm {[Cr{(OH_2)}_6]^{3+}}$$ ${\left[\mathrm{Cr}{\left({\mathrm{OH}}_2\right)}_6\right]}^{3+}$/$$\mathrm {[Cr{(OH_2)}_6]^{2+}}$$ ${\left[\mathrm{Cr}{\left({\mathrm{OH}}_2\right)}_6\right]}^{2+}$, as a commonly known example for a JT distortion, followed by the more difficult ferrous and ferric hexacyanide anion case,$$\mathrm {[Fe{(CN)}_6]^{4-}}$$ ${\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]}^{4-}$/$$\mathrm {[Fe{(CN)}_6]^{3-}}$$ ${\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]}^{3-}$. We found that in both cases CNM of the characteristic normal vibrational modes reflects delocalization consistent with high symmetry and ACS confirms symmetry breaking, as evidenced by the separation of axial and equatorial group frequencies. As underlined by the Cremer-Kraka criterion for covalent bonding, from$$\mathrm {[Cr{(OH_2)}_6]^{3+}}$$ ${\left[\mathrm{Cr}{\left({\mathrm{OH}}_2\right)}_6\right]}^{3+}$to$$\mathrm {[Cr{(OH_2)}_6]^{2+}}$$ ${\left[\mathrm{Cr}{\left({\mathrm{OH}}_2\right)}_6\right]}^{2+}$there is an increase in axial covalency whereas the equatorial bonds shift toward electrostatic character. From$$\mathrm {[Fe{(CN)}_6]^{4-}}$$ ${\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]}^{4-}$to$$\mathrm {[Fe{(CN)}_6]^{3-}}$$ ${\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]}^{3-}$we observed an increase in covalency without altering the bond nature. Distinct$$\pi $$ $\pi$back-donation disparity could be confirmed by comparison with the isolated CN$$^-$$ ${}^{-}$system. In summary, our study positions the CNM/ACS protocol as a robust tool for investigating less-explored JT distortions, paving the way for future applications. Graphical abstractThe adiabatic connection scheme relates local to normal modes, with symmetry breaking giving rise to axial and equatorial group local frequencies 

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5. CUPID, the Cuore upgrade with particle identification

   https://doi.org/10.1140/epjc/s10052-025-14352-1  

   Alfonso, K; Armatol, A; Augier, C; Avignone_III, F T; Azzolini, O; Barabash, A S; Bari, G; Barresi, A; Baudin, D; Bellini, F; et al (July 2025, The European Physical Journal C)

   Abstract CUPID, the CUORE Upgrade with Particle Identification, is a next-generation experiment to search for neutrinoless double beta decay ($$0\mathrm {\nu \beta \beta }$$ $0\nu \beta \beta$) and other rare events using enriched Li$$_{2}$$ $_2^{}$$$^{100}$$ $_{}^{100}$MoO$$_{4}$$ $_4^{}$scintillating bolometers. It will be hosted by the CUORE cryostat located at the Laboratori Nazionali del Gran Sasso in Italy. The main physics goal of CUPID is to search for$$0\mathrm {\nu \beta \beta }$$ $0\nu \beta \beta$of$$^{100}$$ $_{}^{100}$Mo with a discovery sensitivity covering the full neutrino mass regime in the inverted ordering scenario, as well as the portion of the normal ordering regime with lightest neutrino mass larger than 10 meV. With a conservative background index of 10$$^{-4}$$ $_{}^{-4}$ cts$$/($$ $/($keV$$\cdot $$ $·$kg$$\cdot $$ $·$yr$$)$$ $)$, 240 kg isotope mass, 5 keV FWHM energy resolution at 3 MeV and 10 live-years of data taking, CUPID will have a 90% C.L. half-life exclusion sensitivity of$$1.8\cdot 10^{27}$$ $1.8·{10}^{27}$ yr, corresponding to an effective Majorana neutrino mass ($$m_{\beta \beta }$$ $m_{\beta \beta }$) sensitivity of 9–15 meV, and a$$3\sigma $$ $3\sigma$discovery sensitivity of$$1\cdot 10^{27}$$ $1·{10}^{27}$ yr, corresponding to an$$m_{\beta \beta }$$ $m_{\beta \beta }$range of 12–21 meV. 

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