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1. Correlation between scale-invariant normal-state resistivity and superconductivity in an electron-doped cuprate

   https://doi.org/10.1126/sciadv.aav6753  

   Sarkar, Tarapada; Mandal, P. R.; Poniatowski, N. R.; Chan, M. K.; Greene, Richard L. (May 2019, Science Advances)

   An understanding of the normal state in the high-temperature superconducting cuprates is crucial to the ultimate understanding of the long-standing problem of the origin of the superconductivity itself. This so-called “strange metal” state is thought to be associated with a quantum critical point (QCP) hidden beneath the superconductivity. In electron-doped cuprates—in contrast to hole-doped cuprates—it is possible to access the normal state at very low temperatures and low magnetic fields to study this putative QCP and to probe the T ➔ 0 K state of these materials. We report measurements of the low-temperature normal-state magnetoresistance (MR) of the n-type cuprate system La 2− x Ce x CuO 4 and find that it is characterized by a linear-in-field behavior, which follows a scaling relation with applied field and temperature, for doping ( x ) above the putative QCP ( x = 0.14). The magnitude of the unconventional linear MR decreases as T c decreases and goes to zero at the end of the superconducting dome ( x ~ 0.175) above which a conventional quadratic MR is found. These results show that there is a strong correlation between the quantum critical excitations of the strange metal state and the high- T c superconductivity. 

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2. Magnetic field reveals vanishing Hall response in the normal state of stripe-ordered cuprates

   https://doi.org/10.1038/s41467-021-24000-3  

   Shi, Zhenzhong; Baity, P. G.; Terzic, J.; Pokharel, Bal K.; Sasagawa, T.; Popović, Dragana (December 2021, Nature Communications)

   null (Ed.)

   Abstract The origin of the weak insulating behavior of the resistivity, i.e. $${\rho }_{xx}\propto {\mathrm{ln}}\,(1/T)$$ ρ x x ∝ ln ( 1 / T ) , revealed when magnetic fields ( H ) suppress superconductivity in underdoped cuprates has been a longtime mystery. Surprisingly, the high-field behavior of the resistivity observed recently in charge- and spin-stripe-ordered La-214 cuprates suggests a metallic, as opposed to insulating, high-field normal state. Here we report the vanishing of the Hall coefficient in this field-revealed normal state for all $$T\ <\ (2-6){T}_{{\rm{c}}}^{0}$$ T < ( 2 − 6 ) T c 0 , where $${T}_{{\rm{c}}}^{0}$$ T c 0 is the zero-field superconducting transition temperature. Our measurements demonstrate that this is a robust fundamental property of the normal state of cuprates with intertwined orders, exhibited in the previously unexplored regime of T and H . The behavior of the high-field Hall coefficient is fundamentally different from that in other cuprates such as YBa 2 Cu 3 O 6+ x and YBa 2 Cu 4 O 8 , and may imply an approximate particle-hole symmetry that is unique to stripe-ordered cuprates. Our results highlight the important role of the competing orders in determining the normal state of cuprates. 

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3. Atomic-scale electronic structure of the cuprate pair density wave state coexisting with superconductivity

   https://doi.org/10.1073/pnas.2002429117  

   Choubey, Peayush; Joo, Sang Hyun; Fujita, K.; Du, Zengyi; Edkins, S. D.; Hamidian, M. H.; Eisaki, H.; Uchida, S.; Mackenzie, A. P.; Lee, Jinho; et al (June 2020, Proceedings of the National Academy of Sciences)

   null (Ed.)

   The defining characteristic of hole-doped cuprates is d -wave high temperature superconductivity. However, intense theoretical interest is now focused on whether a pair density wave state (PDW) could coexist with cuprate superconductivity [D. F. Agterberg et al., Annu. Rev. Condens. Matter Phys. 11, 231 (2020)]. Here, we use a strong-coupling mean-field theory of cuprates, to model the atomic-scale electronic structure of an eight-unit-cell periodic, d -symmetry form factor, pair density wave (PDW) state coexisting with d -wave superconductivity (DSC). From this PDW + DSC model, the atomically resolved density of Bogoliubov quasiparticle states N r , E is predicted at the terminal BiO surface of Bi 2 Sr 2 CaCu 2 O 8 and compared with high-precision electronic visualization experiments using spectroscopic imaging scanning tunneling microscopy (STM). The PDW + DSC model predictions include the intraunit-cell structure and periodic modulations of N r , E , the modulations of the coherence peak energy Δ p r , and the characteristics of Bogoliubov quasiparticle interference in scattering-wavevector space q - space . Consistency between all these predictions and the corresponding experiments indicates that lightly hole-doped Bi 2 Sr 2 CaCu 2 O 8 does contain a PDW + DSC state. Moreover, in the model the PDW + DSC state becomes unstable to a pure DSC state at a critical hole density p *, with empirically equivalent phenomena occurring in the experiments. All these results are consistent with a picture in which the cuprate translational symmetry-breaking state is a PDW, the observed charge modulations are its consequence, the antinodal pseudogap is that of the PDW state, and the cuprate critical point at p * ≈ 19% occurs due to disappearance of this PDW. 

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4. Toward an Ab Initio Theory of High-Temperature Superconductors: A Study of Multilayer Cuprates

   https://doi.org/10.1103/PhysRevX.15.021071  

   Bacq-Labreuil, Benjamin; Lacasse, Benjamin; Tremblay, A-M S; Sénéchal, David; Haule, Kristjan (May 2025, Physical Review X)

   Significant progress toward a theory of high-temperature superconductivity in cuprates has been achieved via the study of effective one- and three-band Hubbard models. Nevertheless, material-specific predictions, while essential for constructing a comprehensive theory, remain challenging due to the complex relationship between real materials and the parameters of the effective models. By combining cluster dynamical mean-field theory and density functional theory in a charge-self-consistent manner, here we show that the goal of material-specific predictions for high-temperature superconductors from first principles is within reach. To demonstrate the capabilities of our approach, we take on the challenge of explaining the remarkable physics of multilayer cuprates by focusing on the two representative ${\mathrm{Ca}}_{(1+n)}{\mathrm{Cu}}_n{\mathrm{O}}_{2n}{\mathrm{Cl}}_2$and ${\mathrm{HgBa}}_2{\mathrm{Ca}}_{(n-1)}{\mathrm{Cu}}_n{\mathrm{O}}_{(2n+2)}$families. We shed light on the microscopic origin of many salient features of multilayer cuprates, in particular, the $n$dependence of their superconducting properties. The growth of $T_c$from the single-layer to the trilayer compounds is here explained by the reduction of the charge transfer gap and, consequently, the growth of superexchange $J$as $n$increases. The origin of both is traced to the appearance of low-energy conduction bands reminiscent of standing wave modes confined within the stack of ${\mathrm{CuO}}_2$planes. We interpret the ultimate drop of $T_c$for $n\ge 4$as a consequence of the inhomogeneous doping between the ${\mathrm{CuO}}_2$planes, which prevents the emergence of superconductivity in the inner planes due to their insufficient effective hole doping, as we also highlight the existence of a minimal doping (4%) required for superconductivity to appear in one of the planes. We explain material-specific properties such as the larger propensity of ${\mathrm{HgBa}}_2{\mathrm{Ca}}_{(n-1)}{\mathrm{Cu}}_n{\mathrm{O}}_{(2n+2)}$to superconduct compared with ${\mathrm{Ca}}_{(1+n)}{\mathrm{Cu}}_n{\mathrm{O}}_{2n}{\mathrm{Cl}}_2$. We also find the coexistence of arcs and pockets observed with photoemission, the charge redistribution between copper and oxygen, and the link to the pseudogap. Our work establishes a framework for comprehensive studies of high-temperature superconducting cuprates, enables detailed comparisons with experiment, and, through its settings, unlocks opportunities for theoretical material design of high-temperature superconductors. Published by the American Physical Society2025 

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5. The Strange Metal State of the Electron-Doped Cuprates

   https://doi.org/10.1146/annurev-conmatphys-031119-050558  

   Greene, Richard L.; Mandal, Pampa R.; Poniatowski, Nicholas R.; Sarkar, Tarapada (March 2020, Annual Review of Condensed Matter Physics)

   An understanding of the high-temperature copper oxide (cuprate) superconductors has eluded the physics community for over thirty years and represents one of the greatest unsolved problems in condensed matter physics. Particularly enigmatic is the normal state from which superconductivity emerges, so much so that this phase has been dubbed a “strange metal.” In this article, we review recent research into this strange metallic state as realized in the electron-doped cuprates with a focus on their transport properties. The electron-doped compounds differ in several ways from their more thoroughly studied hole-doped counterparts, and understanding these asymmetries of the phase diagram may prove crucial to developing a final theory of the cuprates. Most of the experimental results discussed in this review have yet to be explained and remain an outstanding challenge for theory. 

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