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Abstract Neogloboquadrina pachydermais the dominant species of planktonic foraminifera found in polar waters and is therefore invaluable for paleoceanographic studies of the high latitudes. However, the geochemistry of this species is complicated due to the development of a thick calcite crust in its final growth stage and at greater depths within the water column. We analyzed the in situ Mg/Ca and δ18O in discrete calcite zones using laser ablation‐inductively coupled plasma‐mass spectrometry, electron probe microanalysis, and secondary ion mass spectrometry within modernN. pachydermashells from the highly dynamic Fram Strait and the seasonally isothermal/isohaline Irminger Sea. Here we compare shell geochemistry to the measured temperature, salinity, and δ18Oswin which the shells calcified to better understand the controls onN. pachydermageochemical heterogeneity. We present a relationship between Mg/Ca and temperature inN. pachydermalamellar calcite that is significantly different than published equations for shells that contained both crust and lamellar calcite. We also document highly variable secondary ion mass spectrometry δ18O results (up to a 3.3‰ range in single shells) on plankton tow samples which we hypothesize is due to the granular texture of shell walls. Finally, we document that the δ18O of the crust and lamellar calcite ofN. pachydermafrom an isothermal/isohaline environment are indistinguishable from each other, indicating that shifts inN. pachydermaδ18O are primarily controlled by changes in environmental temperature and/or salinity rather than differences in the sensitivities of the two calcite types to environmental conditions.
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Reconstructing Pliocene West Pacific Warm Pool Hydroclimate Using In Situ Microanalyses on Fossil Planktic Foraminifer Shells
Abstract A controversial aspect of Pliocene (5.3–2.6 Ma) climate is whether El Niño‐like (El Padre) conditions, characterized by a reduced trans‐equatorial sea‐surface temperature (SST) gradient, prevailed across the Pacific. Evidence for El Padre is chiefly based on reconstructions of sea‐surface conditions derived from the oxygen isotope (δ18O) and Mg/Ca compositions of shells belonging to the planktic foraminiferTrilobatus sacculifer. However, fossil shells of this species are a mixture of multiple carbonate phases—pre‐gametogenic, gametogenic (reproductive), and diagenetic calcites—that formed under different physiological and/or environmental conditions and are averaged in conventional whole‐shell analyses. Through in situ measurements of micrometer‐scale domains within Pliocene‐aged shells ofT. sacculiferfrom Ocean Drilling Program Site 806 in the western equatorial Pacific, we show that the δ18O of gametogenic calcite is 0.6–0.8‰ higher than pre‐gametogenic calcite, while the Mg/Ca ratios of these two phases are the same. Both the whole‐shell and pre‐gametogenic Mg/Ca records indicate that average early Pliocene SSTs were ~1°C warmer than modern, with present‐day SSTs being established during the latest Pliocene and early Pleistocene (~3.0–2.0 Ma). The measurement of multiple calcite phases by whole‐shell δ18O analyses masks a late Pliocene to earliest Pleistocene (3.6–2.2 Ma) decrease in seawater δ18O (δ18Osw) values reconstructed from in situ pre‐gametogenic δ18O and Mg/Ca measurements. Our novel δ18Oswrecord indicates that sea‐surface salinities in the west Pacific warm pool were higher than modern prior to ~3.5 Ma, which is consistent with more arid conditions under an El Padre state.
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- PAR ID:
- 10456538
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Paleoceanography and Paleoclimatology
- Volume:
- 35
- Issue:
- 7
- ISSN:
- 2572-4517
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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